Synthesis of poly-yne polymers containing transition metals,disilane, disiloxane and phosphine groups in the main chain

The synthesis and characterization of metal poly-yne polymers containing disilane, disiloxane and phosphine groups in the main chain are described. The platinum and palladium poly-yne polymers were synthesized by polycondensation reactions between a metal chloride and an α, ω-bisethynyl complex in amines in the presence of cuprous iodide as a catalyst. The nickel poly-yne polymers were synthesized by an alkynyl ligand exchange reaction between a nickel acetylide and an α, ω-bisethynyl complex in diethylamine in the presence of cuprous iodide as a catalyst. The reaction of the platinum poly-yne polymer, containing disiloxane groups in the main chain, with copper (I) salts afforded adducts of η-²-bonded σ-acetylide polymer complexes. The reactions of the palladium poly-yne polymer, containing phosphine groups in the main chain, with transition-metal carbonyl complexes afforded polymer complexes which have phosphorus in the main chain-transition-metal bonds. A concentrated solution of the platinum poly-yne polymer containing disiloxane groups in the main chain forms a lyotropic liquid crystal in dichloromethane or 1, 2-dichloroethane.     

Meromorphic functions in the solution of the two-dimensional problem of elasticity

We introduce meromorphic functions that follow logically from the solutions of doubly periodic problems of two-dimensional elasticity (a rectangular period lattice). We establish their properties and their connection with the known meromorphic functions. We give convenient formulas for numerical implementation. Translated fromMatematichni Metodi ta Fiziko-Mekhanichni Polya, Vol. 40, No. 2, pp. 53–58.     

1.2 Anorganische analyse

Ohne Zusammenfassung     

Stereochemical aspects of the formation of toxisterols A

Mechanisms for the formation of toxisterol A are suggested. The connection between the conformation of the initial previtamin and the stereochemistry of the reaction products is discussed.Lensoviet Leningrad Technological Institute. Translated from Khimiya Prirodnykh Soedinenii, No. 2, pp. 225–229, March–April, 1989.     

Radiotracer study of deposition caused by suspended sediments of river seman

The deposition caused by suspended sediments in three points at the Seman river mouth was determined by means of¹³⁷Cs. The soil pollution with this radionuclide, caused by the Chernobyl accident is given, too.     

A comparison of spin relaxation and local motion between symmetrically and asymmetrically ring-substituted bisphenol units in dissolved polycarbonates

Carbon-13 and proton spin-lattice relaxation times were measured at two field strengths on solutions 10% by weight of two polycarbonates in C₂D₂Cl₄ from ?20 to +120°C. The first polycarbonate is an asymmetrically substituted form with one chlorine on one of the two phenylene aromatic rings of the bisphenol unit, whereas the second polycarbonate is symmetrically substituted with two chlorines on each of the two rings. The nuclear spin relaxation data are interpreted in terms of several local motions likely in these polymers. Segmental motion was described by the Hall–Helfand correlation function. Segmental motion in the monosubstituted polycarbonate is somewhat slower than in unsubstituted polycarbonate, whereas segmental motion in the tetrasubstituted polycarbonate is considerably slower. Phenylene ring rotation is observed in unsubstituted polycarbonate and in the monosubstituted polycarbonate above 40°C. Below 40°C in the monosubstituted species, and at all temperatures in the tetrasubstituted species, ring rotation is replaced by ring libration as the predominant motion contributing to spin lattice relaxation. In addition, the rotational motion of the two types of rings in the asymmetric monosubstituted form are very similar although not identical. The substituted ring is slightly less mobile than the rings of unsubstituted polycarbonate. This indicates a strong coupling of ring motion, although the coupling leads to less than synchronous motion. Methyl group rotation is present in both polymers and is little affected by the various structural modifications.     

Nonlinear Theory of the Plasma Wave Excitation in a Bounded Beam-Plasma System

The excitation of symmetric and antisymmetric plasma waves by a beam layer that moves within a homogeneous plasma enclosed by a metallic wall was dealt with theoretically. Investigations were carried out for the magnetic field free case and for a magnetized electron beam. In the latter case, the beam electrons are assumed to be unable to move in the perpendicular direction. The theoretical model bases upon an extension of the well known single wave theory to a two-dimensional beam-plasma system. Special emphasis should be paid to the fact that the perpendicular wave profile of the excited waves was determined self-consistently. Energy and momentum balance equations are derived for this system. The theoretical method outlined in this paper which is based on a Green's-function technique can be extended easily to three-dimensional systems or to beam-plasma systems with other boundary conditions. The main features of the saturation process of the basic unstable wave types are discussed. Several interesting effects were found in the magnetic field free case: (i) numerical solutions describe an increasing steepening of the wave amplitudes in perpendicular direction near the center of the system for the symmetric potential wave; (ii) for the antisymmetric wave, a smoothing tendency was found in the development of the perpendicular wave potential profile; (iii) spatial separation of the slow and fast beam electrons was observed; (iv) it is shown for the antisymmetric potential wave type that, under certain conditions, a very efficient beam particle retardation mechanism occurs which is connected with a strong reduction of the formation of a fast particle group; (v) generally it was shown that the conversion of the kinetic energy of the beam electrons into the plasma wave energy may be more effective as compared with the case of the magnetized beam.     

X-ray scattering studies of the structure of aqueous hydroxy-propylcellulose solutions

X-ray diffraction studies have been undertaken on aqueous solutions of hydroxy propylcellulose (HPC) over a wide range of the scattering vector Q. The experiments revealed only modest differences in local structure on a distance scale ca. 5–300 Å despite the fact that they covered concentrations generally interpreted as ranging from the isotropic (35.1 wt %) to the anisotropic liquid crystalline (LC) phase (53.5 wt %). Several models were used to interpret the small-angle scattering data, and each gave similar structural parameters and extrapolated intensities ( Q → 0) for both solutions. Peaks were observed with d-spacings ca. 12–17 Å in both materials. Wide-angle x-ray scattering (WAXS) showed slightly increased local order over a size range ca. 5–20 Å for the anisotropic solution, and this is consistent with a greater intensity of the 13 Å peak in this material. It is difficult to reconcile these findings with an interpretation of the LC state involving major differences with the isotropic phase and a high degree of orientational order extending over long length scales.