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111.
Roberto Ballini Dennis Fiorini Maria Victoria Gil Alessandro Palmieri 《Tetrahedron》2004,60(12):2799-2804
Nitroalkanes have been found to give good yields in Michael and nitroaldol (Henry) reactions by the use of a catalytic amount (10 mol%) of CTAOH, at room temperature and under solvent free conditions and in very short reaction times. The methods do not need a large excess of the nitroalkanes and show good chemoselectivity toward further functionalities. 相似文献
112.
Paul du Bois-Reymond 《Mathematische Annalen》1882,20(1):122-124
Ohne ZusammenfassungAbgedruckt aus den Sitzungsberichten der math.-phys. Classe der k. b. Akadem. d. Wiss. zu München. 相似文献
113.
Paul A. Binding Patrick J. Browne Bruce A. Watson 《Journal of Mathematical Analysis and Applications》2004,291(1):246-261
Three inverse problems for a Sturm-Liouville boundary value problem −y″+qy=λy, y(0)cosα=y′(0)sinα and y′(1)=f(λ)y(1) are considered for rational f. It is shown that the Weyl m-function uniquely determines α, f, and q, and is in turn uniquely determined by either two spectra from different values of α or by the Prüfer angle. For this it is necessary to produce direct results, of independent interest, on asymptotics and oscillation. 相似文献
114.
Nearly four hundred non-routine organizational decisions were investigated to discover search approaches––determining the frequency of use and success of each search approach uncovered. A “search approach” is made up of a direction and a means to uncover solution ideas. Direction indicates desired results and it can be either implicit or explicit, with an explicit direction offering either a problem or a goal-like target. Solutions can be uncovered by opportunity, bargaining, and chance as well as by rational approaches. Defining a search approach as a direction coupled with a means of search, search approaches were linked with indicators of success, measured by the decision's adoption, value and timeliness, noting frequency. A rational, goal-directed, search approach was more apt to produce successful outcomes. Bargaining with stakeholders to uncover solutions was always combined some of the search approaches in this study, and this merger improved the prospects of success. Searches with an opportunistic or chance (emergent opportunity) features and rational searches with a problem target were more apt to produce unsuccessful outcomes. The means used to come up with a solution had less bearing on success than did the type of direction, with goal-directed searches leading to the best outcomes. Each search approach is discussed to reveal best practices and to offer suggestions to improve practice. 相似文献
115.
Claude Didierjean Julien Marin Emmanuel Wenger Jean‐Paul Briand Andr Aubry Gilles Guichard 《Acta Crystallographica. Section C, Structural Chemistry》2004,60(3):o200-o203
X‐ray studies reveal that tert‐butyl (6S)‐6‐isobutyl‐2,4‐dioxopiperidine‐1‐carboxylate occurs in the 4‐enol form, viz. tert‐butyl (6S)‐4‐hydroxy‐6‐isobutyl‐2‐oxo‐1,2,5,6‐tetrahydropyridine‐1‐carboxylate, C14H23NO4, when crystals are grown from a mixture of dichloromethane and pentane, and has an axial orientation of the isobutyl side chain at the 6‐position of the piperidine ring. Reduction of the keto functionality leads predominantly to the corresponding β‐hydroxylated δ‐lactam, tert‐butyl (4R,6S)‐4‐hydroxy‐6‐isobutyl‐2‐oxopiperidine‐1‐carboxylate, C14H25NO4, with a cis configuration of the 4‐hydroxy and 6‐isobutyl groups. The two compounds show similar molecular packing driven by strong O—H⋯O=C hydrogen bonds, leading to infinite chains in the crystal structure. 相似文献
116.
Thomas J. Delia Dennis P. Anderson Jennifer M. Schomaker 《Journal of heterocyclic chemistry》2004,41(6):991-993
In a continuation of our studies involving the nucleophilic displacement of one of the chlorines from 2,4,6‐trichloropyrimidine, we now report the initial displacement of one of the fluorine atoms from 2,4,6‐trifluoropyrimidine using both aliphatic and aromatic amines. The monosubstitution products favor 2‐substitution with ammonia and ethanolamine while aniline gave the 4‐substituted derivative as the preferred product. 相似文献
117.
Isosteric derivatives and analogues of the 7-keto-8-aminopelargonic acid (KAPA), 7,8-diaminopelargonic acid (DAPA) and desthiobiotin (DTB) vitamer intermediates involved in the biosynthetic pathway of biotin were prepared and evaluated as potential herbicides. The most active compound was desmethyl-KAPA which displayed a GR50 (concentration of the active compound that causes a 50% growth inhibition) value of 8 ppm, where values <50 ppm are considered herbicidal. Other KAPA analogs where the terminal Me group was replaced by bulkier substituents such as Et, i-Pr and HOCH2 showed moderate activity. 相似文献
118.
Walter D. Neumann Paul Norbury 《Transactions of the American Mathematical Society》2003,355(2):519-538
We show that although the fundamental group of the complement of an algebraic affine plane curve is not easy to compute, it possesses a more accessible quotient, which we call the Orevkov invariant.
119.
Nathan S. Feldman Paul McGuire 《Proceedings of the American Mathematical Society》2003,131(6):1793-1801
In this paper we show that the spectral picture of an irreducible subnormal operator may be arbitrarily prescribed subject only to certain natural necessary conditions. This completes work begun by the second author.
120.