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Dr. James Biggs Dr. Karsten Danielmeier Dr. Julia Hitzbleck Dr. Jens Krause Tom Kridl Dr. Stephan Nowak Dr. Enrico Orselli Dr. Xina Quan Dirk Schapeler Will Sutherland Dr. Joachim Wagner 《Angewandte Chemie (International ed. in English)》2013,52(36):9409-9421
We present the development and applications of dielectric elastomers. For the last 10 years the significance of this class of polymers has risen as more applications seem possible and first products have been commercialized. 相似文献
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This paper proposes a data-driven stability criterion for quadratic stabilization of unknown nonlinear discrete-time systems. The novelty of this quadratic stability criterion lies in the direct use of the time series of system states, instead of using mathematical models. The data-driven stability criterion is utilized to design a control for stabilizing unknown nonlinear systems using online black-box system identification. The effectiveness and the adaptability of the proposed approach are compared with those of adaptive feedback linearization method with an example of stabilizing a nonlinear aeroelastic system. 相似文献
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Thomas Prenveille Cyrielle Garreau Mathias Matner Dirk Dijkstra Wilhelm Oppermann Diethelm Johannsmann 《Journal of polymer science. Part A, Polymer chemistry》2019,57(5):621-629
The reactivity of urethanes based on 1,6‐hexamethylene diisocyanate (HDI) and 4,4′‐methylene diphenyl diisocyanate (MDI) was investigated at temperatures between 190 °C and 235 °C. Diurethane model compounds end‐capped with either 1‐dodecanol (D‐core‐D) or 1‐hexadecanol (H‐core‐H) were mixed and annealed at high temperature. The core was either MDI or HDI. The transurethanization reaction was followed based on the formation of the compounds (H‐core‐D). The amount of H‐core‐D and of side products, which had formed after variable annealing times, were identified with 1H NMR, FTIR, SEC, and MALDI‐TOF. Transurethanization was considerably faster for MDI‐based urethanes than for HDI‐based urethanes. Only traces of side products were formed during annealing of MDI‐based urethanes, whereas a significant amount of allophanates was formed from HDI‐based urethanes under the same conditions. © 2018 Wiley Periodicals, Inc. J. Polym. Sci., Part A: Polym. Chem. 2019 , 57, 621–629 相似文献
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Yulia B. Monakhova Svetlana P. Mushtakova Thomas Kuballa Dirk W. Lachenmeier 《Magnetic resonance in chemistry : MRC》2014,52(12):755-759
An eight‐fold suppression pulse sequence was recently developed to improve sensitivity in 1H NMR measurements of alcoholic beverages [Magn. Res. Chem. 2011 (49): 734–739]. To ensure that only one combined hydroxyl peak from water and ethanol appears in the spectrum, adjustment to a certain range of ethanol concentrations was required. To explain this observation, the structure of water–ethanol solutions was studied. Hydroalcoholic solutions showed extreme behavior at 25% vol, 46% vol, and 83% vol ethanol according to 1H NMR experiments. Near‐infrared spectroscopy confirmed the occurrence of four significant compounds (‘individual’ ethanol and water structures as well as two water–ethanol complexes of defined composition – 1 : 1 and 1 : 3). The successful multiple suppression can be achieved for every kind of alcoholic beverage with different alcoholic strengths, when the final ethanol concentration is adjusted to a range between 25% vol and 46% vol (e.g. using dilution or pure ethanol addition). In this optimum region, an individual ethanol peak was not detected, because the ‘individual’ water structure and the 1 : 1 ethanol–water complex predominate. The nature of molecular association in ethanol–water solutions is essential to elucidate NMR method development for measurement of alcoholic beverages. The presented approach can be used to optimize other NMR suppression protocols for binary water–organic solvent mixtures, where hydrogen bonding plays a dominant role. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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Gerold Jäger Changxing Dong Boris Goldengorin Paul Molitor Dirk Richter 《Journal of Heuristics》2014,20(1):107-124
We introduce a reduction technique for large instances of the traveling salesman problem (TSP). This approach is based on the observation that tours with good quality are likely to share many edges. We exploit this observation by neglecting the less important tour space defined by the shared edges, and searching the important tour subspace in more depth. More precisely, by using a basic TSP heuristic, we obtain a set of starting tours. We call the set of edges which are contained in each of these starting tours as pseudo-backbone edges. Then we compute the maximal paths consisting only of pseudo-backbone edges, and transform the TSP instance to another one with smaller size by contracting each such path to a single edge. This reduced TSP instance can be investigated more intensively, and each tour of the reduced instance can be expanded to a tour of the original instance. Combining our reduction technique with the currently leading TSP heuristic of Helsgaun, we experimentally investigate 32 difficult VLSI instances from the well-known TSP homepage. In our experimental results we set world records for seven VLSI instances, i.e., find better tours than the best tours known so far (two of these world records have since been improved upon by Keld Helsgaun and Yuichi Nagata, respectively). For the remaining instances we find tours that are equally good or only slightly worse than the world record tours. 相似文献
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