铯原子气室中相干布居俘获的参数依赖关系研究

基于铯原子基态6S_1/2的两个超精细能级（F=3与F=4）与激发态6P_3/2的超精细能级（F′=4）构成的Λ型三能级系统,采用室温下的未充缓冲气体和充有分压为266.6 Pa的氖气作为缓冲气体的铯原子气室对于相干布居俘获（CPT）的参数依赖关系进行了实验研究和理论分析.主要研究了CPT信号的半高全宽和幅度对于频率差为铯原子基态6S_1/2的超精细分裂（9.19263177 GHz）且位相锁定的两激光束的功率、光强比值、光斑直径、磁屏蔽之后的剩余磁场以及是否充缓冲气体等实验参数的依赖关系.在优化的实验参数条件下获得了约340 Hz的CPT信号半高全宽.     

Widely and continuously tunable optical parametric generator infrared laser

The experimental results of a high efficiency infrared laser are demonstrated on a quasi phase matched optical parametric generator in PPMgLN (5% MgO doping) pumped by a 1064 nm Nd:YAG laser. A broad continuous signal spectrum 1.56?C1.67 ??m are obtained by tuning the crystal temperature from 20°C to 200°C. When the average pump power is 1.82 W with about 70 ns pulse duration operating at a repetition rate of 10 kHz, the maximum total output power of the PPMgLN OPG is about 323.58 mW consisting of 210 mW of 1.639 ??m signal radiation and 113.58 mW of 3.02 ??m idler radiation.     

Investigation of a Negative Step Effect on Stilling Basin by Using CFD

The negative-step stilling basin is an efficient and safe energy dissipator for high-head, large-unit discharge high-dam projects. However, studies of the effects of the negative step on the hydraulic performance of a high-dam stilling basin have not been conclusive. In the present study, a 2D RANS-VOF numerical model was developed to simulate the flow field of a negative-step stilling basin. The numerical model was validated with a physical model and then used to simulate and test the performance of the negative-step stilling basin with different step heights and incident angles. The results showed that the flow pattern, the free-surface profile, the velocity profile, the characteristic lengths are strongly influenced by the step geometry. Increasing the height of the step will increase the relative flow depth and the reattachment length in the basin, but reduce the bottom velocity and the roller length. The incident angle has no significant influence on the flow pattern of the negative-step stilling basin, and increasing the incident angle of the step will reduce the bottom velocity and the reattachment length. Both the step height and the incident angle have no significant influence on the energy dissipation efficiency because of the high submergence conditions in this study.     

原位制备SrSb2O6/g-C3N4新型二维异质结用于可见光催化降解四环素的研究

本文采用高温固相原位制备新型二维SrSb2O6/g-C3N4异质结光催化复合材料,并将其用于可见光催化降解四环素.通过XRD和FT-IR谱对其结构进行表征.光催化降解实验表明,异质结复合材料较母体g-C3N4和SrSb2O6而言,光催化效率均得到了提升.其中,异质结样品SSO-CN-2对四环素溶液具有最优的光催化降解效...     

Rapid Identification of Wild Gentiana Genus in Different Geographical Locations Based on FT-IR and an Improved Neural Network Structure Double-Net

Gentiana Genus, a herb mainly distributed in Asia and Europe, has been used to treat the damp heat disease of the liver for over 2000 years in China. Previous studies have shown significant differences in the compositional contents of wild Gentiana Genus samples from different geographical origins. Therefore, the traceable geographic locations of the wild Gentiana Genus samples are essential to ensure practical medicinal value. Over the last few years, the developments in chemometrics have facilitated the analysis of the composition of medicinal herbs via spectroscopy. Notably, FT-IR spectroscopy is widely used because of its benefit of allowing rapid, nondestructive measurements. In this paper, we collected wild Gentiana Genus samples from seven different provinces (222 samples in total). Twenty-one different FT-IR spectral pre-processing methods that were used in our experiments. Meanwhile, we also designed a neural network, Double-Net, to predict the geographical locations of wild Gentiana Genus plants via FT-IR spectroscopy. The experiments showed that the accuracy of the neural network structure Double-Net we designed can reach 100%, and the F1_score can reach 1.0.     

ZnF2-Riched Inorganic/Organic Hybrid SEI: in situ-Chemical Construction and Performance-Improving Mechanism for Aqueous Zinc-ion Batteries

Uncontrolled dendrites growth and serious parasitic reactions in aqueous electrolytes, greatly hinder the practical application of aqueous zinc-ion battery. On the basis of in situ-chemical construction and performance-improving mechanism, multifunctional fluoroethylene carbonate (FEC) is introduced into aqueous electrolyte to construct a high-quality and ZnF₂-riched inorganic/organic hybrid SEI (ZHS) layer on Zn metal anode (ZMA) surface. Notably, FEC additive can regulate the solvated structure of Zn²⁺ to reduce H₂O molecules reactivity. Additionally, the ZHS layer with strong Zn²⁺ affinity can avoid dendrites formation and hinder the direct contact between the electrolyte and anode. Therefore, the dendrites growth, Zn corrosion, and H₂ evolution reaction on ZMA in FEC-included ZnSO₄ electrolyte are highly suppressed. Thus, ZMA in such electrolyte realize a long cycle life over 1000 h and deliver a stable coulombic efficiency of 99.1 % after 500 cycles.     

Detachable Porous Organic Polymers Responsive to Light and Heat

Stimuli-responsive porous materials have captured much attention due to the on-demand tunable properties. Most reported stimuli-responsive porous materials are based on molecule isomerism or host-guest interaction, and it is highly desired to develop new types based on different responsive mechanism. Herein, inspired by natural cells which have the ability to fuse and divide induced by external stimulation, we report a new type of stimuli-responsive porous material based on detachment mechanism. A detachable porous organic polymer, namely DT-POP-1, is fabricated from the polymerization of anthracene-containing monomer (AnMon) when irradiated by 365 nm UV light. DT-POP-1 can detach into the monomer AnMon when irradiated with 275 nm UV light or heat. Such polymerization/detachment is reversible. The detachment results in a big difference in porosity and adsorption capacity, making the present detachable porous polymer highly promising in adsorptive separation and drug delivery.