Cr^4＋：YAG的可饱和吸收特性与被动Q开关性能研究

运用速率方程计算了Ｃｒ＾４＋：ＹＡＧ晶体的可饱和吸收特性参数，包括初始吸收系数，饱和吸收系数，饱和光强和损耗调制度，用Ｃｒ＾４＋：ＹＡＧ对脉冲和连续Ｎｄ：ＹＡＧ激光器进行了被动调Ｑ，在脉冲Ｎｄ：ＹＡＧ激光器上得到了８ｎｓ的调Ｑ激光脉冲，在连续Ｎｄ：ＹＡＧ激光器的调Ｑ中得到了间隔和幅度抖动小于５％的输出脉冲充列。     

艾纳香中黄酮化合物的研究

从中药艾纳香(Blumea balsamifera DC)中分离得到两种新的黄酮化合物,应用NMR、MS、IR、UV等波谱数据,确定其化学结构为3,5,3'-三羟基-7,4'-二甲氧基黄酮(Ⅰ)和3,5,3',4'-四羟基-7-甲氧基黄酮(Ⅱ).     

非线性ABS型算法的一个统一收敛定理

本文讨论非线性方程组的算法的局部收敛性，给出了一个统一的收敛定理．该定理相当一般，不仅包含ＡＢＳ型方程，而且对目前常用的许多方法也都适用．     

Certificateless signature: a new security model and an improved generic construction

Certificateless cryptography involves a Key Generation Center (KGC) which issues a partial key to a user and the user also independently generates an additional public/secret key pair in such a way that the KGC who knows only the partial key but not the additional secret key is not able to do any cryptographic operation on behalf of the user; and a third party who replaces the public/secret key pair but does not know the partial key cannot do any cryptographic operation as the user either. We call this attack launched by the third party as the key replacement attack. In ACISP 2004, Yum and Lee proposed a generic construction of digital signature schemes under the framework of certificateless cryptography. In this paper, we show that their generic construction is insecure against key replacement attack. In particular, we give some concrete examples to show that the security requirements of some building blocks they specified are insufficient to support some of their security claims. We then propose a modification of their scheme and show its security in a new and simplified security model. We show that our simplified definition and adversarial model not only capture all the distinct features of certificateless signature but are also more versatile when compared with all the comparable ones. We believe that the model itself is of independent interest.A conventional certificateless signature scheme only achieves Girault’s Level 2 security. For achieving Level 3 security, that a conventional signature scheme in Public Key Infrastructure does, we propose an extension to our definition of certificateless signature scheme and introduce an additional security model for this extension. We show that our generic construction satisfies Level 3 security after some appropriate and simple modification. A preliminary version of the extended abstract of partial results appeared in ACISP 2006 [9].     

丁酮分子内价轨道1a″的电子动量谱学研究

用高分辨率电子动量谱仪进行丁酮分子的结合能谱和内价轨道1a″电子动量谱的实验工作，以及用Hartree-Fock和密度泛函理论方法对1a″轨道电子动量谱的理论研究. 得到了各价轨道的电离能值以及理论计算的总能、偶极矩和1a″轨道的二维密度图. 并比较了内价轨道1a″的电子动量谱的实验和理论计算结果，实验结果与理论计算符合较好.     

Enhanced blue-green-red up-conversion and 1.3-μm emission of Pr/Yb-codoped oxyhalide tellurite glasses with PbCl2 doping

We report on the blue-green-red up-conversion spectroscopic properties of Pr³⁺/Yb³⁺-codoped oxyhalide tellurite glasses upon excitation of a conventional 980 nm laser diode (LD). Significant enhancement of the blue-green-red up-conversion emission intensity has been observed with increasing PbCl₂ doping. The up-conversion intensity has a quadratic dependence on incident pump laser power, indicating a two-photon process. The population of the Pr³⁺ upper ³P₀ emitting level was accomplished through a combination of a ground state absorption, energy transfer and excitated state absorption. 1.3-μm emission in the second telecom window originated from Pr³⁺:¹G₄→³H₅ transition has also been investigated upon excitation at 980 nm LD. The measured peak wavelength and full width at half-maximum of the fluorescent are 1335 nm and ∼100 nm, respectively. An enhanced 1.3μm emission with increasing PbCl₂ doping has also been observed. Codoping of Yb³⁺ significantly enhance both the blue-green-red up-conversion emission and 1.3-μm emission intensity by way of a nonradiative Yb³⁺:²F₅→Pr³⁺:¹G₄ energy transfer.     

A new method and instrument for accurately measuring interval between ultrashort pulses

Using second-order autocorrelation conception, a novel method and instrument for accurately measuring interval between two linearly polarized ultrashort pulses with real time were presented. The experiment demonstrated that the measuring method and instrument were simple and accurate (the measurement error ＜ 5 fs). During measuring, there was no moving element resulting in dynamic measurement error.     

Time-resolved Luminescence-based Chemosensor for Fluoride Anion

Design and synthesis of new chemosensors for fluoride anion (F-)1-6 have been of interest to chemists for many years, because F- plays a crucial role in the dental care5 and the treatment of osteoporosis7. Recently, the fluorescent chemosensors of fluorid…     

球形汞膜电极倒导数恒电流溶出分析法研究

本文推导并验证了球形汞膜电极倒导数恒电流溶出分析法理论。确定其理论的应用条件为汞膜厚度不超过4.6×10~(-4)cm,探讨了噪音对灵敏度的影响。     

Laser performance of monolithic Cr,Nd:YAG self-Q-switched laser

The self-Q-switched laser performance of monolithic Cr⁴⁺,Nd³⁺:YAG concave-planar resonator with 5-mm length was studied experimentally and theoretically. The slope efficiency is as high as 24% and pump threshold is as low as 64 mW. The pulse width, the single pulse energy and the pulse repetition rate of monolithic Cr,Nd:YAG self-Q-switched laser were measured as a function of absorbed pump power. With the increase of pump power, the pulse width decreases and the pulse energy and the pulse repetition rate increase. The average output power of 91 mW with pulse width of 7 ns at repletion rate of 35.5 kHz was obtained at the maximum absorbed pump power of 440 mW, the peak power is as high as 370 W. The theoretical prediction of pulse energy, pulse width and pulse repetition rate as a function of absorbed pump power based on rate equations is in a good agreement with our experimental data. This can lead to develop the diode laser-pumped monolithic self-Q-switched solid-state microchip lasers.