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Brunner CT Baran ET Pinho ED Reis RL Neves NM 《Colloids and surfaces. B, Biointerfaces》2011,84(2):77-507
Poly(butylene succinate) (PBSu), poly(butylene succinate-co-adipate) (PBSA) and poly(butylene terephthalate-co-adipate) (PBTA) microcapsules were prepared by the double emulsion/solvent evaporation method. The effect of polymer and poly(vinyl alcohol) (PVA) concentration on the microcapsule morphologies, drug encapsulation efficiency (EE) and drug loading (DL) of bovine serum albumin (BSA) and all-trans retinoic acid (atRA) were all investigated. As a result, the sizes of PBSu, PBSA and PBTA microcapsules were increased significantly by varying polymer concentrations from 6 to 9%. atRA was encapsulated into the microcapsules with an high level of approximately 95% EE. The highest EE and DL of BSA were observed at 1% polymer concentration in values of 60 and 37%, respectively. 4% PVA was found as the optimum concentration and resulted in 75% EE and 14% DL of BSA. The BSA release from the capsules of PBSA was the longest, with 10% release in the first day and a steady release of 17% until the end of day 28. The release of atRA from PBSu microcapsules showed a zero-order profile for 2 weeks, keeping a steady release rate during 4 weeks with a 9% cumulative release. Similarly, the PBSA microcapsules showed a prolonged and a steady release of atRA during 6 weeks with 12% release. In the case of PBTA microcapsules, after a burst release of 10% in the first day, showed a parabolic release profile of atRA during 42 days, releasing 36% of atRA. 相似文献
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Nicolaou KC Simonsen KB Vassilikogiannakis G Baran PS Vidali VP Pitsinos EN Couladouros EA 《Angewandte Chemie (International ed. in English)》1999,38(23):3555-3559
Strikingly simple cascade dimerization sequences can be used to assemble the complex frameworks of bisorbicillinoids such as bisorbicillinol (1), bisorbibutenolide (2), and trichodimerol (3). The mechanistic facets of the biomimetic total syntheses of these bioactive natural products were also explored. Inspection of the unique molecular architecture of these compounds reveals that they are likely to be assembled in nature by a dimerization of two oxidized forms of sorbicillin. 相似文献
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Preparation and Properties of Some New Arsenate and Vanadate Halogen Apatites The preparation of new apatite-like compounds of the composition Na2Nd2Pb6(RO4)6X2 (with R = As, V and X = Cl, Br and also R = P and X = Br) is reported. Crystallographic data for these as well as for the already known Na2Nd2Pb6(PO4)6Cl2 are determined from the corresponding X-ray powder diagrams. Also the infrared and Raman spectra were recorded and briefly discussed. 相似文献
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Abschätzung mittlerer Schwingungsamplituden der Metall—Sauerstoff-Bindungen einiger Hexaoxometallate
Enrique J. Baran 《Monatshefte für Chemie / Chemical Monthly》1976,107(1):241-245
Mean amplitudes of vibration of a series of hexaoxometalates have been estimated using an approximation method and recently reported spectroscopic data arising from the study of the respective lithium salts. 相似文献
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