Mercury(II) dibromo-bis-(3-amino-5-mercapto-1,2,4-triazole): synthesis,crystal structure,and infrared characterization

The title compound C₄H₈N₈S₂HgBr₂ was prepared and characterized by means of X-ray crystallography, and i.r. measurements. The crystals are orthorhombic, space group Pbcn (no. 60) witha=9.707(2),b=8.609(1),c=16.128(2) Å, andZ=4. The compound exhibits discrete monometallic units with the 1,2,4-triazole molecule acting as a monodentate ligand. The structure consists of units in which the mercury atom is coordinated in a distorted tetrahedral geometry by two sulfur and two bromine atoms. The NH and NH₂ group of the 3-amino-5-mercapto-1,2,4-triazole unit are involved in intermolecular hydrogen bonds. Infrared bands are diagnostic of the coordination environment around the metal atoms.     

The effect of a nonlinear temperature dependent Prandtl-number on heat transfer of fully developed flow of liquids in a straight tube

If Nu_o is the Nusselt Number for a temperature-independent Prandtl number Pr, and Nu the Nusselt number for a temperature dependent Prandtl number, it is usual to define the correction factor Nu/Nu_o=C. A correction factor which has been defined in this form has, up to now, only been expressed as a function of two characteristic Pr numbers. Thus it was simply assumed that the Pr number was a linear function of the temperature. Fluids with very large Pr numbers show a (T;Pr) relationship which deviates considerably from a linear one. This leads to a very large difference (up to 70%) between the calculated and the measured values of the Nusselt number. In the following study we shall determine a so-called curvature parameter of the (T;Pr) curve and obtain a semi-empirical formula for C. This formula has a deviation from the actual relationship many times smaller than that of the formulae for a linear (T;Pr) relationship.

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Zusammenfassung Ist Nu_o die Nusseltzahl bei temperaturunabhangiger und Nu die Nusseltzahl bei temperaturabhangiger Prandtlzahl Pr, so ist es üblich, mit Nu/Nu_o=C den Korrekturfaktor zu bezeichnen. Ein in dieser Form definierter Faktor C ist bisher als Funktion nur zweier charakteristischer Pr-Zahlen ausgedrückt worden. Es wurde somit nur eine lineare Abhängigkeit von der Pr-Zahl von der Temperatur T vorausgesetzt. Flüssigkeiten mit großen Pr-Zahlen weisen eine (T;Pr)-Charakteristik auf, die sehr stark von der linearen abweicht. Sehr große Abweichungen (bis — 70%) der gerechneten von den gemessenen Nu-Zahlen sind eine Folge davon. In vorliegender Arbeit bilden wir mit einer dritten charakteristischen Pr-Zahl einen sogenannten Krümmungsparameter der Kurve (T;Pr) und leiten eine semiempirische Formel für C ab, die um ein großes Vielfaches kleinere Fehler aufweist, als die Formeln für den linearen (T;Pr)-Verlauf.

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Nomenclature

Material constants c_p specific heat at constant pressure [J/kgK] - k heat conductivity [W/mK] - density [kg/m³] - a temperature diffusivity, a=k/c_p [m²/s] - dynamic viscosity [Ns/m²] - kinematic viscosity [m²/s] Fluid dynamics D inner diameter of the tube [m] - L length of tube [m] - w mean speed of fluid [m/s] Heat transfer h coefficient of heat transfer [W/m²K] - T absolute temperature [K] - T_b bulk temperature (corresponding to the adiabatic mixing temperature) [K] - T_w tube wall temperature [K] - T_f=(T_b+T_w)/2 film temperature [K] - T=T_b-T_w temperature forcing difference of heat transfer [K] Characteristic quantities without dimensions Re=wD/ Reynolds number - Pr=/a Prandtl number - Nu=hD/k Nusselt number - related temperature - related Prandtl number - curvature parameter of the Prandtl number Various - C=Nu_b/Nu_o correction factor according to Eq.(5) - p exponent in Eq.(6), (a), (8) and (16) Indices o corresponding to the quasi-isothermal heat transfer - b,w,f with reference to quantities, including physical properties which correspond to the temperatures T_b, T_wor T_f - Pr,k,, for quantities calculated corresponding to the Prandtl number, the thermal conductivity coefficient, the density or the dynamic viscosity - H,C for heating or cooling exp for quantities calculated from experimental data     

Determination of calcium,strontium and barium in single crystals of alkali halides by neutron activation

The determination by neutron activation of trace quantities of calcium, strontium and barium in single crystals of alkali halides has been studied. The matrix is eliminated before the irradiation by an ion-exchange procedure. Gamma spectroscopy after radiochemical separation is used to determine strontium and barium. Calcium is determined by measuring the β-activity of ⁴⁹Sc formed by the decay of ⁴⁹Ca. Long-lived radioactive tracers are used to determine the chemical yields.     

Nonparametric Resampling for Homogeneous Strong Mixing Random Fields

Künsch (1989, Ann. Statist.17 1217-1241) and Liu ane Singh (1992, in Exploring Limits of Bootstrap (R. Le Page and L. Billard, Eds.), pp. 225-248, Wiley, New York) have recently introduced a block resampling method that is successful in deriving consistent bootstrap estimates of distribution and variance for the sample mean of a strong mixing sequence. Raïs and Moore (1990, in Interface ′90) and Raïs (1992, Ph.D. Thesis, University of Montreal) extended the results of Künsch and Liu and Singh in the case of the sample mean of a homogeneous strong mixing random field in two dimensions (n = 2). In this paper, the general case (n Z⁺) is considered, and a resampling technique for strong mixing random fields is formulated, which is an extension of the "blocks of blocks" resampling scheme for sequences in Politis and Romano (1992, Ann. Statist.20 (4) 1985-2007). The "blocks of blocks" method can be used to construct asymptotically correct confidence intervals for parameters of the whole (infinite-dimensional) joint distribution of the random field, for example, the spectral density at a point. A variation of the "blocks of blocks" resampling scheme that involves "wrapping" the data around on a torus will also be studied, in view of its property to yield an unbiased bootstrap distribution.     

Spatial functional normal mixed effect approach for curve classification

This paper proposes a spatial functional formulation of the normal mixed effect model for the statistical classification of spatially dependent Gaussian curves, in both parametric and state space model frameworks. Fixed effect parameters are represented in terms of a functional multiple regression model whose regression operators can change in space. Local spatial homogeneity of these operators is measured in terms of their Hilbert–Schmidt distances, leading to the classification of fixed effect curves in different groups. Assuming that the Gaussian random effect curves obey a spatial autoregressive dynamics of order one [SARH(1) dynamics], a second functional classification criterion is proposed in order to detect local spatially homogeneous patterns in the mean quadratic functional variation of Gaussian random effect curve increments. Finally, the two criteria are combined to detect local spatially homogeneous patterns in the regression operators and in the functional mean quadratic variation, under a state space approach. A real data example in the financial context is analyzed as an illustration.     

Investigation on time scales in a low Reynolds number jet flow using particle-tracking velocimetry

The near flow field of an axisymmetric water jet at Reynolds numbers between 2000 and 5000 is investigated using Particle-Tracking Velocimetry. Measurements are taken in the longitudinal section (along the mean flow) and in cross-sections (orthogonal to the mean flow). From the former, correlation coefficients of the two in-plane velocity components in a Lagrangian framework are obtained: thus Lagrangian integral scales can be computed. Those of the streamwise velocity (axial) component increase on moving away from the centreline, whereas the opposite happens for the vertical velocity (radial) component: integral time scales of the two components are almost equal at the interface between jet and ambient fluids. On the other hand, integral scales are almost constant or increase slightly with the axial direction. In cross-sections, fluid ejection and injection from the jet centreline are observed to be connected to counter-rotating vortices (mushroom): their number and size change with Reynolds number in agreement with results from other authors. The maximum ejection velocity (orthogonal to the mean jet flow), at 3 nozzle diameters downstream of the outlet, is found to be one half of the mean outlet velocity.     

On Leon's criterion

Summary The theory of limit surfaces of resistance for isotropic materials in the space of the principal stress components is recalled. This resistance is viewed in terms of the phenomena of ductile or brittle failure that may arise in alternation for a given material, depending on the type of stress state. A transformation of coordinates is introduced that proves to be very useful for comparing the various limit conditions with that deriving from intrinsic curve theory. Reference is made to the criterion of Stassi, certainly the most reliable of the criteria that allow for dependence of the limit condition on the value of the principal intermediate stress. The theory of the intrinsic curve is generalised by means of Leon's modification, which interprets the phenomenon of tensile fracture. It is shown how Griffith's theory of brittle fracture leads to a limit condition that may be regarded as a special case of the one deriving from Leon's theory. Comparison with some experimental data shows that Leon's theory is well suitable for the study of brittle fracture. A generalisation that takes account of the influence of the principal intermediate stress and so permits good agreement with the experimental data in the field of ductile failure too, whilst conserving the characteristics of Leon's theory in brittle fracture, is proposed.

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Sommario Si richiama la teoria delle superfici limiti di resistenza per materiali isotropi nello spazio delle componenti principali di tensione. Tale resistenza è intesa nei riguardi dei fenomeni di rottura duttile o fragile che possono intervenire in alternativa per uno stesso materiale in dipendenza dei diversi tipi di stato tensionale. Si introduce una trasformazione di coordinate che risulta particolarmente utile per il confronto delle varie condizioni limiti con quella derivante dalla teoria della curva intrinseca. In particolare si fa riferimento al criterio di Stassi, certo il più attendibile fra quelli che prendono in considerazione la dipendenza della condizione limite dal valore della tensione principale intermedia. La teoria della curva intrinseca viene generalizzata attraverso la modifica di Leon, che interpreta il fenomeno della crisi per distacco. Si mostra come la teoria di Griffith della rottura fragile conduca ad una condizione limite che si può considerare un caso particolare di quella derivante dalla teoria di Leon. Per confronto con alcuni dati sperimentali si verifica che questa ultima teoria bene si presta allo studio dei fenomeni di rottura fragile. Si propone una generalizzazione che, tenendo conto dell'influenza della tensione principale intermedia, consente di ottenere un buon accordo con l'esperienza anche nel campo di rottura duttile, pur conservando le caratteristiche della teoria di Leon in quello della rottura fragile.