Rapid Detection of Five Estrogens Added Illegally to Dietary Supplements by Combining TLC with Raman Imaging Microscope

Estrogens added illegally to dietary supplements are hazardous to human health. Traditional detection and analysis methods have many limitations, and we have developed an assay that combines thin-layer chromatography with Raman imaging microscopy (TLC-RIM). The five estrogens (estrone, estradiol, estriol, ethinyl estradiol, and diethylstilbestrol) were initially separated by TLC, then detected by area scanning Raman imaging with a 532 nm laser under a microscope. Raman spectra were obtained for each estrogen, which were used for detecting estrogen illegally added to botanical dietary supplements. The LOD of each estrogen was 0.4, 1.0, 0.8, 0.2, and 0.2 mg/mL, respectively. The matrix in the real sample did not interfere with the detection of estrogens. The method was fast, sensitive, stable, specific, and reliable.     

Effect of Coconut Protein and Xanthan Gum,Soybean Polysaccharide and Gelatin Interactions in Oil-Water Interface

We report on our study of the interactions between coconut protein extracted from coconut meat and three hydrocolloids (gelatin, xanthan gum, and soybean polysaccharide) and their interfacial adsorption and emulsification properties. We used Zeta potential, fluorescence spectroscopy scanning and ITC to investigate the interactions between a fixed concentration (1%) of coconut protein and varying concentrations of hydrocolloid. Through the interfacial tension and interfacial viscoelasticity, the interfacial properties of the hydrocolloid and coconut protein composite solution were explored. The physical stability of the corresponding emulsion is predicted through microstructure and stability analysis. Xanthan gum forms a flocculent complex with coconut protein under acidic conditions. Soy polysaccharides specifically bind to coconut protein. Under acidic conditions, this complex is stabilized through the steric hindrance of soy polysaccharides. Due to gelatin-coconut protein interactions, the isoelectric point of this complex changes. The interfacial tension results show that as time increases, the interfacial tensions of the three composite solutions decrease. The increase in the concentration of xanthan gum makes the interfacial tension decrease first and then increase. The addition of soybean polysaccharides reduces the interfacial tension of coconut protein. The addition of xanthan gum forms a stronger elastic interface film. Emulsion characterization showed that the gelatin-added system showed better stability. However, the addition of xanthan gum caused stratification quickly, and the addition of soybean polysaccharides also led to instability because the addition of polysaccharides led to a decrease in thermodynamic compatibility. This research lays the foundation for future research into coconut milk production technology.     

FeCoCrCuNi高熵合金裂纹及孔洞结构力学与微观构象演化机理的分子动力学模拟研究

本文采用分子动力学方法研究了FeCoCrCuNi高熵合金裂纹及孔洞模型结构在不同轴向拉伸应变速率下的力学与微观结构演化机理. 结果表明：应变速率越高FeCoCrCuNi裂纹结构对应更高的过冲应变和过冲应力,其主要原因是高拉伸速率会导致高强度的BCC结构及孪晶结构的生成,而BCC结构及孪晶结构的产生进而会抑制应力的下降,通过应力-应变曲线,可知FeCoCrCuNi裂纹模型在轴向应力作用下表现为塑性形变. 对于不同尺寸的孔洞FeCoCrCuNi裂纹模型的应力模拟与结构分析,可以得出：孔洞尺寸越大, FeCoCrCuNi裂纹结构对应的过冲应变和过冲应力越小,其主要原因是大尺寸的孔洞造成孔洞之间产生裂纹的,进而会影响这个材料的屈服应变和屈服强度.     

Hierarchical nanowires for high-performance electrochemical energy storage

Nanowires are promising candidates for energy storage devices such as lithium-ion batteries, su- per（：apa.citors and lithium-air batteries. However, simple-structured nanowires have some limitations hence the strategies to make improvements need to be explored and investigated. Hierarchical nanowires with enhanced periormanee have been considered as an ideal candidate for energy storage due to the novel structures and/or synergistic properties. This review describes some of the recent progresses in the hierarchical nanowire merits, classification, synthesis and performance in energy storage applieat, ions. Herein we discuss the hierarchical nanowires based on their structural design from three major categories, including exterior design, interior design and aligned nanowire assembly. This review also briefly outlines the prospects of hierarchical nanowires in morphology control, property enhancement and application versatility.     

IPDA激光雷达数据反演快速精确优化算法

研究了积分路径差分吸收(IPDA)激光雷达中采用洛伦兹线型代替伏格特线型对机载平台探测CO₂柱浓度精度的影响。建立仿真模型,讨论两种线型在数据反演中对温度和气压的敏感性,以及探测相对误差变化随飞行高度的变化。结果表明：伏格特和洛伦兹线型得到的吸收截面,温度和气压敏感性,相对随机误差分别为0.860%,-0.703%和0.224%,基本没有差别,但是洛伦兹线型可以有效地提高光谱参数计算效率。机载IPDA激光雷达采用洛伦兹线型可以快速高精度反演飞行路径上CO₂柱浓度,降低了对系统计算能力的要求,有助于实现在飞期间数据实时反演和分析,以及实施针对突发事件的飞行规划,同时也有助于进一步实现机载激光雷达系统的小型化和集成化。     

甲醇在γ-Al2O3,CeO2及其负载Pd催化剂上吸附和分解的原位红外光谱研究

利用原位傅里叶变换红外光谱 (FTIR)技术对甲醇在γ Al2 O3,CeO2 以及Pd/Al2 O3,Pd/CeO2 催化剂上的吸附和分解行为进行了研究。综合考虑了载体和活性组分的作用 ,分析了甲醇在不同载体负载Pd催化剂上可能的分解途径。在Pd/CeO2 催化剂上 ,活性组分和载体对甲醇分解的过程表现出了一种协同效应。     

快速匹配算法在药筒模块检测中的应用

为了能够快速、准确判断药筒模块是否合格,实现检测的自动化,针对药筒模块中可燃性紧塞盖图像的特点和检测要求,在研究经典相关系数匹配算法基础上,采用了一种快速图像匹配算法,即通过减少相关系数计算量和模板搜索范围,在保证匹配准确度的前提下来提高图像匹配速度。实验和现场测试表明,使用该方法,匹配速度提高了近67%,实现了图像的快速匹配,软件误判率1%,满足实际生产要求。     

夹心式压电换能器的谐振频率跟踪方案设计

分析了夹心式压电换能器的阻抗特性,讨论了基于相位方式的现有跟踪方案的不足,提出了一种新的频率跟踪方案,介绍了实现该方案的电路系统。该方案的特点是:采用先扫频后跟踪的策略,解决了频率范围设定难的问题;增加解锁控制,使得系统在死锁或误跟踪时自动回到频率搜索状态;采用直接数字合成器(DDS)作为频率调整和信号产生的器件,实现了全数字系统,调整方便,精度高;采用复杂可编程逻辑器件(CPLD)做相位比较和DDS控制,使频率跟踪速度快,并且跟踪精度和速度均可控制。     

全光纤光子集成器件及系统

本对全光纤光子集成器件与系统进行了较为全面地综述,结合我们的工作,对目前的研究热点：光纤光栅,光纤激光器,光纤放大器,光纤光栅分插器与传感器等诸多光子器件以及由这些器件组成的波分复用通信系统进行了介绍和评述,一些新成果和新进展表明,这些光子器件与系统在当今和未来的光通信中将发挥重要作用。     

Coherent underwater communication using passive time reversal over multipath channels

Passive time reversal exploits underwater acoustic channels’ spatial and temporal diversity. It can refocus multipath propagated signal at the receiver and can be realized simply by the passive phase conjugation (PPC) method. By the temporal focusing, time delay spread caused by multipath propagation is mitigated for spectral efficient coherent communications. However, the PPC method is unable to eliminate multipath and is limited by channel variations. An adaptive equalizer is therefore needed to compensate residual multipath after refocusing and to track channel temporal variations. Spatial diversity is obtained by using a vertical receiving array. In this paper we used 4-hydrophone array and demonstrated that the adaptive decision feedback equalization in conjunction with PPC significantly decreased the bit error rate.