全文获取类型
收费全文 | 383篇 |
免费 | 2篇 |
国内免费 | 2篇 |
专业分类
化学 | 202篇 |
晶体学 | 6篇 |
力学 | 5篇 |
数学 | 85篇 |
物理学 | 89篇 |
出版年
2023年 | 5篇 |
2021年 | 5篇 |
2020年 | 9篇 |
2019年 | 4篇 |
2018年 | 3篇 |
2017年 | 3篇 |
2016年 | 3篇 |
2015年 | 5篇 |
2014年 | 7篇 |
2013年 | 11篇 |
2012年 | 7篇 |
2011年 | 22篇 |
2010年 | 13篇 |
2009年 | 5篇 |
2008年 | 13篇 |
2007年 | 16篇 |
2006年 | 22篇 |
2005年 | 15篇 |
2004年 | 17篇 |
2003年 | 24篇 |
2002年 | 8篇 |
2001年 | 3篇 |
2000年 | 3篇 |
1998年 | 4篇 |
1997年 | 4篇 |
1996年 | 3篇 |
1995年 | 4篇 |
1994年 | 4篇 |
1990年 | 3篇 |
1988年 | 5篇 |
1987年 | 3篇 |
1986年 | 3篇 |
1984年 | 6篇 |
1983年 | 3篇 |
1982年 | 3篇 |
1980年 | 3篇 |
1978年 | 6篇 |
1965年 | 3篇 |
1907年 | 4篇 |
1905年 | 6篇 |
1904年 | 7篇 |
1901年 | 4篇 |
1900年 | 5篇 |
1899年 | 2篇 |
1898年 | 5篇 |
1897年 | 7篇 |
1892年 | 5篇 |
1889年 | 2篇 |
1882年 | 4篇 |
1881年 | 2篇 |
排序方式: 共有387条查询结果,搜索用时 15 毫秒
11.
We study the existence and non-existence of positive singular solutions of second-order non-divergence type elliptic inequalities of the form $\sum\limits_{i,j = 1}^N {a_{ij} (x)\frac{{\partial ^2 u}} {{\partial x_i \partial x_j }}} + \sum\limits_{i = 1}^N {b_i (x)\frac{{\partial u}} {{\partial x_i }} \geqslant K(x)u^p ,} - \infty < p - \infty , $ with measurable coefficients in a punctured ball B R \{0} of ? N , N ≥ 1. We prove the existence of a critical value p* which separates the existence region from the non-existence region. We show that in the critical case p = p*, the existence of a singular solution depends on the rate at which the coefficients (a i j ) and (b i ) stabilize at zero, and we provide some optimal conditions in this setting. 相似文献
12.
Givenμ, κ, c>0, we consider the functional
defined on allR
n
-valued functionsu on the open subset Ω ofR
n
which are smooth outside a free discontinuity setS
u, on which the tracesu
+,u
− on both sides have equal normal component (i.e.,u has a tangential jump alongS
u).E
Du=Eu − 1/3 (divu)I, withEu denoting the linearized strain tensor.
The functionalF is obtained from the usual strain energy of linearized elasticity by addition of a term (the second integral) which penalizes
the jump discontin uities of the displacement.
The lower semicontinuous envelope
is studied, with respect to theL
1 (Ω;R
n
)-topology, on the spaceP(Ω) of the functions of bounded deformation with distributional divergence inL
2(Ω) (F is extended with value +∞ on the wholeP(Ω)). The following integral representation is proved:
whereϕ is a convex function with linear growth at infinity. NowEu is a measure,ɛ
Du represents the density of the absolutely continuous part of the absolutely continuous part ofE
Du, whileE
s
D
u denotes the singular part and ϕ∞ the recession function ofϕ.
Finally, we show that
coincides with the functional which intervenes in the minimum problem for the displacement in the theory of Hencky’s plasticity
with Tresca’s yield conditions. 相似文献
13.
Shiri Artstein-Avidan Omer Friedland Vitali Milman Sasha Sodin 《Israel Journal of Mathematics》2006,156(1):141-155
We present a quantitative form of the result of Bai and Yin from [2], and use to show that the section of ℓ
1
(1+δ)n
spanned byn random independent sign vectors is with high probability isomorphic to euclidean with isomorphism constant polynomial in
δ−1.
Partially supported by BSF grant 2002-006.
Supported by the National Science Foundation under agreement No. DMS-0111298.
Supported in part by the Israel Science Academy. 相似文献
14.
15.
16.
In this paper, we show that the well-known duality operation in the context of convex bodies in Rn is completely characterized by its property of interchanging sections with projections. Our results are compared to results by Böröczky-Schneider and Artstein-Milman, who showed that in many cases, the property of order reversing is sufficient to determine a duality operation, up to obvious linear modifications. In fact, we provide another result that recovers a known characterization of duality by the property of order reversing, and up to a mild condition, also a characterization of duality by interchanging sections by projections. 相似文献
17.
Ana Barragn Ane Sarasola Lucia Vitali 《Angewandte Chemie (International ed. in English)》2020,59(36):15599-15602
Efficiency in charge‐transport is a fundamental but demanding prerequisite to allow better exploitation of molecular functionalities in organic electronics and energy‐conversion systems. Here, we report on a mechanism that enables a one‐dimensional conductance structure by connecting discrete molecular states at 2.1 eV through the pores of a metal–organic network on Cu(110). Two adjacent, periodic and isoenergetic contributions, namely a molecular resonance and the confined surface‐state, add‐up leading to anisotropic structures, as channels, observable in real‐space conductance images. The adsorption configurations of Br atoms, inorganic byproduct of the redox‐reacted 4,7‐dibromobenzo[c]‐1,2,5‐thiadiazole (2Br‐BTD) molecules on the copper surface, drive the confinement of the Cu surface state within the pores and critically control the channel continuity. Small displacements of the Br atoms change the local surface potential misaligning the energy levels. This work visualizes the effect of order‐disorder transitions caused by the movement of single atoms in the electronic properties of two‐dimensional organic networks. 相似文献
18.
Taran Driver Nikhil Bachhawat Leszek J. Frasinski Jonathan P. Marangos Vitali Averbukh Marina Edelson-Averbukh 《Molecules (Basel, Switzerland)》2021,26(12)
The rate of successful identification of peptide sequences by tandem mass spectrometry (MS/MS) is adversely affected by the common occurrence of co-isolation and co-fragmentation of two or more isobaric or isomeric parent ions. This results in so-called `chimera spectra’, which feature peaks of the fragment ions from more than a single precursor ion. The totality of the fragment ion peaks in chimera spectra cannot be assigned to a single peptide sequence, which contradicts a fundamental assumption of the standard automated MS/MS spectra analysis tools, such as protein database search engines. This calls for a diagnostic method able to identify chimera spectra to single out the cases where this assumption is not valid. Here, we demonstrate that, within the recently developed two-dimensional partial covariance mass spectrometry (2D-PC-MS), it is possible to reliably identify chimera spectra directly from the two-dimensional fragment ion spectrum, irrespective of whether the co-isolated peptide ions are isobaric up to a finite mass accuracy or isomeric. We introduce ‘3-57 chimera tag’ technique for chimera spectrum diagnostics based on 2D-PC-MS and perform numerical simulations to examine its efficiency. We experimentally demonstrate the detection of a mixture of two isomeric parent ions, even under conditions when one isomeric peptide is at one five-hundredth of the molar concentration of the second isomer. 相似文献
19.
We prove the existence of solutions for some semilinear elliptic equations in the appropriate H4 spaces using the fixed‐point technique where the elliptic equation contains fourth‐order differential operators with and without Fredholm property, generalizing the previous results. 相似文献
20.
Castagnola M Rossetti DV Inzitari R Vitali A Lupi A Zuppi C Cabras T Fadda MB Petruzzelli R Giardina B Messana I 《Electrophoresis》2003,24(5):801-807
Measurements by capillary electrophoresis (CE) of bacitracin A(1) effective mobility at different pH values permitted to estimate the five acidic dissociation constants and the Stokes radii at different protonation stages of the macrocyclic dodecapeptide. The pK(a) values were 3.6 and 4.4 for the two carboxylic groups of the lateral chains of D-Asp-11 and D-Glu-4, respectively, 6.4 for the aza-atom of the imidazole ring of His-10, 7.6 for the amino group of N-terminal Ile-1 and 9.7 for the delta-amino group of D-Orn-7, very close to the values obtained by other researchers by titration experiments. In agreement with a rigid macrocyclic structure the Stokes radii of different protonated forms ranged only between 14.3 and 14.8 A. Best fitting procedures performed on experimental mobility measured at two different pH values (5.50 and 6.72) in the presence of increasing Zn(+2) concentration allowed confirming the model that assumes the binding of Zn(+2) to P(0) peptide form with a 1.5 x 10(3) M(-1) intrinsic association constant. Following to Zn(+2) binding, the pK(a) of the amino group of N-terminal Ile-1 is shifted from 7.6 to 5.9 and the Stokes radius is reduced of about 3 A. The mean charge of the bacitracin A(1)-Zn(+2) complex resulted +1.67 and +1.12 at pH 5.50 and 6.72, respectively. These results suggest that the amino group of N-terminal Ile-1 is not essential for Zn(+2) binding. 相似文献