溶剂密度对β胡萝卜素拉曼散射截面的影响

测量了含有9个CC共轭双键的链状多烯类生物分子β胡萝卜素在9种溶剂中的紫外—可见吸收和拉曼光谱.结果表明,β胡萝卜素C—C,CC键拉曼散射截面随溶剂体密度增加而线性增加,其机理是β胡萝卜素分子在体密度大的溶剂中受浮动干扰小,分子结构有序性高,π电子离域扩展,产生强的相干弱阻尼CC键振动,而产生大的拉曼散射截面.密度对分子拉曼散射截面影响研究还没见过报道,本文为多烯类链状分子的光散射理论研究提供了实验线索,也对多烯类链状分子性能研究及光电器件研制有参考价值. 关键词： 拉曼散射截面 多烯分子 吸收光谱 分子结构有序     

嵌入到Fabry-Perot谐振腔的双晶约瑟夫森结阵列的阻抗匹配和相位锁定研究

在He等人所做的嵌入到Fabry-Perot谐振腔中约瑟夫森结阵列的微波辐照研究基础上,提出了同时实现约瑟夫森结阵列阻抗匹配和相位锁定的方法,进行了相关的电磁仿真和数值计算.双晶约瑟夫森结阵列被制作在YSZ双晶基片上,同时被嵌入到Fabry-Perot谐振腔内.通过在基片上制作与结阵列集成的串联馈电半波偶极天线阵,并对其结构进行优化实现了结与天线的匹配,数值计算表明结的辐射效率达到94%;利用天线阵辐射场的特征和对模型合理的设计,使Fabry-Perot谐振腔和基片同时谐振在合适的模式下,从而使结阵列与谐 关键词： 约瑟夫森结阵列 阻抗匹配 相位锁定 Fabry-Perot谐振腔     

Characterize the interaction between naringenin and bovine serum albumin using spectroscopic approach

Naringenin, a flavanone compound highly enriched in grapefruits, has been identified as a possible inhibitor of cell proliferation; and thus has the potential to act as an antitumorigenic agent. In this study, the binding of naringenin to bovine serum albumin (BSA) was studied at the physiological conditions (pH=7.40) by fluorescence and UV-vis spectroscopy. Naringenin strongly quenches the intrinsic fluorescence of BSA, and a decrease in the fluorescence quenching constant was observed together with an increase in temperature, which indicates that the fluorescence quenching of BSA by naringenin is a result of the formation of naringenin-BSA complex. Binding parameters calculating from Stern-Volmer method and Scatchard method showed that naringenin bind to BSA with the binding affinities of the order 10⁴ L mol⁻¹. Thermodynamic parameters such as ΔG, ΔH and ΔS, were calculated at different temperatures, showing that electrostatic interactions were mostly responsible for the binding of naringenin to BSA. Site marker competitive displacement experiments demonstrating that naringenin bind with high affinity to site I (subdomain IIA) of BSA. Furthermore, the effect of metal ions to naringenin-BSA system was studied, and the specific binding distance r (3.30 nm) between donor (Trp-212) and acceptor (naringenin) was obtained according to fluorescence resonance energy transfer (FRET).     

Low-temperature hydrothermal synthesis of highly photoactive mesoporous spherical TiO2 nanocrystalline

TiO₂ microspheres with mesoporous textural microstructures and high photocatalytic activity were prepared by hydrothermal treatment of mixed solution of titanium sulfate and urea with designed time. The prepared samples were characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy and N₂ adsorption-desorption measurements. The photocatalytic activity was evaluated via the photocatalytic oxidation of acetone in air at room temperature. The results show that the hydrothermal time significantly influences on the morphology, microstructure and photocatalytic activity of the as-prepared samples. With increasing hydrothermal time, specific surface areas and pore volumes decrease, contrarily, the crystallite size and relative anatase crystallinity increase. The photocatalytic efficiency of the as-prepared samples is obviously higher than that of commercial Degussa P25 (P25) powders. Especially, the as-prepared TiO₂ powders by hydrothermal treatment for 7 h shows the highest photocatalytic activity, which exceeds that of P25 by a factor of more than 2 times.     

三维介观超导环涡旋态的研究

通过数值求解非线性金兹堡-朗道(G-L)方程组,研究了三维介观超导环中的涡旋态。发现了在细环中只能存在巨涡旋态,以及存在顺磁、抗磁迈斯纳效应和间隙性超导现象。在粗环中,发现了多涡旋态和巨涡旋态共存的混合态。相应讨论有助于理解介观超导环中涡旋态相变。     

Polarization phase-shifting Jamin shearing interferometer

The Jamin shearing interferometer is very useful in wavefront testing, especially for the low coherent light. Based on this interferometer, a polarization phase-shifting Jamin shearing interferometer is proposed to improve the performance. In the interferometer, two interference beams are linearly polarized and a polarization phase shifter is applied to realize the phase shifting. Different types of configurations of the interferometer are given. With phase-shifting interferograms, the precision of the interferometer can be improved. The interferometer is kept as an equal optical path system and its shearing amount remains changeable with simple structure and easy operation. In experiments, phase-shifting interferograms are obtained by rotating the analyzer. The usefulness of the interferometer is verified.     

Beam quality factor of mixed modes emerging from a multimode step-index fiber

The beam quality factors (or M² parameter) of coherent and incoherent superposition of the several lower-order LP modes emerging from a step-index fiber have been calculated by using the second-order moment method. The results indicate that, for an individual LP mode, the M² parameter takes its maximum value when the normalized frequency V of the step-index fiber approaches the cut-off frequency, and it gradually becomes constant as V increases. In the case of incoherent superposition, the larger the fraction intensity carried by the higher-order mode, the larger the beam quality factor M². Under certain circumstances, the value of the M² parameter of the mixed mode that comprises several LP-modes contents may become even smaller and closer to the ideal Gaussian beam than that of the fundamental mode in a step-index fiber. However, in the case of the coherent superposition, the value of the M² parameter of the mixed mode may be greater than that of the higher-order constituent mode. The results reported here could be helpful for the application of the high-power fiber laser systems.     

KGd(MoO4)2:Eu as a promising red phosphor for light-emitting diode application

A red phosphor KGd(MoO₄)₂:Eu³⁺ was prepared by solid-state reaction technique at high temperature. Its photoluminescent property was investigated and the optimum concentration of Eu³⁺ doped in the KGd(MoO₄)₂ is 25 mol%. Compared with Y₂O₂S:0.05Eu³⁺, the obtained KGd(MoO₄)₂:Eu³⁺ shows wider excitation band around 400 nm, higher intensity of Eu^{3+ 5}D₀–⁷F₂ emission upon excitation 393 nm, and the CIE chromaticity coordinates (x = 0.655, y = 0.345) are closer to the standard of National Television Standard Committee (NTSC). The optical properties of KGd(MoO₄)₂:Eu³⁺ suggest that it is an efficient red-emitting phosphor for light-emitting diode applications.     

Ferromagnetism in ZnCoO thin films deposited by PLD

Multilayer structures A–B–A⋅⋅⋅ consisting of alternating layers of a metal A and a semiconductor B can show large anisotropy in their transport properties. In tilted multilayer structures, where layer planes and sample surface include a nonzero tilt angle, nonvanishing off-diagonal elements in the sample’s transport tensors lead to transverse Seebeck and Peltier effects. Achievable temperature differences and figures of merit for transverse Peltier cooling are discussed and compared with experiments, coefficients of performance for transverse power generation are calculated.     

Interaction Between Methylene Blue and CalfThymus Deoxyribonucleic Acid by Spectroscopic Technologies

Characterization of the interaction between methylene blue (MB) and calf thymus deoxyribonucleic acid (ctDNA) was investigated by UV absorption spectra, fluorescence spectra, fluorescence polarization and fluorescence quenching experiments by ferrocyanide. The above results indicated that the binding modes of MB to ctDNA were relative to the molar ratio γ (γ=[DNA]/[MB]). At low γ ratios (γ < 4), remarkable hypochromic effect with no shift of λ_max in the absorption spectra of MB was observed in the presence of increasing amounts of ctDNA, the fluorescence of MB was efficiently quenched by the ctDNA bases and the fluorescence polarization of MB was slightly increased, which indicated that MB cations bound to phosphate groups of ctDNA by electrostatic interaction and then stacked on the surface of ctDNA helix. While at high γ ratios (γ > 6), besides the fluorescence of MB was quenched efficiently by the ctDNA bases, a red shift (about 3 nm) in the absorption spectra of MB was observed and the fluorescence polarization of MB was obviously increased, which indicated the intercalation binding that MB molecules were intercalated into the space of two neighbouring DNA base pairs was the preferred mode. Effects of K₄Fe(CN)₆ on the fluorescence quenching of the MB-ctDNA system at low and high γ ratios were also performed. The results showed that at γ = 1.7, the quenching effect by ferrocyanide was higher than that of pure MB, while at γ = 13.6 a decreased quenching of the fluorescence intensity was observed as compared with that of pure MB, which further proved the above conclusion. In addition, the mechanisms of the hypochromic effect and the fluorescence quenching were also discussed in detail.