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81.
Monge ME Bulone D Giacomazza D Negri M Bernik DL 《Combinatorial chemistry & high throughput screening》2004,7(4):337-344
Multicomponent essential oils Tagetes Minuta and Poleo as well as pure limonene were encapsulated in Tween doped-high methoxylated pectin gels. Optical microscopy reveals that the obtained gels containing limonene consisted in a highly heterogeneous oil-in-water emulsion stabilised by the gelled medium. The influence of limonene encapsulation in pectin gelation kinetics and the gel structural properties were followed by dynamic rheological measurements. An electronic nose device developed in our laboratory was used to follow the flavour release of the three systems in order to discriminate the samples according to the main components released to the headspace. PCA and Neural Network Analysis allowed us to discriminate Tagetes Minuta from Poleo due to the difference in their limonene content. It is remarkable that the fingerprints of encapsulated complex mixtures differ from those obtained for the non-encapsulated oils, showing a preferential release of some components. In the case of limonene, the effect of the encapsulated concentration on the detected odour was also studied. 相似文献
82.
V.N.?StavrouEmail author D.?Preisser E.?Gehrig O.?Hess 《Applied physics. B, Lasers and optics》2004,78(6):765-768
A theory of ultra-fast carrier–light field dynamics of quantum dots is presented. The carrier–light field dynamics is described by Maxwell–Bloch equations. A calculation of the dipole matrix elements requires the determination of the electronic wave functions taking into account their dependence on the degeneracy of the carrier states. The ultra-fast carrier–light field dynamics depends strongly on the external applied electric field. PACS 42.55.Px; 42.60.Rn; 74.78.Fk 相似文献
83.
The cyclization of the A-B rings of squalene to hopene is studied computationally (DFT). A transition structure is found for a concerted, asynchronous pathway for the formation of chair-chair decalin carbocation. The computationally derived conformer leading to this asynchronous transition structure is remarkably similar to the analogous region of 2-azasqualene encapsulated by squalene-hopene cyclase recently reported by Schulz. A concerted A-B ring closure is likely to occur in the cyclization of squalene to hopene. [structure--see text] 相似文献
84.
E. Gehrig O. Hess C. Seibert D. Woll R. Wallenstein 《Applied physics. B, Lasers and optics》2003,76(3):285-288
We theoretically describe and experimentally investigate the spatio-spectral wave mixing of induced and spontaneous emission
in large-area InGaAs-semiconductor laser amplifiers. The dynamic light-matter-coupling is described by a spatially resolved
theory based on Maxwell–Bloch–Langevin equations, taking into account many-body-carrier interactions, energy transfer between
the carrier and phonon systems and, in particular, the spatio-temporal interplay of stimulated and amplified spontaneous emission
and the noise caused by spontaneous emission. Our numerical model reveals the fundamental physical processes which are responsible
for the spectral power distribution of the amplified laser light and predicts the emission properties of high-power semiconductor
laser amplifiers, such as emission spectra and input power–output power characteristics.
Received:30October2002/Revisedversion:21November2002 / Published online: 12 February 2003
RID="*"
ID="*"Corresponding author. Fax: +49-711/6862-349, E-mail: Edeltraud.Gehrig@dlr.de
RID="**"
ID="**"Also at: Institute of Physics, Tampere University of Technology, P.O. Box 692, FIN-33101, Tampere, Finland
RID="***"
ID="***"Present address: Heidelberger Druckmaschinen AG, Speyerer Strasse 6, 69115 Heidelberg, Germany
RID="****"
ID="****"Present address: Lightbit Corporation, 411 Clyde Avenue, Mountain View, CA 94043, USA 相似文献
85.
McGuinness DS Wasserscheid P Keim W Morgan D Dixon JT Bollmann A Maumela H Hess F Englert U 《Journal of the American Chemical Society》2003,125(18):5272-5273
Cr(III) complexes of tridentate SNS ligands have been prepared and evaluated as catalysts for ethylene trimerization, with several giving very high activity and excellent selectivity toward 1-hexene when activated with methylaluminoxane. The new complexes illustrate the potential of sulfur-based ligands on early transition metals for catalysis. 相似文献
86.
[reaction: see Text] Activation by either high pressure or a combination of Lewis acid catalysis and high pressure allows indole derivatives to behave as dienophiles in [4 + 2] cycloaddition reactions under mild conditions. The biactivation mode has the highest impact on the stereoselectivity of the reaction. The cycloadducts resulting from these reactions are characterized by boat-shape conformations that bear well-defined orthogonal planes. 相似文献
87.
K. Pretzl G. Ambrosini R. Arsenescu C. Baglin H. P. Beck K. Borer A. Bussière K. Elsener Ph. Gorodetzky J. P. Guillaud P. Hess S. Kabana R. Klingenberg G. Lehmann T. Lindén K. D. Lohmann R. Mommsen U. Moser K. Pretzl J. Schacher R. Spiwoks F. Stoffel J. Tuominiemi M. Weber 《Acta Physica Hungarica A》2001,14(1-4):297-308
Besides the dedicated search for strangelets NA52 measures light (anti)particle and (anti)nuclei production over a wide range of rapidity. Compared to previous runs the statistics has been increased in the 1998 run by more than one order of magnitude for negatively charged objects at different spectrometer rigidities. Together with previous data taking at a rigidity of ?20 GeV/c we obtained $10^6 \bar p, 10^3 \bar d$ and two $\overline {^3 He} $ without centrality requirements. We measured nuclei and antinuclei (p, d, $\bar p,\bar d$ ) near midrapidity covering an impact parameter range of b ~ 2–12 fm. Our results strongly indicate that nuclei and antinuclei are mainly produced via the coalescence mechanism. However, the centrality dependence of the antibaryon to baryon ratios shows that antibaryons are diminished due to annihilation and breakup reactions in the hadron dense environment. The volume of the particle source extracted from coalescence models agrees with results from pion interferometry for an expanding source. The chemical and thermal freeze-out of nuclei and antinuclei appear to coincide with each other and with the thermal freeze-out of hadrons. 相似文献
88.
Die vorliegende Arbeit beschāftigt sich mit der Answertung von Autoradiogrammen inhomogen markierter mikroskopischer Strukturen am Densitron. Dazu fertigten wir von herkömmlichen Stripping-Filmen (z. B. ORW O K 106) Mikro-Stufengraukeile an und bestimmten die Schwärzung Sijeder Stufe photometrisch. Graukeile geeigneten Schwärzungsumfangs dienten dann zur Einstellung der Farbtrigger des Densitrons, so daß sich die bei dieser Einstellung gemessenen Farbflächen Fi des jeweiligen Objektes bestimmten Schwärzungswerten zuordnen ließen. Als Modellobjekte verwendelen wir erstens Autoradiogramme von 3H-Thymidin-markierten Tumorzellen. Vergleichsmessungen an unterschiedlich lange exponierten, sonst aber identischen Präparaten ergaben eine gute Reproduzierbarkeit der Meßergebnisse. Als zweites Testobjekt dienlen Autoradiogramme einer nur schwach markierten Struktur im Gehirn von Fröschen. Die an diesem Grenzfall erhaltenen Ergebnisse werden mit Meßwerten verglichen, die vom gleichen Objekt mittels Scanning-Photometrie an einem. Mikroskop-Photometer SMP 01 (OPTON, Oberkoches, BRD) gewonnen wurden. 相似文献
89.
90.
A warm standby n-system with operational and repair times following phase-type distributions is considered. The online unit goes through degradating levels, determined by inspections. Two types of repairs are performed, preventive and corrective, depending on the degradation level. The standby units undergo corrective repair. This systems is governed by a level-dependent-quasi-birth-and-death proces (LDQBD process), whose generator is constructed. The availability, rate of occurrence of failures, and other quantities of interest are calculated. A numerical example including an optimization problem and illustrating the calculations is presented. This system extend other previously studied in the literature. 相似文献