激发态卟啉衍生物研究(Ⅶ)——取代基对卟啉—硝基苯化合物发光特性的影响

本文报导共价链相连的X-P-Y“三合板”型化合物在二甲基甲酰胺(DMF)和苯溶液中的发光特性.结果发现:引入取代基X=Cl—,CH3O—和Y=苯、硝基苯对中心卟啉的吸收和荧光光谱均无明显影响,仅其峰值频率将因溶剂不同而有所偏移.此外,由Cl—取代的卟啉—苯的荧光强度总比CH3O—取代时高;若将Y取代基由苯改换为硝基苯时,将使CH3O—P—Y化合物的荧光增强,但在Cl—P—Y化合物中则出现相反的趋势.不论在何种化合物中,在Y取代基中的苯环上引入NO2—基后,均可使其消光系数减小,而且当硝基在邻位取代时,这一效应更为显著.所有这些变化规律均不因溶剂不同而异.如果我们认为X—P—Y化合物的发光强度变化和其中心的卟啉大环上的π电子云密度偏移有规律性的关联,那么上述的一些取代基效应是可以理解的.进而,我们认为:本文所报导的事实将有助于充实巧妙设计高效利用太阳能的分子体系的科学依据.     

Multi-quark structure ofU(3.1)

We interpret the recently observedU(3.1) mesons with the \(\Lambda \bar p\) + pions decays as the bound state of \(\Lambda ,\bar p\) andX ₀(1480). TheX ₀(1480) is a mesonium with \(Q^2 \bar Q^2 \) structures observed in γγ reactions and \(\bar pn\) annihilations. With this interpretation, we can understand its decay modes. Furthermore, we predict the ratio of \(\sigma (\Lambda \bar p\pi ^ + \pi ^ - )/\sigma (\Lambda \bar p\pi ^ + \pi ^ + )\) to be ?3.1 for centrally produced events and that the width of \(U^ - (\Lambda \bar p\pi ^ + \pi ^ - )\) to be greater than that of \(U^ + (\Lambda \bar p\pi ^ + \pi ^ + )\) . Both predictions seem to be in reasonable accord with the available data. We call for the detection of the \(\Lambda \bar p\pi ^ - \pi ^ - \) mode to verify the present interpretation.