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111.
In this paper we analyze a set of equations proposed by Hadeler and Kuttler [20 Hadeler , K. P. , Kuttler , C. ( 1999 ). Dynamical models for granular matter . Granular Matter 2 : 918 . [Google Scholar]], describing the flow of granular matter in terms of the heights of a standing layer and of a moving layer. By a suitable change of variables, the system can be written as a 2 × 2 hyperbolic system of balance laws, which we study in the one-dimensional case. The system is linearly degenerate along two straight lines in the phase plane, and therefore is weakly linearly degenerate at the point of the intersection. The source term is quadratic, consisting of product of two quantities, which are transported with strictly different speeds. Assuming that the initial height of the moving layer is sufficiently small, we prove the global existence of entropy-weak solutions to the Cauchy problem, for a class of initial data with bounded but possibly large total variation.  相似文献   
112.
A simulated annealing algorithm for transient optimization in gas networks   总被引:1,自引:0,他引:1  
In this paper we present a simulated annealing approach for the gas network optimization problem. A gas network consists of a set of pipes to transport the gas from the sources to the sinks whereby gas pressure gets lost due to friction. Further on there are compressors, which increase gas pressure, and valves. The aim is to minimize fuel gas consumption of the compressors whereas demands of consumers have to be satisfied. The problem of transient (time-dependent) optimization of gas networks results in a highly complex mixed integer nonlinear program. We relax the equations describing the gas dynamic in pipes by adding these constraints combined with appropriate penalty factors to the objective function. A suitable neighborhood structure is developed for the relaxed problem where time steps as well as pressure and flow of the gas are decoupled. Our approach convinces with flexibility and very good computational results.  相似文献   
113.
    
The effect of the presence of hexyl group in thiophene on the photophysical and electrochemical properties of poly[(9,9‐dioctyluorene)?2,7‐diyl‐alt‐(4,7‐bis(3‐hexylthien‐5‐yl)?2,1,3‐benzothiadiazole)?2′,2″‐diyl] (F8TBT) is investigated. The copolymers present electron donor–acceptor architecture and are synthesized by Suzuki coupling reaction. The UV/Vis spectra show absorption maximum in the wavelength range of blue and orange, which are associated with different segments of the polymer backbone. Addition of hexyl substituent groups has a positive effect on the molar absorptivity and increases the emission and absorption intensities due to fluorene and thiophene‐benzothiadiazole‐thiophene (TBT) units, although an increment in the bandgap is observed. Cyclic voltammetry study of the polymer films reveal irreversible reduction and oxidation processes of the TBT units in the polymer chain and the HOMO and LUMO energy levels suggest ambipolar character for the polymers, while the electrochemical bandgaps are consistent with the absorbance measurements. © 2016 Wiley Periodicals, Inc. J. Polym. Sci., Part B: Polym. Phys. 2016 , 54, 1975–1982  相似文献   
114.
The use of lipases as biocatalysts in ester synthesis has been the object of growing interest, owing to the importance of esters as emulsifiers, intermediates to produce oleochemicals, and fuel alternatives. We consider in this report the application of lipases in the ethanolysis of palm and palm kernel oils to produce fatty-acid esters, using n-hexane assolvent. In order to maximize ester production, wea dopted a Taguchi design and built an empirical model. Using this procedure, we determined the optimal condition for each system and established the influence of process variables in the conversion.  相似文献   
115.
Changeable Silly Putty is a thermochromic material. It changes color due to a change in temperature. This paper describes advanced experiments designed to find the mechanism of the color change, provides a discussion of proposed mechanisms, and describes three experiments using Changeable Silly Putty that are suitable for young children.  相似文献   
116.
We consider the Cauchy problem for n×n strictly hyperbolic systems of nonresonant balance laws each characteristic field being genuinely nonlinear or linearly degenerate. Assuming that and are small enough, we prove the existence and uniqueness of global entropy solutions of bounded total variation as limits of special wave-front tracking approximations for which the source term is localized by means of Dirac masses. Moreover, we give a characterization of the resulting semigroup trajectories in terms of integral estimates.  相似文献   
117.
    
OH⋅-induced oxidation products of DNA nucleosides and nucleotides have been structurally characterized by collision-induced dissociation tandem mass spectrometry (CID-MS2) and Infrared Multiple Photon Dissociation (IRMPD) spectroscopy. CID-MS2 results have shown that the addition of one oxygen atom occurs on the nucleobase moiety. The gas-phase geometries of +16 mass increment products of 2’-deoxyadenosine (dA(O)H+), 2’-deoxyadenosine 5’-monophosphate (dAMP(O)H+), 2’-deoxycytidine (dC(O)H+), and 2’-deoxycytidine 5’-monophosphate (dCMP(O)H+) are extensively investigated by IRMPD spectroscopy and quantum-chemical calculations. We show that a carbonyl group is formed at the C8 position after oxidation of 2’-deoxyadenosine and its monophosphate derivative. For 2’-deoxycytidine and its monophosphate derivative, the oxygen atom is added to the C5 position to form a C−OH group. IRMPD spectroscopy has been employed for the first time to provide direct structural information on oxidative lesions in DNA model systems.  相似文献   
118.
    
A series of 16 dinuclear thiopyridone-based organometallics with excellent water solubility, increased stability and remarkable cytotoxicity were synthesized and characterized. The complexes of this work formed dimeric species featuring a double positive charge in polar protic solvents, accounting for their outstanding solubility in aqueous solution. Most of them displayed higher antiproliferative activity than their parental thiomaltol complex, with unexpected cytotoxicity trends depending on the employed metal center, ligand modification, and cell line. Insights into their behavior in biological systems were gathered by means of amino-acid interaction studies, cytotoxicity tests in 3D spheroid models, laser ablation, cellular accumulation measurements, as well as cell cycle experiments.  相似文献   
119.
    
Metal–organic framework (MOF)-driven synthesis is considered as a promising alternative for the development of new catalytic materials with well-designed active sites. This synthetic approach is used here to gradually transform a new bimetallic MOF, with Pd and Fe as the metal components, by the in situ generation of aniline under mild conditions. This methodology results in a compositionally homogeneous nanocomposite formed by Fe-doped Pd nanoparticles that, in turn, are supported on iron oxide-doped carbon. The nanocomposite has been fully characterized by several techniques such as IR and Raman spectroscopy, TEM, XPS, and XAS. The performance of this nanocomposite as an heterogeneous catalyst for hydrogenation of nitroarenes and nitrobenzene coupling with benzaldehyde has been evaluated, proving it to be an efficient and reusable catalyst.  相似文献   
120.
    
Preparation of supported metal catalysts with uniform particle size and coordination environment is a challenging and important topic in materials chemistry and catalysis. In this work, we report the regioselective generation of single‐site Ir atoms and their evolution into stabilized subnanometric Ir clusters in MWW zeolite, which are located at the 10MR window connecting the two neighboring 12MR supercages. The size of the subnanometric Ir clusters can be controlled by the post‐synthesis treatments and maintain below 1 nm even after being reduced at 650 °C, which cannot be readily achieved with samples prepared by conventional impregnation methods. The high structure sensitivity, size‐dependence, of catalytic performance in the alkane hydrogenolysis reaction of Ir clusters in the subnanometric regime is evidenced.  相似文献   
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