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931.
Guldi DM Marcaccio M Paolucci F Paolucci D Ramey J Taylor R Burley GA 《The journal of physical chemistry. A》2005,109(43):9723-9730
Fine-tuned control over the donor strength in a series of trannulenes-based donor-acceptor ensembles is used to alter the deactivation path of the photoexcited-state chromophore and to modulate the rates of intramolecular electron transfer. For the first time, a detailed analysis of emission spectra, time-dependent spectroscopic measurements, and electrochemistry prove spectroscopically and kinetically that trannulenes can serve, in a manner similar to C(60) and C(60) monoadducts, as both electron and also as energy acceptor in donor-acceptor ensembles, producing widely different electron-transfer regimes. This investigation also shows that the integration of trannulenes, as a versatile electron-acceptor building block, consistently produces charge recombination in the inverted Marcus region. 相似文献
932.
Wahlen J De Vos D De Hertogh S Nardello V Aubry JM Alsters P Jacobs P 《Chemical communications (Cambridge, England)》2005,(7):927-929
Lanthanum(III)-exchanged zeolites Beta and USY are active and selective catalysts for the generation of singlet oxygen from H2O2 showing superior activity and oxidant efficiency compared to unsupported La-catalysts, e.g. La(OH)3. 相似文献
933.
Ghalit N Rijkers DT Kemmink J Versluis C Liskamp RM 《Chemical communications (Cambridge, England)》2005,(2):192-194
An alkene-bridged mimic of the complex DE-bisthioether-ring system of the antibiotic nisin was prepared in one step from the linear precursor. 相似文献
934.
935.
We have designed a high-efficiency broadband grating coupler for coupling between silicon-on-insulator (SOI) waveguides and optical fibers. The grating is only 13 microm long and 12 microm wide, and the size of the grooves is optimized numerically. For TE polarization the coupling loss to single-mode fiber is below 1 dB over a 35-nm wavelength range when using SOI with a two-pair bottom reflector. The tolerances to fabrication errors are also calculated. 相似文献
936.
Specific external control of chemical reaction systems and both dynamic control and signal processing as central functions in biochemical reaction systems are important issues of modern nonlinear science. For example nonlinear input-output behavior and its regulation are crucial for the maintainance of the life process that requires extensive communication between cells and their environment. An important question is how the dynamical behavior of biochemical systems is controlled and how they process information transmitted by incoming signals. But also from a general point of view external forcing of complex chemical reaction processes is important in many application areas ranging from chemical engineering to biomedicine. In order to study such control issues numerically, here, we choose a well characterized chemical system, the CO oxidation on Pt(110), which is interesting per se as an externally forced chemical oscillator model. We show numerically that tuning of temporal self-organization by input signals in this simple nonlinear chemical reaction exhibiting oscillatory behavior can in principle be exploited for both specific external control of dynamical system behavior and processing of complex information. 相似文献
937.
Motivated by recent experiments, we study the electronic structure near impurities in the chains of YBa2Cu3O6+x. Using a model of proximity induced chain superconductivity, we show that a resonance state in the chain density of states is induced only by a magnetic impurity. The spatial form of the resonance reflects the particle-hole nature of chain superconductivity and therefore distinguishes it from other broken symmetry phases. Because of quantum interference effects between impurities, the chains can undergo a quantum phase transition into a polarized state. 相似文献
938.
The combination of optical coherence tomography and spectroscopy may allow for highly localized, quantitative measurements of tissue spectral properties. We present, for the first time to our knowledge, quantitative measurements of the absorption coefficients of phantoms and of hemoglobin and oxygenated hemoglobin with spectroscopic optical coherence tomography (SOCT). Our results suggest that SOCT will be able to provide localized, quantitative oxygenation measurements. 相似文献
939.
Bourgeois ME Wajer FT Roth M Briguet A Décorps M van Ormondt D Segebarth C Graveron-Demilly D 《Journal of magnetic resonance (San Diego, Calif. : 1997)》2003,163(2):277-287
This paper analyzes the effects of intra-scan motion and demonstrates the possibility of correcting them directly in k-space with a new automatic retrospective method. The method is presented for series of 2D acquisitions with Cartesian sampling. Using a reference k-space acquisition (corrected for translations) within the series, intra-scan motion parameters are accurately estimated for each trajectory in k-space of each data set in the series resulting in pseudo-random sample positions. The images are reconstructed with a Bayesian estimator that can handle sparse arbitrary sampling in k-space and reduces intra-scan rotation artefacts to the noise level. The method has been assessed by means of a Monte Carlo study on axial brain images for different signal-to-noise ratios. The accuracy of motion estimates is better than 0.1 degrees for rotation, and 0.1 and 0.05 pixel, respectively, for translation along the read and phase directions for signal-to-noise ratios higher than 6 of the signals on each trajectory. An example of reconstruction from experimental data corrupted by head motion is also given. 相似文献
940.
Cederberg J Nichol J Frodermann E Tollerud H Hilk G Buysman J Kleiber W Bongard M Ward J Huber K Khanna T Randolph J Nitz D 《The Journal of chemical physics》2005,123(13):134321
A high-precision examination of the hyperfine spectrum of 6LiI in comparison with 7LiI shows a shift in the iodine nuclear electric quadrupole moment that cannot be accounted for by a model in which the electric field gradient at the iodine site is assumed to depend only upon the internuclear distance between Li and I. The other hyperfine interactions are consistent between the two isotopomers, including the previously reported electric hexadecapole interaction of the iodine nucleus. 相似文献