Electric field-assisted charge carrier photogeneration in a ladder-type methyl-substituted poly(paraphenylene) was investigated by ultrafast absorption spectroscopy at low excitation intensity. The dissociation of excitons into electron-hole pairs occurs from the vibrationally relaxed excited state throughout its lifetime and is caused by the applied electric field, rather than by existence of special "dissociation sites." These findings are of importance for material choice in device applications. 相似文献
Fluorescence and transient absorption measurements show that in strongly coupled ZnPc-C60 and H2Pc-C60 dyads charge-separated states are formed; large -delta GCR degree and small lambda assist in stabilising ZnPc(.+)-C60.-/H2Pc(.+)-C60.-. 相似文献
A series of peptidosteroid derivatives containing two independent peptide chains in which Ser and His are incorporated were synthesized by solid-phase peptide synthesis. The activity of the different compounds in the hydrolysis of the activated substrate NF31 was assessed in a stepwise fashion. First, the different resin-bound derivatives 6a-l and 6x-z were individually assayed for serine esterification in the absence of water. The use of a colored substrate allowed for a visual identification of the most active compounds. Through the inclusion of control substances, the involvement of histidine in the mechanism for serine acylation was shown. Second, the hydrolysis and methanolysis of the different acylated derivatives 8a-l and 8x were evaluated using UV spectroscopy, again indicating the involvement of histidine. The feasibility of applying the above procedures in a combinatorial context was proven via the screening of artificial libraries, created by mixing the different resin-bound peptidosteroid compounds. In this respect, the use of a photocleavable linker allowed for the unambiguous structural characterization of the selected members via application of single-bead electrospray tandem mass spectrometry. 相似文献
Motivated by recent traffic control models in ATM systems, we analyse three closely related systems of fluid queues, each consisting of two consecutive reservoirs, in which the first reservoir is fed by a two-state (on and off) Markov source. The first system is an ordinary two-node fluid tandem queue. Hence the output of the first reservoir forms the input to the second one. The second system is dual to the first one, in the sense that the second reservoir accumulates fluid when the first reservoir is empty, and releases fluid otherwise. In these models both reservoirs have infinite capacities. The third model is similar to the second one, however the second reservoir is now finite. Furthermore, a feedback mechanism is active, such that the rates at which the first reservoir fills or depletes depend on the state (empty or nonempty) of the second reservoir.The models are analysed by means of Markov processes and regenerative processes in combination with truncation, level crossing and other techniques. The extensive calculations were facilitated by the use of computer algebra. This approach leads to closed-form solutions to the steady-state joint distribution of the content of the two reservoirs in each of the models. 相似文献
Summary: Phosphonate groups were introduced into block copolymers of styrene derivatives either as single end‐groups or as small blocks using nitroxide‐mediated radical polymerization. In order to combine the hydrophobic and hydrophilic segments, block copolymers with N,N‐dimethyl acrylamide were synthesized. After hydrolysis to phosphonic acid groups, adsorption of the polymer onto metal oxides was possible.
Conversion of the phosphonate groups by transesterification with trimethylbromosilane (TMBS), followed by hydrolysis of the silylester group. 相似文献