Synthesis and characterization of poly(vinyl alcohol)‐graft‐[poly(D,L‐lactide)/poly(D,L‐lactide‐co‐glycolide)] hydrogels

Poly(D ,L ‐lactide) and poly(D ,L ‐lactide‐co‐glycolide) with various composition and with one methacrylate and one carboxylate end group were synthesized and grafted onto poly(vinyl alcohol) (PVA) via the carboxylate group. The graft copolymers were crosslinked via the methacrylate groups using a free radical initiator. The polymer networks were characterized by means of NMR and studied qualitatively by means of IR spectroscopy. The influence of the glycolide content in the polyester grafts and of the number of ester units in the grafts on thermal properties and swellability were studied as well. The high swellability in water is characteristic of all hydrogels. Differential scanning calorimetry (DSC) showed a single glass transition temperature that occurs in the range between 51 and 69 °C. Thermogravimetric analysis (TGA) of the networks showed the main loss in weight in the temperature range between 290 and 370 °C. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 4536–4544, 2007     

L-shell X-ray production cross section measured by heavy ion impact on selected rare earth elements

The production cross sections of L-shell X-ray of some rare earth elements have been measured by collision of ¹²C⁴⁺ and ¹⁶O⁴⁺ ions of 0.5 to 0.75 MeV/amu. The results were compared with experimental data of other authors and with theoretical predictions gained by the ECPSSR and ECPSSR plus multiple ionization (ECPSSR+MI) models. For atomic parameters (fluorescence yields and probabilities for Coster-Kronig transitions) the role of several databases were studied. The ECPSSR theory underestimates cross sections when compared with experimental results obtained in the present work, but ECPSSR+MI has a better agreement with the experimental data. This revised version was published online in July 2006 with corrections to the Cover Date.     

The reconstructed final state of Au+AU collisions from PHENIX and STAR data at √s=130 AgeV— Indication for quark deconfinement at RHIC

The final state of Au+Au collisions at √s=130 AGeV at RHIC has been reconstructed within the framework of the Buda-Lund hydrodynamical model, by performing a simultaneous fit to final data on twoparticle Bose-Einstein correlations of the STAR and PHENIX Collaboration, and final identified single-particle spectra as measured by the PHENIX Collaboration. The results indicate a strongly three dimensional expansion, with a four-velocity field that is almost a spherically symmetric Hubble flow. We find large transverse geometrical source sizes, R _G=9.8±1.2 fm, relatively short mean freeze-out time, τ₀=6.1±0.3 fm/c and a short duration of particle emission, Δτ=0.02±1.5 fm/c. Most strikingsly, we find an indication for a hot central part of the hydrodynamically evolving core, characterized by a central temperature T ₀=202±13 MeV that is close to (or even above) the deconfinement temperature of the quark-hadron phase transition. The best fit indicates a cold surface temperature T _s=110±16 MeV. When the possibility of the hot center is excluded, the confidence level of the fit decreases from 28.9% to 1.0%. Predictions are made for the rapidity dependence of the slope parameters and for the transverse mass depedence of the rapidity width of the single-particle spectra, and the transverse mass dependence of the non-identical particle correlations.     

Fracture strength of class II slot cavities restored with polymerizable restorative materials

This study compared the fracture strength of Class II slot cavities restored with polymerizable restorative materials. Sixty, caries-free, posterior teeth were divided into five groups of 12 teeth. The Class II slot cavities were prepared. The teeth were restored with two packable composites (Filtek P60, Surefil), a microhybrid composite (Filtek Z250)and two ormocer (Definite, Admira). The restorations were then subjected to fracture resistance tests. The marginal ridges of the restorations were loaded at an angle of 13.5° to the long axis of the tooth in an Universal Testing Machine until failure. Analysis of mean forces indicated that, Filtek P60, Surefil and Filtek Z250 exhibited better performance than Definite and Admira. The tested resin composites differed in their mechanical properties. This study suggested that fracture behavior were highly influenced by the filler system. Overall, Filtek P60, Surefil, Filtek Z250, demonstrated good fracture resistance. Copyright © 2003 John Wiley & Sons, Ltd.     

Finding Robust Solutions Using Local Search

This paper investigates how a local search metaheuristic for continuous optimisation can be adapted so that it finds broad peaks, corresponding to robust solutions. This is relevant in problems in which uncertain or noisy data is present. When using a genetic or evolutionary algorithm, it is standard practice to perturb solutions once before evaluating them, using noise from a given distribution. This approach however, is not valid when using population-less techniques like local search and other heuristics that use local search. For those algorithms to find robust solutions, each solution needs to be perturbed and evaluated several times, and these evaluations need to be combined into a measure of robustness. In this paper, we examine how many of these evaluations are needed to reliably find a robust solution. We also examine the effect of the parameters of the noise distribution. Using a simple tabu search procedure, the proposed approach is tested on several functions found in the literature. This revised version was published online in August 2006 with corrections to the Cover Date.     

An anisotropic fibre-network model for mechano-sorptive creep in paper

In this paper a simplified network model for mechano-sorptive creep is presented, which is a further development of an earlier paper [Strömbro, J., Gudmundson, P., 2008. Mechano-sorptive creep under compressive loading – a micromechanical model. International Journal of Solids and Structures 45 (9), 2420–2450.]. It is assumed that the anisotropic hygroexpansion of the fibres leads to large stresses at the fibre bonds when the moisture content changes. The resulting stress state will accelerate creep if the fibre material obeys a constitutive law that is non-linear. Fibre kinks are included in order to capture experimental observations of larger mechano-sorptive effects in compression than in tension. Moisture dependent material parameters and anisotropy in the fibre distribution have been introduced. Theoretical predictions based on the model are compared to experimental results for an anisotropic paper both under tensile and compressive loading at varying moisture content and it is found that the important features in the experiments are captured by the model. Different kinds of drying conditions have also been examined.     

Pulsed laser deposition of atomically flat La1-xSrxMnO3 thin films using a novel target geometry

A new ablation target geometry is presented that was used to produce thin films of La_1-xSr_xMnO₃ grown heteroepitaxially on SrTiO₃ by pulsed reactive crossed-beam laser ablation. The films were grown in order to perform angle-resolved photoelectron spectroscopy, which demands that the surface be atomically flat. In situ and ex situ analysis shows that this condition was met, even after depositing to a thickness of over 100 nm. PACS 61.10.-i; 61.18.Bn; 68.47.Gh; 71.27.+a; 81.15.Fg