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11.
The ionic exchange behavior of Zn2+, Ni2+, and Cu2+ metallic ions on Amberlyst-15 commercial resin was studied as a function of resin solution contact time, initial concentration of metallic ions, nature of the solvent, and the amount of resin. The metallic ions were studied in ternary mixtures using both column and batch experiments. In addition, water, methanol, ethanol, and propan-2-ol were used as solvents for dissolving metallic ions. It was found that the resin behavior depends on the solvent nature and the metallic ion concentration. The analysis of solutions by atomic absorption spectrometry revealed that the affinity of the resin for the studied metallic ions followed the sequence Cu2+ > Ni2+ > Zn2+ in the case of an aqueous medium. Furthermore, uptake increased with increasing amount of resin. A better uptake was observed in the case of the 75:25 % water/methanol compositions when the column technique was used. For the batch technique, we noted a better uptake using 100 % water. The uptake rate decreased with an increase in the number of carbons for the 50 % water–50 % alcohol solvents. The acid–base properties of Amberlyst-15 commercial resin were studied by 2-propanol decomposition test. Propene and acetone are the main expected products and it is believed that they are formed through dehydration or dehydrogenation reaction on acid and base sites, respectively.  相似文献   
12.
The dispersion of NiO supported on boron-modified silicas has been studied by transmission electron microscopy (TEM) and XPS. The TEM experiments showed that all NiO is present in the form of crystallites; values for the dispersion were calculated on the basis of measurements of the size distributions of these crystallites. The XPS measurements were interpreted using a model which assumes large particle sizes and no re-partitioning of the supported species between internal pores and the surface when boron-modification is performed. The variations of dispersion with boron content obtained from this model agree well with the variations measured by TEM.  相似文献   
13.
We consider random, complex sample covariance matrices X*X, where X is a p × N random matrix with i.i.d. entries of distribution μ. It has been conjectured that both the distribution of the distance between nearest neighbor eigenvalues in the bulk and that of the smallest eigenvalues become, in the limit N → ∞, → 1, the same as that identified for a complex Gaussian distribution μ. We prove these conjectures for a certain class of probability distributions μ. © 2004 Wiley Periodicals, Inc.  相似文献   
14.
We consider a version of Glauber dynamics for a p-spin Sherrington– Kirkpatrick model of a spin glass that can be seen as a time change of simple random walk on the N-dimensional hypercube. We show that, for all p ≥ 3 and all inverse temperatures β > 0, there exists a constant γ β ,p  > 0, such that for all exponential time scales, exp(γ N), with γ < γ β ,p , the properly rescaled clock process (time-change process) converges to an α-stable subordinator where α = γ/β 2 < 1. Moreover, the dynamics exhibits aging at these time scales with a time-time correlation function converging to the arcsine law of this α-stable subordinator. In other words, up to rescaling, on these time scales (that are shorter than the equilibration time of the system) the dynamics of p-spin models ages in the same way as the REM, and by extension Bouchaud’s REM-like trap model, confirming the latter as a universal aging mechanism for a wide range of systems. The SK model (the case p = 2) seems to belong to a different universality class.  相似文献   
15.
We study the Gibbs measure of mixed spherical p -spin glass models at low temperature, in (part of) the 1-RSB regime, including, in particular, models close to pure in an appropriate sense. We show that the Gibbs measure concentrates on spherical bands around deep critical points of the (extended) Hamiltonian restricted to the sphere of radius , where is the rightmost point in the support of the overlap distribution. We also show that the relevant critical points are pairwise orthogonal for two different low temperatures. This allows us to explain why temperature chaos occurs for those models, in contrast to the pure spherical models. © 2019 Wiley Periodicals, Inc.  相似文献   
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Future contributions to Journal of Chemical Crystallograpy  相似文献   
18.
The structure and reactivity of Mo(3)S(9) clusters, taken as a model for amorphous molybdenum trisulfide, have been investigated at the B3LYP density functional level of theory. Two computed ground-state cluster structures are close in energy and have similar structural parameters and vibrational modes. These values agree well with the available experimental data. These cluster structures are considered to be formed simultaneously during the preparation process of catalysts. Their catalytic activity has been analyzed on the basis of frontier molecular orbital properties (FMO). It is mainly due to 4d-type orbitals of the unsaturated molybdenum centers without terminal sulfur coordination. The small HOMO-LUMO gaps suggest that Mo(3)S(9) clusters can act as Lewis acids or Lewis bases.  相似文献   
19.
Copolymerization of fluorine ring-substituted 2-phenyl-1,1-dicyanoethenes, RC6H3CH?C(CN)2 (R is 2,3-F,F, 2,4-F,F, 2,5-F,F, 2,6-F,F, and 4-CF3) with 4-fluorostyrene were prepared in the presence of a radical initiator (ABCN) at 70°C. The composition of the copolymers was calculated from nitrogen analysis, and the copolymers were characterized by IR, 1H and 13C-NMR, GPC, DSC, and TGA. The monomer reactivity ratios for 4-fluorostyrene (M1), r1 = 0.6 and 2-(2,4-difluorophenyl)-1,1-dicyanoethene (M2), r2 = 0 were determined from Fineman-Ross plot. The order of relative reactivity (1/r1) for difluoro-substituted monomers is 2,4-F,F (0.31) > 2,3-F,F (0.25) > 2,5-F,F (0.22) > 2,6-F,F (0.10). DSC curves showed that the copolymers were amorphous with high T g in comparison with that poly(4-fluorostyrene) indicating a substantial decrease in chain mobility of the copolymer due to the high dipolar character of the trisubstituted ethylene monomer units. From the thermogravimetric analysis, the copolymers began to degrade in the range 214–260°C. The copolymer of 4-fluorostyrene and 2-(2,4-difluorophenyl)-1,1-dicyanoethene and poly(4-fluorostyrene) were dielectrically characterized in the range 25–200°C. The dominating relaxation process detected in both materials was the α-relaxation, associated with the dynamic glass transition. The relationship polarity-permittivity was discussed.  相似文献   
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