Bi12TiO20纳米粉体的制备及其光吸收特性研究

以钛酸四丁酯和硝酸铋为原料 ,利用化学溶液分解法制备了Bi12 TiO2 0 纳米多晶粉体 .采用XRD和TEM对其结构和形貌进行了表征 .结合热重 差热 (TG DTA)分析 ,探讨了Bi12 TiO2 0 晶相的形成机理 .通过UV Vis漫反射谱的测定 ,研究了Bi12 TiO2 0 纳米晶粉体的光吸收特性 .结果显示 ,从组成为化学计量比的前驱液中可以很容易制得纯Bi12 TiO2 0 纳米晶粉体 ,该Bi12 TiO2 0 纳米晶粉体呈现了在很宽的波长范围内 (5 6 0～ 385nm )对光的吸收的特性 .     

Si微电阻桥温度分布与热传导特性的显微Raman光谱研究

采用显微Raman光谱方法对红外目标模拟器中重掺杂Si微电阻桥单元的热传导特性进行研究，根据Si桥的实际特性建立相应的Raman散射模型，通过测量Raman峰位的移动得到高功率激光辐照下测量点的温度.对Si桥桥面分别进行了沿某些特殊线段的逐点线扫描和覆盖全部桥面的面扫描，得到各点的温升及其分布.用基于有限元分析的软件结合Si桥结构参数对各测量点的温升进行了模拟计算，其结果在热导分布的基本趋势上与实验相一致.实验细致地揭示了热导分布的局域起伏，反映出实际器件的不均匀性，为改进器件设计、优化器件性能提供了实验依据. 关键词： Raman光谱 Si桥 温度分布 热导     

Effects of Evanescent Space-Harmonics on the Transmission Characteristics of a Gaussian Beam by Cylindrical Wire Grids

When electromagnetic waves propagate through a wire grid, there will be some evanescent space harmonics generated around the wire grid. In this paper, we mainly investigate their effects on the transmission characteristics of a Gaussian beam by cylindrical wire grids. The results are compared with those without taking account of evanescent space-harmonics.     

Analysis of the charge transfer mechanisms responsible for the current-voltage characteristics of Ca<Subscript>4</Subscript>Ga<Subscript>2</Subscript>S<Subscript>7</Subscript>: Eu<Superscript>3+</Superscript> single crystals

The current-voltage characteristics of Ca₄Ga₂S₇: Eu³⁺ single crystals are measured for the first time, and the processes affecting these characteristics are analyzed theoretically. It is demonstrated that Ca₄Ga₂S₇: Eu³⁺ single crystals are high-resistance semiconductors with a resistivity of ～10⁹ Ω cm and a relative permittivity of 10.55. The electrical properties of the studied materials are governed by traps with activation energies of 0.13 and 0.19 eV and a density ranging from 9.5×10¹⁴ to 2.7×10¹⁵ cm^?3. The one-carrier injection is observed in weak electric fields. In electric fields with a strength of more than 4×10³ V/cm, traps undergo thermal field ionization according to the Pool-Frenkel mechanism. At low temperatures and strong fields (160 K and 5×10⁴ V/cm), the electric current is most likely due to hopping conduction by charge carriers over local levels in the band gap in the vicinity of the Fermi level.     

Stancu-Sikkema算子的点态估计

本文构造了Stancu—Sikkema算子,并利用点态光滑模研究了此算子的点态逼近正逆定理.     

Urea method for the synthesis of hydrotalcites

Mg-Al, Zn-Al and Ni-Al hydrotalcite-like compounds with high crystallinity were synthesized by using the decomposing property of urea at high temperature. The crystallinity and the regularly of the samples were much preferable to those synthesized by other methods. This revised version was published online in June 2006 with corrections to the Cover Date.     

单光子探测器量子效率的绝对自身标定方法

提出一种单光子探测器量子效率的绝对自身标定方案，利用光参量下转换过程中产生的光子对在时间上的相关性，先将参量光束分为两路，然后引入相对延时，使同时产生的孪生光子先后进入单光子探测器，然后将探测器之后的电路分为三路，其中一路直接进入计数器得到探测器所探测到的光子的总计数率，另两路用电路方法引入和光路相当的相对延时，经符合电路后进入计数器，得到前后到达探测器的光子对之间的符合计数率.这样，从符合计数率与总光子计数率之比即可在不需要任何其他探测器或者参照标准的情况下获得探测器的量子效率.文中给出两种方案，分别适     

Relaxor type perovskites: Primary candidates of nano-polar regions

Relaxor properties of 0.7Pb(Mg_1/3Nb_2/3)O₃-0.3PbTiO₃ (PMN-PT) and non-lead perovskite thin films have been analysed in terms of large frequency dispersion of dielectric response at low temperatures. A wide spectrum of dielectric relaxation was observed in the frequency-dependent response of the imaginary part of the dielectric permittivity. Transformation from normal ferroelectric to relaxor behaviour has been observed in the case of the Ca substituting the BaTiO₃ thin films. A number of techniques were exploited to investigate the wide spectrum of relaxation times in pulsed laser ablated thin films.ac anddc electric field induced complex dielectric properties of 0.7Pb(Mg_1/3Nb_2/3)O₃-0.3PbTiO₃ (PMN-PT) thin films were studied as function of frequencies at different temperatures. Nonlinear behaviour of dielectric susceptibility with respect to the amplitude of theac drive was observed at lower temperatures. The frequency dependence of transition temperatureT _m (temperature of the maximum of dielectric constant) was studied using the Vogel-Fulcher relation. Dedicated to Professor C N R Rao on his 70th birthday     

Gravitation as Anholonomy

A gravitational field can be seen as the anholonomy of the tetrad fields. This is more explicit in the teleparallel approach, in which the gravitational field-strength is the torsion of the ensuing Weitzenböck connection. In a tetrad frame, that torsion is just the anholonomy of that frame. The infinitely many tetrad fields taking the Lorentz metric into a given Riemannian metric differ by point-dependent Lorentz transformations. Inertial frames constitute a smaller infinity of them, differing by fixed-point Lorentz transformations. Holonomic tetrads take the Lorentz metric into itself, and correspond to Minkowski flat spacetime. An accelerated frame is necessarily anholonomic and sees the electromagnetic field strength with an additional term.     

Mechanism of formation of highly conductive layer on ZnO crystal surface

The mechanism of formation of a thin highly conductive layer, which is known to be present on ZnO surface, has been proposed. This process has been assumed to consist in accumulation of mobile shallow donors at crystal surface due to their drift in band-bending electric field caused by adsorbed oxygen. Experimental results that confirm this mechanism have been obtained.