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排序方式: 共有621条查询结果,搜索用时 0 毫秒
101.
102.
Lattice Boltzmann模型在CFD中应用 总被引:1,自引:0,他引:1
近年来,格子Boltzmann方法(LBM)已发展为一种模拟流体和物理问题的新颖的、有前景的数值方法,在许多领域的各种数值问题求解上取得很大的成功.文章介绍了一种模拟复杂流动的高效建模数值算法Lattice Boltzmann方法,和它的基本原理及其应用.并通过两个实例数值模拟计算,说明Lattice Boltzmann方法正确、有效,并展示了广阔的应用前景,为今后更深入的研究和广泛应用打下基础. 相似文献
103.
Stevens F Leach RN Langford SC Dickinson JT 《Langmuir : the ACS journal of surfaces and colloids》2006,22(7):3320-3325
We report observations of poly(methyl methacrylate) films modified by the synergistic effect of solvent exposure and mechanical stress applied by the tip of an atomic force microscope (AFM). We show that these modifications are sensitive to polymer molecular weight as well as solvent strength and the force applied by the tip. Small-area scanning often produces localized patches of raised material as well as depressed areas. The volume change associated with the depressed areas generally increases with increasing solvent strength, increasing applied normal force, and decreasing polymer molecular weight. In contrast, the volume change associated with the raised patches is greatest for 25-145K Mw films in 60 and 100% ethanol solutions. In each case, the normal force applied by the AFM tip must exceed a threshold to significantly modify the surface; this threshold is associated with an increase in lateral force applied by the AFM tip during small-area scanning. We attribute the raised patches to mechanically enhanced swelling due to diffusion of solvent into near-surface material. Permanent net volume loss, when observed, is attributed to localized polymer dissolution. 相似文献
104.
Let l be a given nonzero integer.The authors give an explicit characterization of the positive integer k that makes the Diophantine equation x2-kxy+y2+lx=0 have infinitely many positive integer solutions(x,y). 相似文献
105.
FTIR光谱仪中基于定镜调整的动镜运动控制研究 总被引:1,自引:0,他引:1
动镜是FTIR光谱仪中唯一不断运动的部件,动镜的匀速运动性能以及动镜与定镜的准直性好坏影响干涉效果和光谱图质量,直接制约着仪器的精度和分辨率,对仪器整体指标起着重要作用。文章围绕FTIR光谱仪中干涉仪动镜运动的匀速性以及其与定镜的准直性展开研究,使用相位检测技术对定镜的姿态作出动态调整以补偿动镜与定镜间的倾斜夹角,并且设计了具有磁悬浮特点的动镜支撑系统。文章采用改进的模糊PID控制算法实现动镜运动速度的精确调节,对该控制方案从硬件设计和算法上实现。结果表明所研发的动镜运动控制系统具有足够的精度和实时性,能够保证FTIR光谱仪中干涉仪所需的准直性及动镜匀速性的要求。 相似文献
106.
107.
A highly efficient and reproducible approach for effective Pt nanoparticles dispersion and excellent decoration (inside/outside) of functionalised carbon nanofibers (f-CNF) is presented. The surface morphological, compositional and structural characterisations of the synthesised Pt(19.2)/f-CNF(80.8) material were examined using transmission electron microscopy (TEM/STEM/DF-STEM), energy-dispersive X-ray spectrometry (EDS), thermogravimetric analysis (TGA/DTG), X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS). Cyclic voltammetry (CV) was employed in order to confirm the typical electrochemical response for Pt. The aim of the work was to improve the utility of both the supporting matrix (via the use of both inner/outer surfaces of nanofibers) and precious Pt, together with the sensitive glucose determination. TEM data indicated successful nanoparticle decoration with average Pt particle size 2.4 nm. The studies demonstrated that utilisation of the inner surface of the nanofibers, together with the modified outer surface characteristics using chemical treatment, enables excellent decoration, effective dispersion and efficient impregnation of Pt nanoparticles on carbon nanofibers. Pt(19.2)/f-CNF(80.8) exhibited excellent amperometric response (sensitivity = 22.7 μAmM(-1)cm(-2) and LoD = 0.42 μM) towards direct glucose sensing, over the range 0-10 mM glucose, in neutral conditions (pH 7.4). The improved carbon surface area for nanoparticle decoration, inner surface structure and morphology of nanofibers together with the presence of functional groups provided strong interactions and stability. These features together with the effective nanoparticle dispersion and decoration resulted in excellent catalytic response. The decorated nanoscaled material (Pt(19.2)/f-CNF(80.8)) is capable of large scale production, providing sensing capability in neutral conditions, while eliminating the temperature sensitivity, pH and lifetime issues associated with glucose enzymatic sensors and holds great promise in the quantification of glucose in real clinical samples. 相似文献
108.
In this article it is proved that there exist a large number of polynomials which have small discriminant in terms of the
Euclidean and p-adic metrics simultaneously. The measure of the set of points which satisfy certain polynomial and derivative conditions
is also determined. 相似文献
109.
F.X. Gadéa T. Leininger A.S. Dickinson 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2001,15(2):251-255
An improved ab initio calculation has been performed for the potential for the LiH a 3Σ+ state, using two very large basis sets. The Basis Set Superposition Error (BSSE) correction has been determined for both
basis sets and the non-Born-Oppenheimer correction estimated to be negligible. The best potential is approximately 10% deeper
than the previous estimate. Vibrational energies and scattering lengths have been calculated for 6,7LiH(D) with both potentials, with and without the BSSE correction, and also with an estimated potential expected to bracket
the true potential. The 7LiH scattering length is estimated to be (45 ± 4)a0 and hence the low-energy cross-section in the best a 3Σ+ potential is about half that calculated previously. Enhanced cooling by 7Li of trapped H atoms remains feasible.
Received 30 April 2001 相似文献
110.
γ-Al2O3负载Cr促进SO2-4/ZrO2固体超强酸研究 总被引:16,自引:0,他引:16
将Cr促进的SO^2-4/ZrO2(SZ)固体超强酸Cr-SZ负载于γ-Al2O3载体上,制成Cr-SZ/Al2O3系列固体超强酸,利用探针反应考察了其超强酸性,中强酸性和弱酸性的变化情况,详细研究了样品的比表面、硫含量、ZrO2晶化情况及正丁烷低温异构化反应活性,结果发现,负载后部分Cr-SZ的正丁烷低温异构化反应活性显著提高,含铬样品酸强度和脱氢性能的增强对其正丁烷异构化反应活性的提高均有贡献,样品酸性和脱氢性之间的合适匹配使Cr-SZ/Al2O3显示出很高的正丁烷异构化反应活性。 相似文献