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31.
By the promotion of benzotriazole (20 mol %), two molecules of anilines (or other arylamines) and two molecules of phenylacetaldehyde (or o-bromophenylacetaldehyde) condensed to give a series of 1,2,3,4-tetrahydroquinolines in a stereoselective manner. By the catalysis of SmI(2) or SmI(3), the N-(alpha-aminoalkyl)benzotriazoles derived from anilines and (R)-glyceraldehyde acetonide dissociated to the corresponding iminium and enamine species, which underwent asymmetric [4 + 2] cycloadditions to give optically active tetrahydroquinolines. 相似文献
32.
B. Talukdar 《Physics letters. A》1980,80(5-6):365-366
The variable phase approach to potential scattering is regarded as an embedding technique. Algorithms are presented for studying the spatial behaviour of off-shell T matrices. 相似文献
33.
34.
A comprehensive study on the use of metal-arene systems as organic reductants for TiCl(3) has resulted in an efficient method for the generation of highly reactive low-valent titanium (LVT) reagents. The activated titanium species could be prepared by refluxing a mixture of substoichiometric amounts of arenes, TiCl(3), and Li/Mg in THF or DME. Among the LVT reagents screened, TiCl(3)--Li--naphthalene--THF (reagent I) was the best for coupling of carbonyls to olefins. The reagent could carry out the McMurry olefination of both aromatic and aliphatic substrates at a lower temperature and in a much reduced time as compared to the conventional procedures. Subtle changes in the method of preparation of the LVT reagents influenced the stereoisomeric ratio of the olefins. The reagent was also useful for the synthesis of O- and N- heterocycles and vicinal diamines via intramolecular carbonyl coupling and reductive duplication of imines, respectively. 相似文献
35.
B. Talukdar S. Ghosh J. Shamanna P. Sarkar 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2002,21(1):105-108
It is shown that the usual Hamilton's variational principle supplemented by the methodology of the integer-programming problem
can be used to construct expressions for the Lagrangian densities of higher KdV fields. This is demonstrated with special
emphasis on the second and third members of the hierarchy. However, the method is general enough for applications to equations
of any order. The expressions for Lagrangian densities are used to calculate results for Hamiltonian densities that characterize
Zakharov-Faddeev-Gardner equation.
Received 27 January 2002 / Received in final form 6 May 2002 Published online 24 September 2002 相似文献
36.
Feierabend KJ Zhu L Talukdar RK Burkholder JB 《The journal of physical chemistry. A》2008,112(1):73-82
Rate coefficients, k1(T), over the temperature range of 210-390 K are reported for the gas-phase reaction OH + HC(O)C(O)H (glyoxal) --> products at pressures between 45 and 300 Torr (He, N2). Rate coefficients were determined under pseudo-first-order conditions in OH using pulsed laser photolysis production of OH radicals coupled with OH detection by laser-induced fluorescence. The rate coefficients obtained were independent of pressure and bath gas. The room-temperature rate coefficient, k1(296 K), was determined to be (9.15 +/- 0.8) x 10-12 cm3 molecule-1 s-1. k1(T) shows a negative temperature dependence with a slight deviation from Arrhenius behavior that is reproduced over the temperature range included in this study by k1(T) = [(6.6 +/- 0.6) x 10-18]T2[exp([820 +/- 30]/T)] cm3 molecule-1 s-1. For atmospheric modeling purposes, a fit to an Arrhenius expression over the temperature range included in this study that is most relevant to the atmosphere, 210-296 K, yields k1(T) = (2.8 +/- 0.7) x 10-12 exp[(340 +/- 50)/T] cm3 molecule-1 s-1 and reproduces the rate coefficient data very well. The quoted uncertainties in k1(T) are at the 95% confidence level (2sigma) and include estimated systematic errors. Comparison of the present results with the single previous determination of k1(296 K) and a discussion of the reaction mechanism and non-Arrhenius temperature dependence are presented. 相似文献
37.
Dhrubajyoti Das Gopinadhanpillai Gopakumar C. V. S. Brahmmananda Rao N. Sivaraman Akella Sivaramakrishna 《Journal of Coordination Chemistry》2017,70(19):3338-3352
Extraction behavior of some selected actinides like U(VI), Th(IV), and Am(III) was investigated with three different H-phosphine oxides, viz. diphenyl hydrogen phosphine oxide (DPhPO), dihexyl hydrogen phosphine oxide (DHePO) and diphenyl phosphite (DPP). The H-phosphine oxides exhibited a dual nature towards the extraction of actinides where the ligand not only extracts the metals by cation exchange but also by coordination with the phosphoryl group at lower and higher acidic concentrations, respectively. Among all ligands employed, DPhPO showed highest extraction with actinides with a substituent dependent trend as follows: DPhPO > DHePO > DPP. This trend emphasizes the importance of substituents around the phosphine oxide towards their extraction of actinides. The coordination behavior of DPhPO was studied by investigating its corresponding complexes with Th(NO3)4 and UO2(NO3)2. The metal complexes of these actinides were characterized using FT-IR, 1H and 31P NMR spectroscopic techniques. Density Functional Theory (DFT) calculations were also performed to understand the electronic and geometric structure of the ligand and the corresponding metal complexes. 相似文献
38.
Trimodal Control of Ion‐Transport Activity on Cyclo‐oligo‐(1→6)‐β‐D‐glucosamine‐Based Artificial Ion‐Transport Systems
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Arundhati Roy Tanmoy Saha Dr. Marina L. Gening Dr. Denis V. Titov Dr. Alexey G. Gerbst Dr. Yury E. Tsvetkov Prof. Nikolay E. Nifantiev Dr. Pinaki Talukdar 《Chemistry (Weinheim an der Bergstrasse, Germany)》2015,21(48):17445-17452
Cyclo‐oligo‐(1→6)‐β‐D ‐glucosamines functionalized with hydrophobic tails are reported as a new class of transmembrane ion‐transport system. These macrocycles with hydrophilic cavities were introduced as an alternative to cyclodextrins, which are supramolecular systems with hydrophobic cavities. The transport activities of these glycoconjugates were manipulated by altering the oligomericity of the macrocycles, as well as the length and number of attached tails. Hydrophobic tails of 3 different sizes were synthesized and coupled with each glucosamine scaffold through the amide linkage to obtain 18 derivatives. The ion‐transport activity increased from di‐ to tetrameric glucosamine macrocycles, but decreased further when flexible pentameric glucosamine was introduced. The ion‐transport activity also increased with increasing length of attached linkers. For a fixed length of linkers, the transport activity decreased when the number of such tails was reduced. All glycoconjugates displayed a uniform anion‐selectivity sequence: Cl?>Br?>I?. From theoretical studies, hydrogen bonding between the macrocycle backbone and the anion bridged through water molecules was observed. 相似文献
39.
Raj Kiran Karthik Pandey R. N. Singh Bhupinder Talukdar A. 《Journal of Radioanalytical and Nuclear Chemistry》2019,322(2):655-662
Journal of Radioanalytical and Nuclear Chemistry - Fifty diverse soybean genotypes were screened for their ability to tolerate iron deficiency stress in a hydroponics experiment with low iron... 相似文献
40.
A metallic fishnet metamaterial structure in sub-THz region is presented. The proposed structure is based on hexagonal resonators. Simulations have been performed by a 3D full-wave electromagnetic simulator and a negative refractive index has been observed at the frequency range between 0.55 and 0.70 THz with the help of the graphene layer. In order to observe the effect of the graphene layer, the metamaterial structure has been simulated and examined before and after graphene integration. Significant modification in the propagation properties has been observed after the graphene integration. Change in S-parameters with the size variation of hexagonal resonators and alteration in graphene thickness are also presented as a parametric study to show the tunability of the structure. Suitability of the metamaterial for sensor applications has been investigated. The proposed metamaterial structure is promising to be effectively used for tunability and sensor applications. 相似文献