Observation of intersubband excitations in a multilayer two dimensional electron gas

We report the observation, by resonant inelastic light scattering, of intersubband excitations of the multilayer two dimensional electron gas, in modulation doped GaAsAlGaAs heterojunction superlattices. These are the first measurements of these transitions by any technique, and furnish intersubband energies in good agreement with calculated values. The spectral bands are broad, and nearly Lorentzian in shape: the implied relaxation rates scale linearly with band energy and are significantly faster than transport relaxation rates. Finally, the polarized spectra reveal differences between spin-flip and non spin-flip excitations which are unique to multilayer two dimensional electron gases.     

The evaluation of integrals containing a parameter

Summary A number of methods for obtaining expansions and approximations to an integral containing a parameter are expounded, and each illustrated by evaluating the function      

Gas-phase deprotonation of arylalkylamines. A collision-induced dissociation study

The collision-induced dissociation (CID) of deprotonated arylalkylamines of general formula R(1)C(6)H(4)CHR(2)CH(2)NR(3)(2) (where R(1) = H, OH, F or NO(2); R(2) = H or OH; R(3) = H or CH(3)) generated by negative chemical ionization with H(2)O and D(2)O as ionizing reagents, is discussed. The negative chemical ionization mass spectra show that, in the absence of a hydroxy group in the aromatic ring, deprotonation takes place at the benzylic position whereas the proton is lost from the OH group when present. The nitro compound forms only M(-.) ions. The CID spectra of the deprotonated molecules show that fragmentations are strongly dependent on the structural features of the molecules, namely the presence or absence of substituents in the aromatic ring or aliphatic chain. Copyright 1999 John Wiley & Sons, Ltd.     

WKB methods for difference equations II

Summary In a previous paper [1] it was shown how to develop solutions to difference equations analogous to WKB solutions to differential equations. In the work now reported a much more general comparison equation theory [2] is developed for difference equations, exploiting the fact that a difference equation can be considered as a differential equation of infinite order. Second order difference equations are considered in the main; by applying the theory to first order difference equations a useful generalization of the Euler-Maclaurin summation formula is found.     

Performance analysis of asynchronous parallel Jacobi

The directed acyclic graph (DAG) associated with a parallel algorithm captures the partial order in which separaT.L.cal computations are completed and how their outputs are subsequently used in further computations. Unlike in a synchronous parallel algorithm, the DAG associated with an asynchronous parallel algorithm is not predetermined. Instead, it is a product of the asynchronous timing dynamics of the machine and cannot be known in advance, as such it is best thought of as a pseudorandom variable. In this paper, we present a formalism for analyzing the performance of asynchronous parallel Jacobi’s method in terms of its DAG. We use this app.roach to prove error bounds and bounds on the rate of convergence. The rate of convergence bounds is based on the statistical properties of the DAG and is valid for systems with a non-negative iteration matrix. We supp.ort our theoretical results with a suit of numerical examples, where we compare the performance of synchronous and asynchronous parallel Jacobi to certain statistical properties of the DAGs associated with the computations. We also present some examples of small matrices with elements of mixed sign, which demonstrate that determining whether a system will converge under asynchronous iteration in this more general setting is a far more difficult problem.     

Purification and Characterization of Agarase from Marine Bacteria <Emphasis Type="Italic">Acinetobacter</Emphasis> sp. PS12B and Its Use for Preparing Bioactive Hydrolysate from Agarophyte Red Seaweed <Emphasis Type="Italic">Gracilaria verrucosa</Emphasis>

Acinetobacter strain PS12B was isolated from marine sediment and was found to be a good candidate to degrade agar and produce agarase enzyme. The extracellular agarase enzyme from strain PS12B was purified by ammonium sulfate precipitation followed by DEAE-cellulose ion-exchange chromatography. The specific activity of the crude enzyme which was 1.52 U increased to 45.76 U, after two-stage purification, with an enzyme yield of 9.76%. Purified enzyme had a molecular mass of 24 kDa. The optimum pH and temperature for activity of purified agarase were found to be 8.0 and 40 °C, respectively. The K_m and V_max values for agarase were 4.69 mg/ml and 0.5 μmol/min, respectively. Treatment with EDTA reduced the agarase activity by 58% at 5 mM concentration. The enzyme activity was stimulated by the presence of Fe²⁺, Mn²⁺, and Ca2⁺ ions while reducing reagents (β-mercaptoethanol and dithiothreitol, DTT) enhanced its activity by 30–40%. The purified agarase exhibited tolerance to both detergents and organic solvents. Major hydrolysis products of agar were DP4 and also a mixture of longer oligosaccharides DP6 and DP7. The enzyme hydrolysed seaweed (Gracilaria verrucosa) exhibited strong antioxidant activity in vitro. Successful hydrolysis of seaweed indicates the potential use of the enzyme to produce seaweed hydrolysate having health benefits as well as the industrial application like the production of biofuels.     

Determination of the REE content,geological age,and absorbed alpha dose of allanite mineral from Palawan,Philippines

Allanite is a common accessory mineral in igneous rocks that contains significant amounts of rare-earth elements (REEs), thorium (Th), and uranium (U). The presence of Th and U in the allanite exposes it to radiation resulting in radiation damage in its crystal structure and further leads to metamictization. Hence, allanite can be used as a natural analogue to assess the long-term radiation effects in materials for high-level nuclear waste disposal. It provides information on the effect of α-decay on the crystal structure including the stability and integrity of the material. In this study, the absorbed α-dose of allanite from Ombo, Palawan, Philippines, was estimated from the Th and U content and geological age of the mineral using X-ray fluorescence and gamma-ray spectrometry. The amount of Th and REE was measured to be around 1.37 and ~30.4 wt.%, respectively. Radiometric dating using gamma-ray spectrometry estimated the age of the allanite mineral to be around 24–35 million years. Having obtained the amount of radioactivity and the time of exposure, the corresponding absorbed α-dose was estimated to be at 2.84 × 10¹⁴ α-decays/mg. Results suggest that the allanite mineral studied has not accumulated significant radiation damage to cause amorphization and still exhibit a crystalline structure. This study may provide data on the properties of allanite or silicate matrices as part of the ongoing studies on silicate minerals as natural analogues.