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41.
Todora Ojkova Dimitar Barkov Anton Popov 《Monatshefte für Chemie / Chemical Monthly》2000,131(7):727-732
Zusammenfassung. Die Phasengleichgewichte in den Systemen Cs2SeO4-CoSeO4-H2O und Cs2SeO4-NiSeO4-H2O bei 25.0°C wurden untersucht. Dabei wurde die Entstehung zweier kongruent l?slicher Doppelsalze (Cs2Co(SeO4)2ċ6H2O und Cs2Ni(SeO4)2ċ6H2O) festgestellt, die mittels chemischer, thermogravimetrischer und r?ntgenographischer Methoden identifiziert wurden.
Investigation of the Phase Equilibria in the Systems Cs2SeO4-CoSeO4-H2Oand Cs2SeO4-NiSeO4-H2O at 25.0°C
Summary. Phase equilibria in the systems Cs2SeO4-CoSeO4-H2O and Cs2SeO4-NiSeO4-H2O at 25.0°C were studied. Two congruently soluble double salts (Cs2Co(SeO4)2ċ6H2O and Cs2Ni(SeO4)2ċ 6H2O) were found to be formed which were identified by chemical, thermogravimetrical, and X-ray phase analysis.
Received October 14, 1999. Accepted (revised) February 1, 2000 相似文献
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Dimitar Petrov 《Journal of mathematical chemistry》2014,52(7):1978-1983
The coefficients \(c_{k}\) (k = 2, 4, 6) that pertain to spin-correlated matrix elements of the tensor operator \({{\varvec{U}}}^{{\varvec{(k)}}}\) have been evaluated by means of the differences \({{\varvec{U}}}^{{\varvec{(k)}}}\) (intermediate) \(-\) \({{\varvec{U}}}^{{\varvec{(k)}}}\) (LS) and the reduced matrix elements of the operator \({{\varvec{V}}}^{{\varvec{(1k)}}}\) . Only spin-allowed transitions have been considered from each ground level to the excited energy levels within the \(4\hbox {f}^{2}\) and \(4\hbox {f}^{12}\) configurations of the free ions Pr (3+) and Tm (3+), respectively. The values of the coefficients \(c_{k}\) thus found correspond in most cases by sign and order of magnitude to those determined in other sources as corrections to lanthanide (3+) crystal-field parameters. 相似文献
45.
An accurate analysis of voice quality is imperative when using acoustic measurements to diagnose vocal pathologies. It is known that noise has a significant effect on the reliability and validity of acoustic voice measurements, but the precise relationship has not been established. The purpose of this study was to investigate the influence of noise on the accuracy, reliability, and validity of acoustic voice quality measurements while balancing for gender, age, intersubject and intrasubject variability, microphones, computer hardware, analysis software, and type of noise. Level of noise was precisely controlled. The specific focus of interest was to determine the critical levels of noise that can invalidate voice quality measurements and to generate practical recommendations. Results suggest that the recommended, acceptable, and unacceptable levels of noise in the acoustic environment are above 42 dB, above 30 dB, and below 30 dB signal-to-noise ratio, respectively. 相似文献
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Ivana Kuzminac Olivera R. Klisurić Dušan Škorić Dimitar Jakimov Marija Sakač 《Structural chemistry》2017,28(3):567-576
Starting from 3β-acetoxy-17a-homo-17-oxa-androst-5-en-16-one (1) and in the reaction with N-bromoacetamide (NBA) and perchloric acid, the 5α-bromo-6β-hydroxy (2), 5β,6β-epoxy (3) and 5α,6β-dibromo (4) derivatives were obtained. The structure of compounds 2–4, particularly stereochemistry at C5 and C6, is established by detailed NMR and X-ray analysis. The in vitro antiproliferative activity of newly synthesized compounds 2–4 against six human tumor cell lines was evaluated. All three compounds showed a significant toxicity toward hormone-independent breast adenocarcinoma MDA-MB-231 and cervical carcinoma cells HeLa, while dibromo derivative 4 was active toward five human cancer cell lines. These new 5,6-disubstituted-D-homolactone steroidal compounds have also displayed selectivity toward cancerous cell lines against inactivity found for noncancerous control cell line. This selectivity was not found for control compound, well-known chemotherapy drug cisplatin. 相似文献
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Stable poly{(vinyl acetate)‐co‐[3‐dimethyl(methacryloyloxyethyl)ammonium propanesulfonate]} latexes with different compositions were synthesized by emulsifier‐free emulsion copolymerization. An unusual “overshooting” behavior of the copolymer tablets is explained based on the formation of specific clusters of oppositely oriented dipoles. The variation of their concentration with the zwitterionic monomer unit fraction, ionic strength and temperature is responsible for the differences in the swelling kinetics established. The results show that these parameters can be used to control swelling degree of copolymer matrices and their sustained drug delivery.
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Maria M. Milanova Dimitar S. Todorovsky Christo C. Balarew Natalia L. Minkova Katya I. Ivanova 《Central European Journal of Chemistry》2007,5(1):13-19
The cocrystallization of Ce2(SO4)3 and La2(SO4)3 is studied in aqueous and H2SO4 (150 g/dm3) solutions at 25 °C and 64 °C. The effect of the formation of inner sphere sulfate complexes of the type LnSO
4
+
in determining the composition of the equilibrium phases is revealed.
相似文献