全文获取类型
收费全文 | 193篇 |
免费 | 6篇 |
国内免费 | 1篇 |
专业分类
化学 | 131篇 |
晶体学 | 3篇 |
力学 | 1篇 |
数学 | 8篇 |
物理学 | 57篇 |
出版年
2022年 | 3篇 |
2021年 | 6篇 |
2020年 | 4篇 |
2019年 | 5篇 |
2017年 | 2篇 |
2016年 | 4篇 |
2015年 | 7篇 |
2014年 | 7篇 |
2013年 | 21篇 |
2012年 | 8篇 |
2011年 | 12篇 |
2010年 | 11篇 |
2009年 | 6篇 |
2008年 | 13篇 |
2007年 | 9篇 |
2006年 | 8篇 |
2005年 | 7篇 |
2004年 | 2篇 |
2003年 | 2篇 |
2001年 | 2篇 |
2000年 | 2篇 |
1999年 | 2篇 |
1997年 | 2篇 |
1996年 | 3篇 |
1995年 | 3篇 |
1994年 | 1篇 |
1993年 | 1篇 |
1992年 | 1篇 |
1990年 | 1篇 |
1988年 | 1篇 |
1986年 | 2篇 |
1985年 | 2篇 |
1984年 | 5篇 |
1983年 | 2篇 |
1982年 | 6篇 |
1981年 | 4篇 |
1979年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
1974年 | 1篇 |
1972年 | 1篇 |
1971年 | 1篇 |
1967年 | 2篇 |
1966年 | 2篇 |
1965年 | 2篇 |
1964年 | 3篇 |
1959年 | 1篇 |
1958年 | 2篇 |
1957年 | 2篇 |
1956年 | 1篇 |
排序方式: 共有200条查询结果,搜索用时 62 毫秒
141.
One-pot efficient synthesis of functionalized 5,6-dihydropyran-2-ones has been delineated by reacting 2H-pyran-2-ones and acetol in the presence of a base at room temperature. The formation of 5,6-dihydropyran-2-ones revealed that the reaction proceeded in a unique ‘ring transformation-rearrangement’ sequence. 相似文献
142.
Deepti Srivastava Datta Madamwar R. B. Subramanian 《Applied biochemistry and biotechnology》2010,162(3):766-779
Pentavalent arsenate reductase activity was localized and characterized in vitro in the cytosolic fraction of a newly isolated
bacterial strain from arsenic-contaminated sites. The bacterium was gram negative, rod-shaped, nonmotile, non-spore-forming,
and noncapsulated, and the strain was identified as Pseudomonas sp. DRBS1 following biochemical and molecular approaches. The strain Pseudomonas sp. DRBS1 exhibited enzymatic machinery for reduction of arsenate(V) to arsenite(III). The suspended culture of the bacterium
reduced more than 97% of As(V) (40–100 mM) to As(III) in 48 h. The growth rate and total cellular yield decreased in the presence
of higher concentration of arsenate. The suspended culture repeatedly reduced 10 mM As(V) within 5 h up to five consecutive
inputs. The cell-free extracts reduced 86% of 100 μM As(V) in 40 min. The specific activity of arsenate reductase enzyme in
the presence of 100 μM arsenate is 6.68 μmol/min per milligram protein. The arsenate reductase activity is maximum at 30 °C
and at pH 5.2. The arsenate reductase activity increased in the presence of electron donors like citrate, glucose, and galactose
and metal ions like Cd+2, Cu+2, Ca+2, and Fe+2. Selenate as an electron donor also supports the growth of strain DRBS1 and significantly increased the arsenate reduction. 相似文献
143.
The variation of resistivity in an amorphous As30Te70?x Si x system of glasses with high pressure has been studied for pressures up to 8 GPa. It is found that the electrical resistivity and the conduction activation energy decrease continuously with increase in pressure, and samples become metallic in the pressure range 1.0–2.0 GPa. Temperature variation studies carried out at a pressure of 0.92 GPa show that the activation energies lie in the range 0.16–0.18 eV. Studies on the composition/average co-ordination number ? r? dependence of normalized electrical resistivity at different pressures indicate that rigidity percolation is extended, the onset of the intermediate phase is around ? r?=2.44, and completion at ? r?=2.56, respectively, while the chemical threshold is at ? r?=2.67. These results compare favorably with those obtained from electrical switching and differential scanning calorimetric studies. 相似文献
144.
The detailed study, of the behaviour of di/tri halo carbonyls to act as the synthetic equivalents of corresponding mono γ-halo carbonyls, is carried out. 相似文献
145.
JPC – Journal of Planar Chromatography – Modern TLC - Premna integrifolia is an important constituent of the famous herbal formulation “Dashmool” of the Indian Ayurvedic... 相似文献
146.
Zhengzheng?Feng Adam?Bymaster Chris?Emborsky Deepti?Ballal Bennett?Marshall Kai?Gong Alejandro?Garcia Kenneth?R.?Cox Walter?G.?ChapmanEmail author 《Journal of statistical physics》2011,145(2):467-480
Self-assembly, important in industrial and biological processes, is governed not only by molecular size and shape, but also
by hydrogen bonding forces and hydrophobicities, both of which have important temperature-dependent consequences. Recent advances
in statistical mechanics enable the study of these processes at the molecular level. We discuss one such approach based on
classical density functional theory. The theory, based on extensions and simplifications of Wertheim’s theory for associating
molecules, is applicable to study the behavior of water at hydrophobic and hydrophilic surfaces and supramolecular assembly
based on intermolecular association of polyatomic molecules. Insights into the theory and into the physics of associating
molecules are discussed. 相似文献
147.
An expeditious straightforward synthesis of sesquiterpene-cored arenes functionalized with electron-withdrawing or electron-donating substituents is described and illustrated by Michael addition of S-(−)-citronellal on functionalized 2H-pyran-2-one in a single step at room temperature. The reaction was further generalized by synthesizing isoprenylated 9,10-dihydrophenanthrene-2-carbonitrile using 5,6-dihydro-2-oxo-4-sec-amino-2H-benzo[h]chromene-3-carbonitriles and S-(−)-citronellal under similar reaction conditions. 相似文献
148.
An innovative synthesis of terphenyls functionalized with electron-withdrawing or -donating substituents is described and illustrated by carbanion-induced ring transformation of 2H-pyran-2-ones with 2-methoxyacetophenone in excellent yields. The existing protocols for the synthesis of terphenyls are generally inter- and intramolecular aryl-aryl cross couplings in the presence of metal complexes. In this letter, we report a potentially useful alternative to conventional metal-catalyzed cross-coupling reactions. 相似文献
149.
150.
Ankita Singh Vipin K. Maikhuri Vineet Verma Rajni Johar Chhatwal Deepti Sharma 《合成通讯》2020,50(18):2787-2795
AbstractHere in, the condensation of boc-glycine with 2,6-anhydro-3,4,5-tri-O-benzyl-D-gluco-heptitol followed by its boc-deprotection to form 2,6-anhydro-3,4,5-tri-O-benzyl-D-gluco-heptitolyl bis-glycinate, which in turn on condensation with succinic acid/pyridine-2,6-dicarboxylic acid led to the formation of sugar-amino acid hybrid macrocyclic compounds 4, 6 and debenzylated marocyclic compound 5, having amide bonds that function as efficient host for polar, hydrogen bond acceptors and carboxylate ions. The anion inclusion capability of synthesized macrocylic hosts has been evaluated by the study of their binding with boc-GlyCOOˉ anion as guest through 1H NMR titration studies in CDCl3. The binding constant (Ka) of boc-GlyCOOˉ guest with macrocyclic hosts 4 and 6 involving succinate and pyridine-2,6-dicarboxylate linkers was found to be 9.201?×?103 and 1.437?×?104 M?1, respectively. The higher binding constant was observed in the complex of boc-GlyCOOˉ with pyridine-dicarboxylate containing host may be due to the extra rigidity & suitable conformation attained by the presence of rigid-aromatic dicarboxylate linker. 相似文献