首页 | 本学科首页   官方微博 | 高级检索  
文章检索
  按 检索   检索词:      
出版年份:   被引次数:   他引次数: 提示:输入*表示无穷大
  收费全文   529110篇
  免费   5861篇
  国内免费   1626篇
化学   286210篇
晶体学   8010篇
力学   22664篇
综合类   18篇
数学   60572篇
物理学   159123篇
  2021年   4117篇
  2020年   4644篇
  2019年   4962篇
  2018年   6293篇
  2017年   6178篇
  2016年   9750篇
  2015年   6271篇
  2014年   9485篇
  2013年   23834篇
  2012年   18060篇
  2011年   22331篇
  2010年   15472篇
  2009年   15086篇
  2008年   20336篇
  2007年   20339篇
  2006年   19033篇
  2005年   17254篇
  2004年   15959篇
  2003年   14089篇
  2002年   13912篇
  2001年   15696篇
  2000年   11841篇
  1999年   9439篇
  1998年   7884篇
  1997年   7634篇
  1996年   7421篇
  1995年   6725篇
  1994年   6479篇
  1993年   6314篇
  1992年   7118篇
  1991年   7167篇
  1990年   6844篇
  1989年   6743篇
  1988年   6708篇
  1987年   6632篇
  1986年   6285篇
  1985年   8205篇
  1984年   8412篇
  1983年   6771篇
  1982年   7090篇
  1981年   6932篇
  1980年   6589篇
  1979年   6988篇
  1978年   7256篇
  1977年   7058篇
  1976年   7011篇
  1975年   6545篇
  1974年   6436篇
  1973年   6605篇
  1972年   4547篇
排序方式: 共有10000条查询结果,搜索用时 0 毫秒
91.
We examine the influence of relativistic and QED effects on the existence of the 1,3P o H- resonances between n = 2 and 3 hydrogen thresholds, the relativistic and QED corrections and the coupling effects between the high singlet and triplet states are considered as first-order perturbations. We firstly obtain accurate non-relativistic resonant energies and widths of fifteen 1P o resonances, and fifteen 3P o resonances. The fifteen 1P o resonances are classified to be 3 (2, 0) - n ( 4 ? n ? 12) and 3 (1, 1) + n ( 3 ? n ? 8). The fifteen 3P o resonances are classified to be 3 (2, 0) + n ( 3 ? n ? 12) and 3 (1, 1) - n ( 4 ? n ? 8). We found there exist six Feshbach resonances for 3 (2, 0) - n (1P o ) series, four Feshbach resonances for 3 (1, 1) + n (1P o ) series, seven Feshbach resonances for 3 (2, 0) + n (3P o ) series, and three Feshbach resonances for 3 (1, 1) - n (1P o ) series. Received 22 February 2002 Published online 24 September 2002  相似文献   
92.
This work is devoted to the numerical solution of the Navier–Stokes equations for compressible viscous fluids. Finite element approximations and stabilization techniques are addressed. We present methods to implement discontinuous approximations for the pressure and the density. An upwinding methodology is being investigated which combines the ideas behind the stream line Petrov–Galerkin method and the flux limiter methods aiming to introduce numerical diffusion only where it is necessary.  相似文献   
93.
The interaction between trivalent lanthanide ions and poly(1,4,7,10,13‐pentaoxacyclopentadecan‐2‐yl‐methyl methacrylate), PCR5, in aqueous solution and in the solid state have been studied. In aqueous solution, evidence of a weak interaction between the lanthanides and PCR5 comes from the small red shift of the Ce(III) emission spectra and the slight broadening of the Gd(III) EPR spectra. From the Tb(III) lifetimes in the presence of H2O and D2O the loss of one or two water coordinated molecules is confirmed when Tb(III) is bound to PCR5. An association constant of the order of 200 M?1 was obtained for a 1:1 (lanthanide:15‐crown‐5) complex from the shift of the polymer NMR signals induced by Tb(III). A similar association constant is obtained from the differences of the molar conductivity of Ce(III) solution at various concentrations in presence and absence of PCR5. When Tb(III) is adsorbed on PCR5 membranes, lifetime experiments in H2O and D2O confirm the loss of 5 or 6 water coordinated molecules indicating that in solid state the lanthanide(III)‐PCR5 interaction is stronger than in solution. The adsorption of Ce(III) in PCR5 membranes shows a Langmuir type isotherm, from which an equilibrium constant of 39 M?1 has been calculated. SEM shows that the membrane morphology is not much affected by lanthanide adsorption. Support for lanthanide ion–crown interactions comes from ab initio calculations on 15‐crown‐5/La(III) complex. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1788–1799, 2007  相似文献   
94.
95.
We investigate the existence and stability of solutions for higher-order two-point boundary value problems in case the differential operator is not necessarily positive definite, i.e. with superlinear nonlinearities. We write an abstract realization of the Dirichlet problem and provide abstract existence and stability results which are further applied to concrete problems.  相似文献   
96.
We show how methods for estimating the concentration function of the sum of independent random variables can be used to obtain estimates of the concentration function for the values of additive functions under suitable conditions. Previously obtained estimates of the concentration function are consequences of the estimate obtained in the present paper for functions from of the class under consideration.  相似文献   
97.
The Mathematical Intelligencer encourages comments about the material in this issue. Letters to the editor should be sent to either of the editors-in-chief, Chandler Davis or Marjorie Senechal.  相似文献   
98.
99.
Butyltins were analyzed in waters from California river and lake marinas and were detected at the part per trillion (ppt) level in most locations. The tributyltin:dibutyltin (TBT/DBT) ratios in the fresh waters were similar to those in their saline counterparts indicating like rates of degradation in the two salinity regimes.  相似文献   
100.
设为首页 | 免责声明 | 关于勤云 | 加入收藏

Copyright©北京勤云科技发展有限公司  京ICP备09084417号