Thermolysis behavior of flame-retardant copolyamide 66 (FR-PA66) in the presence of triaryl phosphine oxide (TPO) has been studied using different techniques such as differential scanning calorimetry, thermal gravimetric analysis, Fourier transform-infrared spectroscopy, and gas chromatography–mass spectrometry. The results indicate that TPO extends the thermolysis time of FR-PA66, and improves the thermolysis temperature. A three-stage mechanism for the decomposition of FR-PA66 has been proposed in this article. In the first stage, cleavage of P–C bond takes place in FR-PA66, while in the second stage, cleavage of polyamide chain occurs mainly. In the third stage, formation of cyclic compounds proceeds along with the formation of carbonized protective layer on the degraded polymer. 相似文献
The three photons from the dominant ortho-positronium decay and two vector mesons from the ηc exclusive decays are found to be in tripartite and high-dimensional entangled states, respectively. These two classes of entangled states possess the Hardy type nonlocality and allow a priori for quantum mechanics vs local realism test via Bell inequalities. The experimental realizations are shown to be feasible, and a concrete scheme to fulfill the test in experiment via two-vector-meson entangled state is proposed. 相似文献
Knockout reaction experiment was carried out by using the 6He beams at 61.2 MeV/u impinging on a CH2 target. The α core fragments at forward angles were detected in coincidence with the recoiled protons at larger angles. From this exclusive measurement the valence nucleon knockout mechanism and the core knockout mechanism can be distinguished by the relation between the polar angles of the core fragments and the recoiled protons, respectively. It is demonstrated that the core knockout mechanism may result in some strong contamination to the real invariant mass spectrum.
Cellular pH homeostasis is essential for many physiological and pathological processes. pH monitoring is helpful for the diagnosis, treatment and prevention of disorders and diseases. Herein, we developed a ratiometric fluorescent pH probe (TCC) based on a coumarin derivative containing a highly active lactone ring. TCC exhibited a typical AIE effect and emitted blue fluorescence under weak acidic condition. When under weak basic condition, the active lactone moiety underwent a hydrolysis reaction to afford a water-soluble product, which gave red-shifted emission. The emission color change from blue through cyan and then to yellow within pH 6.5–9.0 which is approximate to the biological pH range. And the fluorescence color change along with pH value is reversible. Furthermore, TCC was successfully utilized in the detection of the intracellular pH change of live HeLa cells, which indicated that TCC had practical potential in biomedical research.
Transport in Porous Media - A numerical model is investigated representing counter-current spontaneous imbibition of water to displace oil or gas from a core plug. The model is based on mass and... 相似文献
This paper investigates the dynamical behaviour of the Liu system with time delayed feedback. Two typical situations are considered and the effect of time-delay parameter on the dynamics of the system is discussed. It is shown that the Liu system with time delayed feedback may exhibit interesting and extremely rich dynamical behaviour. The evolution of the dynamics is shown to be complex with varying time-delay parameter. Moreover, the strange attractor like ‘wormhole' is detected via numerical simulations. 相似文献
In order to improve the optical properties of the Ⅲ-Ⅴ laser diodes(LDs) by means of H2S plasma passivation technology,H2S plasma passivation treatment is performed on the GaAs(110) surface.The optimum passivation conditions obtained are 60-W radio frequency(RF)power and 20-min duration.So the laser cavity surfaces axe treated under the optimum passivation conditions.Consequently,compared with unpassivated lasers with only AR/HR-coatings,the catastrophic optical damage (COD) threshold value of the passivated lasers by H2S plasma treatment is increased by 33%,which is almost the same as that of (NH4)2Sx treatment.And the life-test experiment has demonstrated that this passivation method is more stable than(NH4)2Sx solution wet-passivated treatment. 相似文献
High chemical yields and good enantiomeric excesses are obtained by using soluble polymer-supported tartrate ester in the epoxidation of trans-hex-2-en-1-ol using Ti(OPri)4/tert-butyl hydroperoxide. 相似文献