在LiCl-KCl-NaCl熔盐体系中碳的阴极还原的研究

用循环伏安法和电位阶跃法研究了LiCl-KCl-NaCl熔盐体系中碳的阴极还原机理。在钨、铂、不锈钢等微电极上得到的伏安图表明碳的还原是由CO_3~(2-)离子经一步电化学反应实现的,电极反应速度控制步骤为CO_3~(2-)离子向阴极的扩散过程,还原过程具有反应物吸附特征。碳在W、Pt、不锈钢电极上析出电位分别为-2.05V、-1.745V和-1.90V(均相对于Ag/AgCl参比电极)。     

Diaquabis(2,5‐dihydroxybenzoato‐κO)bis(1,10‐phenanthroline‐κ2N,N′)strontium(II) bis(1,10‐phenanthroline) tetrahydrate

The title compound, [Sr(C₇H₅O₄)₂(C₁₂H₈N₂)₂(H₂O)₂]·2C₁₂H₈N₂·4H₂O, consists of an Sr^II complex, uncoordinated phenanthroline (phen) molecules and solvent water molecules. The Sr^II ion is located on a twofold axis and is coordinated by two phen ligands, two dihydroxybenzoate anions and two water molecules in a distorted tetragonal antiprismatic geometry. Partially overlapped arrangements exist between parallel coordinated and parallel uncoordinated phen rings; the face‐to‐face separations between the former (coordinated) and the latter (uncoordinated) rings are 3.436 (13) and 3.550 (14) Å, respectively. This difference suggests the effect of metal coordination on π–π stacking between phen rings.     

Synthesis and magnetic properties of the one-dimensional linear chain structure cyano-bridged complex [Cu(teta)(H2O)2][Cu(teta) Fe(CN)6]ClO4·2H2O (teta=5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacylotetradecane)

Reaction of either K₃[Fe(CN)₆] or K₄[Fe(CN)₆] with a macrocyclic Cu^II complex, [Cu(teta)](ClO₄)₂ (teta = 5,7,7,12,14,14-hexamethyl-1,4,8,11-tetraazacylotetradecane), in aqueous solution gave the same product as shown by spectroscopic and physicochemical characterisation. The crystal structure of the complex shows that it is a one-dimensional linear chain type heterobinuclear Fe^III–Cu^II polymer. The unit is composed of a [Cu(teta)(H₂O)₂]²⁺ cationic complex, a Fe^III–Cu^II alternate linear chain unit, a ClO ₄ ^– ion and four water molecules. The Cu atom is coordinated in a distorted octahedral arrangement by four nitrogen atoms from one teta ligand and two nitrogen atoms of the bridging cyanide groups. The Cu—N bond distances involving the cyanide bridges, 2.522(7) and 2.608(7)Å, respectively, indicate weak antiferromagnetic interactions between the Fe^III and Cu^II atoms.     

Donorstabilisierte Galliumdihalogenide Ga2X4·2D (X = Cl,Br; D = Donormolekül): Ein experimenteller Beitrag zu den Variationsmöglichkeiten der Ga‐Ga‐Einfachbindung

Donor‐stabilized Galliumdihalides Ga₂X₄·2D (X = Cl, Br; D = Donor): An Experimental Contribution on the Variation of the Gallium‐Gallium Single Bond During the disproportionation of metastable GaX‐solutions (X= Cl, Br) donor‐stabilized galliumdihalides are formed as oxidized products. According to X‐ray structure analyses they all exhibit dimeric entities DX₂Ga‐GAX₂D (D= THF, NHEt2, NEt3, 4‐^tButylpyridin or Br^‐), which means these compounds are isoelectronic with ethane and could schematically be regarded as representatives of catenulate or alkane‐like gallium subhalides: Ga_n(X, D)_2n+2. The gallium‐gallium bond in these compounds is shorter than in the organometallic compounds such as R₂Ga‐GaR₂. The comparison of the bonding situation in the galliumdihalides, particularly of the gallium‐gallium bond, shows clearly the influence by donor molecules as well as by halogen ligands.     

神经网络的函数逼近能力分析

本文综述了多层前传网络（ＭＬＰ）及径向基函数网络（ＲＢＦ）对函数任意精度逼近的能力，比较了两种网络的最佳逼近特性。对激活函数类的扩充作了介绍，并说明有限数值精度对函数逼近能力实现的影响。     

Notable shift of ultraviolet intensity on Sn-doped ZnO nanostructure fabricated by sol–gel method

Sn-doped ZnO (SZO) thin films are deposited by sol–gel dip-coating method with Sn content at 0 at.% and 1–15 at.% with an increment of 2 at.%. The structure and luminescence of the films are investigated. X-ray diffraction results indicate that all the SZO samples show preferential orientation along the (002) direction, and the scanning electron microscope exhibits that the surface morphology of the films change from nanoparticles to nanorods with increasing Sn concentration. X-ray photoelectron spectroscopy reveals that Sn exists as valence of +4 in the matrix. The photoluminescence peaks at 381 and 398 nm are observed in all the samples. The ratio of intensity of peak at 381 nm to that of peak at 398 nm differed markedly. The intensity of peak at 398 nm might be due to the response for the Sn atoms, while the intensity of peak at 381 nm is probably related to the quantum size effect.