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101.
102.
Dietmar Vogt 《Mathematische Annalen》1972,196(4):281-292
Ohne Zusammenfassung 相似文献
103.
Dr. Hubert Tietz 《Mathematische Zeitschrift》1970,113(2):136-144
Ohne Zusammenfassung 相似文献
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Constituents of Osmanthus Absolute, Ist communication:2,5-Epoxy-megastigma-6,8-dienes Besides some further ionone derivatives we identified two new bicyclic oxacompounds ( 1a / 1b ) of the megastigmane type in the Osmanthus absolute. Isolation, special features of their spectral datas and synthesis starting from ethyl α-safranate are described. The synthetic pathway choosen allowed the additional identification of four substances occurring in the same natural substrate, because some synthetic by-products formed int he reaction sequence exhibited corresponding spectra and GLC. retention as the hitherto unknown components of the Osmanthus absolute. 相似文献
108.
Würthner F Stepanenko V Chen Z Saha-Möller CR Kocher N Stalke D 《The Journal of organic chemistry》2004,69(23):7933-7939
A detailed study on bromination and subsequent imidization of perylene bisanhydride with cyclohexylamine is reported. The present results reveal that previously reported 1,7-difunctionalized perylene bisimides are presumably contaminated with the respective 1,6 regioisomers. N,N'-Dicyclohexyl-1,7-dibromoperylene bisimide 1,7-3 is obtained for the first time in isomerically pure form, and its structure is unequivocally confirmed by X-ray analysis. By using regioisomerically pure 1,7-dibromoperylene bisimide 1,7-3, 1,7-dipyrrolidinylperylene bisimides 4a-c and 1,7-dipyrrolidinylperylene bisanhydride 5 as well as the unsymmetrically difunctionalized 1-bromo-7-pyrrolidinyl- and 1-cyano-7-pyrrolidinylperylene bisimides 7 and 8 are synthesized in good yield. 相似文献
109.
Evgueni Riaplov John P Maier Dietmar Panten Pavel Rosmus 《Journal of Molecular Spectroscopy》2003,222(1):15-21
Mass selected C2S− ions have been co-deposited with neon to grow a matrix at 6 K. The and electronic absorption spectra of the linear CCS− anion have been identified with origin band at 10 606 and 22 273 cm−1, respectively. After exposure to UV radiation a new electronic transition of CCS is observed (origin band at 30 563 cm−1) in addition to its known band system. Ab initio calculations provide support for the symmetry assignment of the upper electronic states of CCS−, CCS and of the vibrational structure in the spectra. 相似文献
110.
A. P. Nizovtsev S. Ya. Kilin F. Jelezko I. Popa A. Gruber C. Tietz J. Wrachtrup 《Optics and Spectroscopy》2003,94(6):848-858
The spin-selective photokinetics of a single matrix-isolated impurity molecule with a triplet-triplet optical transition, T 0–T 1, is considered and the manifestations of the photokinetics in the fluorescence excitation spectra and intensity autocorrelation functions g (2)(τ) of the molecule undergoing narrow-band optical excitation is studied to resolve the fine structure of the transition. The rates of intersystem crossings (ISCs) T 1→S→T 0 to and from a nonradiating singlet state S of the molecule and the rate of population relaxation among the ground (T 0) state sublevels can be obtained from the spectra and g (2)(τ) using the analytical expressions obtained. New experiments on an individual NV defect center in nanocrystals of diamond, where, for the first time, the fine structure of its triplet-triplet 3 A-3 E zero-phonon optical transition (~637 nm) at 1.4 K was resolved, are interpreted. It is concluded that the rate of the ISC transition from the m S =0 sublevel of the excited 3 E state to the singlet 1 A state (~1 kHz) is much slower than the rates from the m S =±1 substates, while the rates of ISC transitions to different m S substates of the ground 3 A state are close to each other (~1 Hz). As a result, only the optical transition between m S =0 sublevels in the 3 A-3 E manifold contributes strongly to the fluorescence. The experimentally observed double-exponential decay of the g (2)(τ) function is explained by the two pathways available to the center for it to leave the S state: (i) the S→ T 0(m S )=0) transition and (ii) the S→T 0(m S =±1) transitions followed by the slow spin-lattice relaxation T 0(m S =±1)→T 0(m S =0) (rate ~0.1 Hz). The work is important for studies where the NV center is used as a single photon source or for quantum information processing. 相似文献