XY(H,Li,Na)分子基态的结构与势能函数

运用群论及原子分子反应静力学方法,推导了XY(H,Li,Na)分子基态的电子态及相应的离解极限.并采用密度泛函方法(B3LYP)和二次组态相互作用方法(QCISD)优化计算了XY(H,Li,Na)分子基态的平衡结构、振动频率和离解能.使用QCISD/6-311++G(3df,3pd)方法,对XY(H,Li,Na)分子基态进行了单点能扫描计算,采用最小二乘法拟合Murrell-Sorbie函数得到了相应的势能函数和与该基态相对应的光谱常数(Be,αe,ωe和ωexe),计算结果与实验数据符合得相当好.     

Influence of reaction gas flows on the properties of SiGe:H thin film prepared by plasma assisted reactive thermal chemical vapour deposition

A new preparing technology, very high frequency plasma assisted reactive thermal chemical vapour deposition （VHFPA-RTCVD）, is introduced to prepare SiGe：H thin films on substrate kept at a lower temperature. In the previous work, reactive thermal chemical vapour deposition （I~TCVD） technology was successfully used to prepare SiGe：H thin films, but the temperature of the substrate needed to exceed 400℃. In this work, very high frequency plasma method is used to assist RTCVD technology in reducing the temperature of substrate by largely enhancing the temperature of reacting gases on the surface of the substrate. The growth rate, structural properties, surface morphology, photo- conductivity and dark-conductivity of SiGe：H thin films prepared by this new technology are investigated for films with different germanium concentrations, and the experimental results are discussed.     

Space-Selective Precipitation of Ba2TiSi2O8 Crystals in Sm3^＋-Doped BaO-TiO2-SiO2 Glass by Femtosecond Laser Irradiation

The ferroelectric crystal Ba2TiSi2O8 with high second-order optical nonlinearity is precipitated in Sm^3＋-doped BaO-TiO2-SiO2 glass by a focused 800hm, 250 kHz and 150fs femtosecond laser irradiation. No apparent blue and red emissions are observed at the beginning, while strong blue emission due to second harmonic generation and red emission due to the f-f transitions of Sm^3＋ are observed near the focal point of the laser beam after irradiation for 25s. Micro-Raman spectra confirm that Ba2 TiSi2O8 crystalline dots and lines are formed after laser irradiation. The mechanism of the phenomenon is discussed.     

组合式Si-PIN 14 MeV中子探测器

提出了一种在多片Si-PIN探测器中间用2mm厚的聚乙烯作为灵敏度增强介质,采用加法电路模式进行信号输出的组合式新型DT聚变中子(14MeV)探测技术原理. 这种组合的主要特点有： 1)大幅度提高了Si-PIN探测器的中子灵敏度和测量统计性; 2)提高了探测器的n/γ分辨本领; 3)在实现多个探测器信号相加的同时,组合探测器相对于单片探测器时间响应没有明显改变. 从实验及理论上对组合探测器的14MeV中子及1.25MeV γ灵敏度、n/γ分辨,时间特性和测量统计性进行了研究. 关键词： Si-PIN半导体探测器 灵敏度 n/γ分辨 时间响应     

Pump-to-Stokes transfer of relative intensity noise in Brillouin fiber ring lasers

We have experimentally investigated pump-to-Stokes intensity noise transfer in both the frequency domain and the time domain in all-fiber single-frequency Brillouin ring lasers. In the high-frequency region (>1MHz), the pump-to-Stokes noise transfer function can be much smaller than unity, indicating that the Brillouin fiber lasers act as an efficient low-pass filter. The maximum noise reduction of 40-60 dB was observed at antiresonant frequencies that are multiples of half the cavity free spectral range. This is the first experimental demonstration, to the authors' knowledge, of intensity noise reduction in Brillouin fiber lasers.     

交叉型波荡器软X射线自由电子激光极化控制的影响因素

 交叉型波荡器是一种实现软X射线自由电子激光极化控制的有效方式。以自放大自发辐射自由光电子激光为例,采用统计的方法系统地分析了交叉型波荡器软X射线自由电子激光极化控制的影响因素。通过对光场相干长度、光脉冲两分量之间相对滑移长度和光场分量平均功率差异等的分析,给出了优化交叉型波荡器极化控制方案遵循的原则,即：辐射场相干时间尽可能长,光场分量相对滑移长度尽可能短,辐射场分量功率差异尽可能小等。该原则为交叉型波荡器软X射线自由电子激光极化控制方案的优化提供了依据。     

基于SBS光限幅和金属酞菁光限幅相结合的复合型光限幅器的研究

为了使受激布里渊散射(SBS)光限幅器的输出能量更"平",提出了一种基于SBS光限幅和金属酞菁光限幅相结合的复合型光限幅器的方案,即SBS光限幅后边放置金属酞菁光限幅,在两种光限幅器的共同限幅作用下,使复合型光限幅器的输出光能量更"平". 数值模拟了该复合型光限幅器的输出光能量随入射光强度的变化曲线,并在Countinuum's Nd: YAG种子注入式激光器中进行了实验验证. 理论和实验结果均表明,复合型光限幅器的输出光能量比单独SBS光限幅器更"平". 关键词： 复合型光限幅器 SBS光限幅 金属酞菁限幅     

单室沉积非晶硅/非晶硅/微晶硅三叠层太阳电池的研究

在产业化比较成熟的单室沉积非晶硅薄膜太阳电池基础上,进行了非晶硅/非晶硅/微晶硅三叠层太阳电池性能优化的研究.在生产线上纯单室沉积的非晶硅/非晶硅叠层太阳电池基础上,通过调节n-p隧穿结并采用自行研制开发的单室微晶硅底电池的沉积路线,获得了单室沉积的光电转换效率达到9.52%的非晶硅/非晶硅/微晶硅三叠层太阳电池. 关键词： 硅基薄膜太阳电池 三叠层 微晶硅