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991.
采用直接共聚法合成表面含有乙烯基的具有立方相Ia3d结构的介孔硅分子筛(V-ClMS),然后对乙烯基团进行环氧化制备得到表面环氧基功能化的介孔硅分子筛(E-CIMS),采用X射线衍射、N2吸附-脱附、透射电镜、热重分析和13C固体核磁共振对制备的介孔硅分子筛进行了表征.结果表明,表面含有乙烯基的V-ClMS介孔硅分子筛能被一步成功合成,并易于发生环氧化而获得表面环氧基功能化的E-CIMS介孔硅分子筛.将E-CIMS介孔硅分子筛作为载体用于固定化青霉素G酰化酶(PGA),研究了表面环氧基团对固定化PGA初活性和操作稳定性的影响.结果表明,随着表面环氧基团数量的增加,介孔硅分子筛孔径减小,表面疏水性增加,导致载酶量和初活性减小.但介孔硅分子筛表面适量的环氧基团能增强E-CIMS介孔硅分子筛与PGA之间的相互作用,从而提高固定化PGA的操作稳定性. 相似文献
992.
Shi-Ping Zhan Xing Huang Qi-Cheng Zhao Li Chen Wei-Min Hou Song Zhang 《高分子科学杂志,A辑:纯化学与应用化学》2013,50(10):1070-1074
Dispersion polymerization of lactides and lactones has been studied and has received a great deal of attention used to prepare biodegradable polymers in supercritical carbon dioxide (ScCO2). The triblock copolymers of poly(?-caprolactone) PCL-polydimethylsiloxane (PDMS)-poly(?-caprolactone) PCL by the feed ratio of 1:2:1 and 1:3:1, respectively were synthesized to be used as the stabilizers in the dispersion polymerization of L-lactide. The fine poly(L-lactide) (PLLA) powders were obtained at the concentrations of 3% to 5%w/w (stabilizer/monomer). The results demonstrated that the triblock copolymers were the effective stabilizers for the dispersion polymerization of L-lactide. It was also found that the cooling process had a significant effect on the particle size of the fine powders. In order to obtain the best PLLA powders, it would be necessary to use the cooling process with stirring. 相似文献
993.
994.
Coupled atomic-molecular condensates in a double-well potential: decaying molecular oscillations 总被引:1,自引:0,他引:1
H. Jing S. Gu M. Zhan 《The European Physical Journal D - Atomic, Molecular, Optical and Plasma Physics》2006,39(2):271-275
We present a four-mode model that describes coherent
photo-association (PA) in a double-well Bose-Einstein condensate,
focusing on the average molecular populations in certain
parameters. Our numerical results predict an interesting
strong-damping effect of molecular oscillations by controlling the
particle tunnellings and PA light strength, which may provide a
promising way for creating a stable molecular condensate via
coherent PA in a magnetic double-well potential. 相似文献
995.
996.
Xiaoyun Liu Guozhu Zhan Yingfeng Yu Shanjun Li 《Journal of Polymer Science.Polymer Physics》2006,44(21):3102-3108
The structural transition in the polyethersulfone (PES)‐modified bismaleimide resin, 4,4′‐bismaleimidodiphenylmethane (BDM), during isothermal curing was studied by using rheological technique, different scanning calorimetry (DSC), and time resolved light scattering (TRLS). Comparing with the cure of neat bismaleimide, two separate tan δ crossover points were observed because of the phase separation during curing the blends of PES/BDM. These two structural transitions stemmed from the fixing of phase structure of the system and the chemical crosslinking of bismaleimide, respectively. The effect of curing temperature and the PES content on structural transition was discussed and found that the occurrence of two structural transition exhibited the different dependency of curing temperature and PES content. The relaxation exponent n and gel strength S were also found to be temperature‐dependent and composition‐dependent. Moreover, the relaxation exponent n of the second structural transition is much lower than that of the first structural transition in the PES/bismaleimide blends. © 2006 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 44: 3102–3108, 2006 相似文献
997.
998.
We study the optimal control of an assembly system that produces one assembled-to-order final product with multiple made-to-stock components and sells it at variable price. It is shown that a threshold control on component production, product price, and product orders maximizes total discounted profit over an infinite horizon. 相似文献
999.
Based on geometry picture of gravitational gauge theory, the cosmological constant is determined theoreti-cally. The cosmological constant is related to the average energy density of gravitational gauge field. Because the energydensity of gravitational gauge field is negative, the cosmological constant is positive, which generates repulsive force onstars to make the expansion rate of the Universe accelerated. A rough estimation of it gives out its magnitude of theorder of about 10-52m-2, which is well consistent with experimental results. 相似文献
1000.
酞菁锌掺杂二氧化硅凝胶基质的光谱学特征 总被引:1,自引:1,他引:0
利用溶胶凝胶技术将四磺化酞菁锌 (ZnPcS4)成功地引入到了二氧化硅凝胶基质中 ,制备了均匀掺杂的有机 /无机复合干凝胶。研究ZnPcS4分子在溶胶凝胶过程中紫外可见吸收光谱的变化规律以探索其在复合体系中的存在状态。实验表明 ,在溶胶阶段 ,随着时间的延长 ,紫外可见吸收光谱中单体的吸收峰强度增大 ,说明凝胶中酞菁单体的浓度增大 ;而形成凝胶后 ,随着时间的延长 ,紫外可见吸收光谱中单体的吸收峰强度减小 ,二聚体的吸收峰强度增大 ,说明由于体系结构和微化学环境的变化 ,酞菁分子趋向于聚合。 相似文献