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排序方式: 共有93条查询结果,搜索用时 97 毫秒
71.
72.
Shinde Vikas Mahulikar Pramod Mhaske Pravin C. Nawale Laxman Sarkar Dhiman 《Research on Chemical Intermediates》2018,44(2):1247-1260
Research on Chemical Intermediates - A series of 2-aryl-4-((4-aryl-1H-1,2,3-triazol-1-yl)methyl)thiazole derivatives (8a–p) have been synthesized. The structure of the newly synthesized... 相似文献
73.
Reactions of alpha-hydroxyalkyl radicals with 3,5-pyridinedicarboxylic acid (3,5-PDCA) and nicotinic acid (NA) were studied at appropriate pHs in aqueous solutions by pulse radiolysis technique. At pH 1, CH(3)C*HOH and *CH(2)OH radicals were found to react with 3,5-PDCA by rate constants of 2.2 x 10(9) and 5.1 x 10(8) dm(3) mol(-1) s(-1), respectively, giving radical adduct species. The adduct species formed in the reaction of CH(3)C*HOH radicals with 3,5-PDCA underwent unimolecular decay (k = 9.8 x 10(4) s(-1)) giving pyridinyl radicals. Reaction of (CH(3))(2)C*OH, CH(3)C*HOH, and *CH(2)OH radicals with NA at pH 3.3 gave the adduct species which subsequently decayed to the pyridinyl radicals. At pH 1, wherein NA is present in the protonated form, (CH(3))(2)C*OH radicals directly transfer electrons to NA, whereas CH(3)C*HOH and *CH(2)OH radicals react with higher rate constants compared with those at pH 3.3, initially giving the adduct species which subsequently undergo elimination reaction giving pyridinyl radicals. Reactions of alpha-hydroxyalkyl radicals with 3,5-pyridinedicarboxylic acid and nicotinic acid are found to proceed by an addition-elimination pathway that provides one of the few examples of organic inner sphere electron-transfer reactions. Rate constant for the addition reaction as well as rate of elimination varies with the reduction potential of alpha-hydroxyalkyl radicals. 相似文献
74.
MVN Murthy Urjit A Yajnik KRS Balaji G Bhattacharyya Amol Dighe Shashikant Dugad ND Hari Dass PK Kabir Kamales Kar D Indumathi John G Learned Debasish Majumdar NK Mondal MVN Murthy SN Nayak Sandip Pakvasa Amitava Raychaudhuri RS Raghavan G Rajasekaran R Ramachandran Alak K Ray Asim K Ray Saurabh Rindani HS Sharatchandra Rahul Sinha Nita Sinha S Umasankar Urjit A Yajnik 《Pramana》2000,55(1-2):347-355
We have identified some important and worthwhile physics opportunities with a possible neutrino detector located in India.
Particular emphasis is placed on the geographical advantage with a stress on the complimentary aspects with respect to other
neutrino detectors already in operation. 相似文献
75.
Shikha Dhiman Teodora Andrian Beatriz Santiago Gonzalez Marrit M. E. Tholen Yuyang Wang Lorenzo Albertazzi 《Chemical science》2022,13(8):2152
The characterization of newly synthesized materials is a cornerstone of all chemistry and nanotechnology laboratories. For this purpose, a wide array of analytical techniques have been standardized and are used routinely by laboratories across the globe. With these methods we can understand the structure, dynamics and function of novel molecular architectures and their relations with the desired performance, guiding the development of the next generation of materials. Moreover, one of the challenges in materials chemistry is the lack of reproducibility due to improper publishing of the sample preparation protocol. In this context, the recent adoption of the reporting standard MIRIBEL (Minimum Information Reporting in Bio–Nano Experimental Literature) for material characterization and details of experimental protocols aims to provide complete, reproducible and reliable sample preparation for the scientific community. Thus, MIRIBEL should be immediately adopted in publications by scientific journals to overcome this challenge. Besides current standard spectroscopy and microscopy techniques, there is a constant development of novel technologies that aim to help chemists unveil the structure of complex materials. Among them super-resolution microscopy (SRM), an optical technique that bypasses the diffraction limit of light, has facilitated the study of synthetic materials with multicolor ability and minimal invasiveness at nanometric resolution. Although still in its infancy, the potential of SRM to unveil the structure, dynamics and function of complex synthetic architectures has been highlighted in pioneering reports during the last few years. Currently, SRM is a sophisticated technique with many challenges in sample preparation, data analysis, environmental control and automation, and moreover the instrumentation is still expensive. Therefore, SRM is currently limited to expert users and is not implemented in characterization routines. This perspective discusses the potential of SRM to transition from a niche technique to a standard routine method for material characterization. We propose a roadmap for the necessary developments required for this purpose based on a collaborative effort from scientists and engineers across disciplines.SRM, an advanced nanoscopy technique demands a transition from being a niche sophisticated technique to standard routine method for material characterization. The roadmap of necessary developments through multidisciplinary collaboration is discussed. 相似文献
76.
Hishikar Prafull Dhiman S. K. Tiwari Anil Kumar Gaba Vivek Kumar 《Journal of Thermal Analysis and Calorimetry》2022,147(10):5549-5574
Journal of Thermal Analysis and Calorimetry - The present study reviews the physical attributes of the fluid behaviour in the flow regimes of steady cross-flow around two infinite circular... 相似文献
77.
Sanam Pudasaini A T K Perera Dhiman Das Sum Huan Ng Chun Yang 《Electrophoresis》2019,40(18-19):2522-2529
Electroporation is a powerful tool for inactivating cells and transfecting biological cells and has applications in biology, genetic engineering, medicine, environment, and many others. We report a new continuous flow device embedded with insulating micropillars to achieve better performance of cell inactivation. The use of micropillars creates multiple electroporation zones with enhanced local electric field strengths. Using a model solution of Saccharomyces cerevisiae, we examined the inactivation performance of the device under various applied electric voltages and flow rates. Results from the numerical simulations and experiments showed that even with an induced transmembrane potential of 0.58 V, close to 63% of cell inactivation was achieved at a flow rate of 2.5 mL/h. This was higher than the 24% cell inactivation observed for a reference device without micropillars that was subjected to the same conditions. 相似文献
78.
79.
Fabrício RS Pereira Andréa Alessio Maurício S Sercheli Tatiane Pedro Elizabeth Bilevicius Jane M Rondina Helka FB Ozelo Gabriela Castellano Roberto JM Covolan Benito P Damasceno Fernando Cendes 《BMC neuroscience》2010,11(1):1-13
Background
Recent studies have shown that the human right-hemispheric auditory cortex is particularly sensitive to reduction in sound quality, with an increase in distortion resulting in an amplification of the auditory N1m response measured in the magnetoencephalography (MEG). Here, we examined whether this sensitivity is specific to the processing of acoustic properties of speech or whether it can be observed also in the processing of sounds with a simple spectral structure. We degraded speech stimuli (vowel /a/), complex non-speech stimuli (a composite of five sinusoidals), and sinusoidal tones by decreasing the amplitude resolution of the signal waveform. The amplitude resolution was impoverished by reducing the number of bits to represent the signal samples. Auditory evoked magnetic fields (AEFs) were measured in the left and right hemisphere of sixteen healthy subjects.Results
We found that the AEF amplitudes increased significantly with stimulus distortion for all stimulus types, which indicates that the right-hemispheric N1m sensitivity is not related exclusively to degradation of acoustic properties of speech. In addition, the P1m and P2m responses were amplified with increasing distortion similarly in both hemispheres. The AEF latencies were not systematically affected by the distortion.Conclusions
We propose that the increased activity of AEFs reflects cortical processing of acoustic properties common to both speech and non-speech stimuli. More specifically, the enhancement is most likely caused by spectral changes brought about by the decrease of amplitude resolution, in particular the introduction of periodic, signal-dependent distortion to the original sound. Converging evidence suggests that the observed AEF amplification could reflect cortical sensitivity to periodic sounds. 相似文献80.
K. Prashanthi B.A. Chalke K.C. Barick A. Das I. Dhiman V.R. Palkar 《Solid State Communications》2009,149(5-6):188-191
La doping at Bi Site in multiferroic BiFeO3 (BFO) is known to stabilize the ferroelectric perovskite phase and reduce the leakage current. It has been observed that in Dy modified BFO sample, La is not required for the said reason. In fact, the removal of La from Dy modified BFO system leads to the reduction in leakage current. Moreover, the magnetic properties are enhanced by order of magnitude in the absence of La in the system. Remarkably, a similar trend in properties has been also observed in thin films grown on Pt/TiO2/SiO2/Si substrate by using the pulsed laser deposition technique. This significant variation in the properties after removal of La from the system could be attributed to the change in lattice parameters, bond lengths and Fe–O–Fe bond angle as determined by powder x-ray and neutron diffraction study. 相似文献