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131.
振动谱学研究中的光谱线型函数 总被引:3,自引:1,他引:2
本文讨论了在振动谱带计算拟合处理中的光谱线型函数问题,推导出适用于单道及多道拉曼光谱仪及色散型红外谱仪谱带线型公式。通过实验及拟合计算证实了它们的适用性并讨论了可能的误差源。理论计算和实验验证结果说明:在振动谱的谱带拟合计算中,应使用根据测谱条件计算求得的谱带线型函数,以保证拟合结果的可靠性。 相似文献
132.
M. Alves Da Silva M. Helena Gil A. P. Piedade J. S. Redinha A. M. Oliveira Brett J. M. Caridade Costa 《Journal of polymer science. Part A, Polymer chemistry》1991,29(2):269-274
The immobilization of catalase on grafted membranes of poly(ethylene)-g-co-acrylic acid and poly(tetrafluoroethylene)-g-co-acrylic acid and their application in hydrogen peroxide electrochemical sensors is described. The introduction of carboxylic acid groups onto a hydrophobic support provides a good environment for subsequent enzyme immobilization. This single membrane, hydrogen peroxide sensor showed significant improvement with respect to the double membrane versions. The response is very rapid, the linear range being from 10 μM up to 6 mM, with a detection limit of 4.7 μM, and a lifetime of more than 4 months. 相似文献
133.
L. S. de C. Oliveira M. T. X. Silva A. Vasquez J. A. H. da Jornada 《Hyperfine Interactions》1991,66(1-4):267-270
An exploratory Mössbauer spectroscopy study of the Fe-C system in the C rich region, prepared by high pressure-high temperature treatment near the graphite-diamond stability line, was made. The results obtained for the different processing conditions give no evidence of Fe intercalation in graphite. The presence of some water in the cell produced hydrated Fe complexes, which can explain the deleterious effect of water or hydrogen in the high pressure diamond synthesis. 相似文献
134.
Miloslav Duchoň Anatolij Dvurečenskij Paolo de Lucia 《International Journal of Theoretical Physics》1997,36(9):1941-1958
We present a solution to the moment problem for effect algebras, concerning mean values of all powers of an observable concentrated
on the interval [0, 1] for states from a convex set. We give a solution for particular examples, e.g., for the set of all
effect operators. We examine how this problem is related to a socalled E-property. Finally, we give a solution for observables
studied in the operational approach to physical theories. 相似文献
135.
J.-J. Sauvain L. F. de Alencastro J. Tarradellas R. Camenzind G. Karlaganis C. Vuilleumier 《Fresenius' Journal of Analytical Chemistry》1994,350(7-9):555-562
The analysis of PCB in transformer oils has been achieved with three HRGC/ECD based methods, proposed by the International Electrotechnical Commission (IEC/TC 10), by the Comité Européen de Normalisation (CEN/TC 19/WG 22) and by the Deutsches Institut für Normung (DIN 51 527). The same clean-up, described in the CEN/TC 19/WG 22, has been used for all the samples, allowing a comparison of the quantification procedure only. The total chlorine content has also been determined with X-ray fluorescence. These different methods of quantification are compared and their application for legislative purposes is discussed.Dedicated to Professor Dr Dieter Klockow on the occasion of his 60th birthday 相似文献
136.
Patricia Smichowski María Beatriz de la Calle Guntiñas Carmen Cámara 《Fresenius' Journal of Analytical Chemistry》1994,348(5-6):380-384
Summary A method is described for antimony preconcentration based on retention on a column of activated alumina. Recovery is 80% when no pH-control and 4 mol/l HCl as eluent are used. The preconcentration factor is 400. The method was applied to the determination of antimony in spiked tap and sea water. The analytical performance of the method is discussed. 相似文献
137.
J.C. Góes S.D. FigueiróJ.A.C. de Paiva I.F. de VasconcelosA.S.B. Sombra 《Journal of Physics and Chemistry of Solids》2002,63(3):465-470
In this paper, we report results of a study of the physicochemical, dielectric and piezoelectric properties of anionic and native collagen films, considering the development of new biomaterials which have potential applications in coating of cardiovascular prostheses, support for cellular growth and in systems for controlled drug delivery. The piezoelectric strain tensor element d14, the elastic constant s55, and the dielectric permittivity ?11 were measured for the anionic and native collagen films. It was observed that the collagen samples submitted to the alkaline treatment present lower thermal stability than those made from native collagen. However, the treated samples present a higher piezoelectricity compared with the native collagen. The frequency constant fL and the piezoelectric strain element d14, obtained for the alkaline-treated sample (72 h), present the highest values for the samples under study (444.1 kHz m and 0.079 pC/N, respectively). We believe that the alkaline treatment led to an increase of the organization of the microscopic fiber structure of the sample, which could result in an increase of the piezoelectricity. 相似文献
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