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Jarkova E. Pleiner H. Mller H.-W. Fink A. Brand H.R. 《The European physical journal. E, Soft matter》2001,5(1):583-588
The European Physical Journal E - We derive hydrodynamic equations for nematic ferrofluids (ferronematics) in the limit that the magnetic degree of freedom has relaxed to its equilibrium value. We... 相似文献
85.
Tomáš Opravil Petr Ptáček František Šoukal Jaromír Havlica Jiří Brandštetr Lenka Opravilová 《Journal of Thermal Analysis and Calorimetry》2013,112(3):1401-1406
The expansion effect of laboratory-prepared expansive additives for M-type expansive cement was investigated at the early stage of hydration by the multicell isoperibolic calorimeter and volumetric technique based on Archimedes’ principle. The relative volume changes and heat released during hydration are strongly affected by the content of lime in the expansive additive due to the influence of CaO on the kinetics and mechanism of formation of ettringite. The increasing content of lime favours the formation of monosulphate and its later transformation to ettringite generating expansion stress. The effect of expansive additive on the behaviour of mortar samples was measured as linear elongation of test blocks using Graf-Kaufman dilatometer. Lower or higher content of lime in expansion additive slightly decreases the 7th-day compressive and flexural strength of samples while this effect is negligible for expansive additive with nominal composition of ettringite. 相似文献
86.
On the Existence of the Oxonium Ion in Solid Basic Aluminium Sulphates Oxonium alunite was investigated by 1H-NMR-, heat capacity, electric conductivity, and thermoanalytic measurements. In the 1H-NMR spectrum the existence of the oxonium ion was surely proved. From the results of the other investigations follow, that the oxonium ion is fast bonded in the structure and that exists an unimportant amount of mobile ionic charge carriers only. 相似文献
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Clément Suspène Stéphane Brandès Roger Guilard Prof. 《Chemistry (Weinheim an der Bergstrasse, Germany)》2010,16(21):6352-6364
The present study reports the synthesis and rational design of porous structured materials by using a templating method. A tetraethoxysilylated tripodal tetraamine (TREN) was covalently incorporated in a silica framework with a double imprint: A surfactant template and a metal ion imprint. The presence of a cationic surfactant (CTAB) endowed the material with a high porosity, and the tripodal or square‐pyramidal topology of the ligand was preserved thanks to the use of the silylated CuII complex. After removal of the surfactant and de‐metalation, the incorporated tetraamine was quantitatively complexed by CuCl2 and the material has shown after thermal activation that a reversible binding of O2 on the metal ions occurred. This chemisorption process was monitored by UV/Vis and EPR spectroscopies, and the Cu:O2 adduct was postulated to be an end‐on μ‐η1:η1‐peroxodicopper(II) complex bridged by a chloride ion. The CuI‐active species, formed during the activation step, were fully recovered during several O2 binding cycles. The high reactivity of the copper complexes and the room‐temperature stability of the dioxygen adduct were explained by the fine adaptability of the tripodal ligand to different geometries, the confinement of the active sites in the hybrid silica that protect them from degradation by a control of the metal‐ion microenvironment, as well as the short‐range lamellar order of the copper complexes in the framework. 相似文献
89.
M. Kaliteevski S. Brand R.A. Abram I. Iorsh A.V. Kavokin T.C.H. Liew I.A. Shelykh 《Superlattices and Microstructures》2011
We have demonstrated theoretically that it is possible to use the resonant coupling of exciton-polaritons in a planar microcavity and Tamm plasmons at a metal film on the surface of the structure to provide lateral spatial control of the exciton-polaritons within the cavity. The resonant coupling of the Tamm plasmons to cavity exciton-polaritons results in a triplet of hybrid plasmon–exciton-polariton modes with the lowest at a significantly lower energy than that of the unperturbed exciton-polaritons. Further, a patterned metal film on the structure surface can provide a sufficiently large lateral modulation of the excitation energy that localization of the exciton-polaritons within chosen regions of the cavity is possible. We show how the approach opens the way to a practical demonstration of polariton channels, traps, and devices, including logic gates. 相似文献