全文获取类型
收费全文 | 1592篇 |
免费 | 76篇 |
国内免费 | 9篇 |
专业分类
化学 | 1079篇 |
晶体学 | 8篇 |
力学 | 35篇 |
数学 | 254篇 |
物理学 | 301篇 |
出版年
2024年 | 1篇 |
2023年 | 23篇 |
2022年 | 52篇 |
2021年 | 69篇 |
2020年 | 45篇 |
2019年 | 57篇 |
2018年 | 49篇 |
2017年 | 40篇 |
2016年 | 92篇 |
2015年 | 44篇 |
2014年 | 84篇 |
2013年 | 106篇 |
2012年 | 133篇 |
2011年 | 130篇 |
2010年 | 73篇 |
2009年 | 65篇 |
2008年 | 85篇 |
2007年 | 101篇 |
2006年 | 81篇 |
2005年 | 73篇 |
2004年 | 61篇 |
2003年 | 31篇 |
2002年 | 27篇 |
2001年 | 17篇 |
2000年 | 16篇 |
1999年 | 11篇 |
1998年 | 9篇 |
1997年 | 7篇 |
1996年 | 9篇 |
1995年 | 5篇 |
1994年 | 10篇 |
1993年 | 6篇 |
1992年 | 4篇 |
1991年 | 4篇 |
1990年 | 4篇 |
1989年 | 3篇 |
1988年 | 5篇 |
1987年 | 4篇 |
1986年 | 4篇 |
1985年 | 6篇 |
1984年 | 6篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1981年 | 3篇 |
1980年 | 5篇 |
1979年 | 1篇 |
1978年 | 1篇 |
1977年 | 4篇 |
1976年 | 2篇 |
1974年 | 1篇 |
排序方式: 共有1677条查询结果,搜索用时 156 毫秒
51.
Effect of methoxyl groups on the NMR spectra: configuration and conformation of natural and synthetic indanic and tetralinic structures
下载免费PDF全文
![点击此处可从《Magnetic resonance in chemistry : MRC》网站下载免费的PDF全文](/ch/ext_images/free.gif)
Beatriz Lantaño José M. Aguirre Eleonora V. Drago Diego J. de la Faba Nicolás Pomilio Jorge D. Mufato 《Magnetic resonance in chemistry : MRC》2017,55(7):619-633
Here, we studied the influence of the methoxyl groups attached at C‐7 and C‐2′ of natural and synthetic 1‐arylindanes on the chemical shift of the signal of bibenzylic hydrogen and carbon atoms and J1,2 coupling constants. This influence was also analysed in natural 1‐aryltetralins and related compounds that possess methoxyl and/or hydroxyl groups bound at C‐8 and C‐2′. The methoxyl groups attached at C‐7 in indanes or at C‐8 in tetralins produce a deshielding signal at H‐1 and shield at C‐1 and a strong decrease in the value of J1,2 due to the pseudoequatorial location adopted by the aryl group bound at C‐1, avoiding an ‘A1,3 strain’. Furthermore, compounds with hydroxyl or methoxyl groups in C‐2′, in the absence of substituents of C‐7 or C‐8, present a strong deshielding signal at H‐1, strong shield of the C‐1 signal and a decrease in the value of J1,2. This is attributed to the stereoelectronic effects of the methoxyl or hydroxyl groups, which we have called ‘Asarone effect’. NOESY experiments were conducted to confirm the configuration and conformation of some of the compounds included in this work. This study shows that both effects, A1,3 strain and Asarone effect, must be taken into account when the structure of natural indanes and tetralins is analysed by using 1H‐NMR and 13C‐NMR spectra. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
52.
Journal of High Energy Physics - For the homogeneous configuration given by the long string limit of the folded string with a spin in AdS 3 and a spin and a winding number in S 1, we solve the... 相似文献
53.
54.
55.
56.
We define the hyperbolic order of any locally injective holomorphic function between arbitrary hyperbolic domains of the complex plane and study the relation between the hyperbolic order and the Schwarzian derivative for locally injective holomorphic functions from the unit disk into itself. 相似文献
57.
58.
Diego Julio Cirilo-Lombardo 《Physics of Particles and Nuclei Letters》2017,14(6):874-881
In previous works [1, 2], the 2-dimensional charge transport with parallel (in plane) magnetic field was considered from the theoretical point of view showing explicitly that the specific form of the emergent equation enforces the respective field solution to fulfil the Majorana condition. In this paper we review, explain and analyze these important results in the context of the generated physical effects, namely, the quantum ring as spin filter, the quantum Hall effect and a new one of pure topological origin (as the described by the Aharonov–Casher theorems). The link with supersymmetrical models is briefly discussed. 相似文献
59.
60.
Marco Cespi Luca Casettari Giulia Bonacucina Gianfabio Giorgioni Diego R Perinelli Giovanni Filippo Palmieri 《先进技术聚合物》2013,24(11):1018-1024
This paper deals with a new application of diblock methoxy polyethylene glycol‐polylactide block copolymers, a class of synthetic biomaterials largely studied in the pharmaceutical and biomedical fields owing to their favorable properties such as biocompatibility, biodegradability, low immunogenicity, and good mechanical properties. In this work, these materials were evaluated as additives for gastro‐soluble pharmaceutical coating aimed to reduce film stiffness and water permeability. Two copolymers with different polylactide chain lengths were synthesized and characterized in term of molecular weight and solid‐state properties. A series of free films with different hypromellose/copolymers ratio were prepared and characterized in terms of appearance, components miscibility, plasticity, and water vapor permeability. The obtained results demonstrate that copolymers effectively influence hypromellose film properties according to their concentration and molecular weight. Specifically, the addition of the copolymer with a molecular weight of 6.5 kDa in a ratio hypromellose:polymer 5:1, allowed to obtain films with good appearance, improved plasticization, and water permeability properties. For higher molecular weight, copolymer or different ratios was not possible to observe the improvement of all the properties at the same time. The results also make possible to define the critical features to improve in order to use block copolymers as additive in hypromellose film coating. The availability of new water‐soluble additives able to work as plasticizer and moisture sealer in polymeric films represents an important progress not only in the field of pharmaceutical coating but also in that of food coatings, as for example in the formulation of edible films. Copyright © 2013 John Wiley & Sons, Ltd. 相似文献