Enhanced Green Emission from Er<Subscript>2</Subscript>WO<Subscript>6</Subscript> Nanocrystals Embedded Composite Tellurite Glasses

A series of tungsten-tellurite glasses activated with different concentrations (0–1.5 mol %) of Er³⁺ has been synthesized. The structural properties of the best luminescent sample and the optical properties of its Er³⁺ ions, are studied both immediate after its preparation as well as after its ageing. On ageing the glass suffers structural reorganization and generates Er₂WO₆—nanocrystals in the matrix, which greatly enhances the normal and upconversion green luminescence efficiency of Er³⁺. The nanocrystal aided enhancement of normal and upconversion luminescence of Er³⁺ of the glass has been attributed to the crystal field effects of the new environment of Er³⁺ in the nanocrystals. A phenomenon of preferential enhancement of red upconversion luminescence at the cost of green upconversion luminescence of Er³⁺ at its higher concentrations in the glass has been observed and the related photo-physics is proposed. The material shows the prospect of being used as NIR solar concentrator.     

Statistical convergence in intuitionistic fuzzy n-normed linear spaces

The aim in our article is to introduce the notion of statistical convergence and statistically Cauchy sequences in intuitionistic fuzzy n-normed linear spaces. The paper shows that some properties of statistical convergence of real sequences also hold for sequences in this space. Characterization for statistically convergent and statistically Cauchy sequences is also given. Further, the concept of statistical limit points and statistical cluster points are introduced and their relation with limit points of sequences have been investigated.     

Dynamics of Logamediate and Intermediate Scenarios in the Dark Energy Filled Universe

We have considered a model of two component mixture i.e., mixture of Chaplygin gas and barotropic fluid with tachyonic field. In the case, when they have no interaction then both of them retain their own properties. Let us consider an energy flow between barotropic and tachyonic fluids. In both the cases we find the exact solutions for the tachyonic field and the tachyonic potential and show that the tachyonic potential follows the asymptotic behavior. We have considered an interaction between these two fluids by introducing a coupling term. Finally, we have considered a model of three component mixture i.e., mixture of tachyonic field, Chaplygin gas and barotropic fluid with or without interaction. The coupling functions decays with time indicating a strong energy flow at the initial period and weak stable interaction at later stage. To keep the observational support of recent acceleration we have considered two particular forms (i) Logamediate Scenario and (ii) Intermediate Scenario, of evolution of the Universe. We have examined the natures of the recent developed statefinder parameters and slow-roll parameters in both scenarios with and without interactions in whole evolution of the universe.     

Correspondence Between Ricci and Other Dark Energies

Purpose of the present paper is to view the correspondence between Ricci and other dark energies. We have considered the Ricci dark energy in presence of dark matter in non-interacting situation. Subsequently, we have derived the pressure and energy density for Ricci dark energy. The equation of state parameter has been generated from these pressure and energy density. Next, we have considered the correspondence between Ricci and other dark energy models, namely tachyonic field, DBI-essence and new agegraphic dark energy without any interaction and investigated possible cosmological consequences.     

A facile strategy for the fabrication of uniform CdS nanowires with high yield and its controlled morphological growth with the assistance of PEG in hydrothermal route

A series of novel wurtzite cadmium sulphide (CdS) nanowires with uniform diameter were synthesized by using a rapid and simple solvothermal route. CdS nano structures with certain morphology could be selectively produced by only varying the concentration of poly ethylene glycol (PEG) as a surfactant in the reaction system with cadmium acetate, sulphur powder and ethelynediamine (EDA). We extensively studied UV-vis absorption spectra, photoluminescence spectra after confirming CdS nanowires with diameter 24-25 nm and length ranging up to several nano meters by field emission scanning electron microscopy (FE-SEM). Therefore we may definitely propose a new formation mechanism of CdS nanowires assisted by PEG with its illustrating optical properties.     

Synthesis of novel dihydrooxazine and oxazoline based sugar hybrids from sugar azides

A convenient one-step method for the synthesis of novel dihydrooxazine and oxazoline based sugar hybrids is reported starting from the readily accessible sugar azides and aldehydes. We have used Aubé’s protocol to achieve this transformation. The resulting glycoconjugates could be used to increase the diversity on the sugar backbone and may find applications as potential glycomimetics and in drug discovery.     

Kinetics and mechanisms of substitution of aqua-ligands in cis-diaqua-bis(bipyridyl)ruthenium(ll) ion by L-cysteine in aqueous medium

Transition Metal Chemistry - The title reaction has been studied spectrophotometrically and a rate-law established within the pH range 5.0 to 6.5, $$ {?...     

On three dimensional transient wave motions on a running stream

Summary This paper considers the three-dimensional transient wave motions in a fluid produced by a moving oscillatory disturbance of frequency acting on the free surface of the fluid. The problem is treated as an initial value problem and is solved by the joint Laplace-Fourier transform method combined with the asymptotic treatment for the double Fourier inversion integrals. The explicit representation of the steady state as well as the transient solution of the problem is presented. It is shown that the ultimate steady is set up in the limit. A brief discussion on the principal behaviour of the wave motions is made.

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Sommario Si considerano i moti ondosi transitori tridimensionali prodotti in un fluido da una eccitazione oscillatoria, in movimento, di frequenza che agisce sulla superficie libera. Il problema è trattato come problema di valori iniziali e viene risolto con il metodo della trasformata congiunta di Laplace-Fourier combinata con il trattamento asintotico per gli integrali doppi di inversione di Fourier. Si espone la rappresentazione in forma esplicita della soluzione di regime e di quella transitoria. Si dimostra che la condizione finale di regime viene stabilita nel passaggio al limite. Si esegue una breve discussione del principale comportamento del moto ondoso.