High spin states in 121Te

High spin states of ¹²¹Te, populated in the ¹¹⁴Cd (¹¹B, p3n) reaction, have been studied through γ-ray spectroscopy. The level scheme has been established up to J^π = 51/2^?. Three-quasiparticle states, based on the ^πg _7/2 ² ? vh_11/2 and πg _7/2d_5/2 ? vh_11/2 configurations, have been identified. A favoured 39/2^? state is suggested to be the fully aligned [πg_7/2 ²]6 + ? [vh _11/2 ³]_27/2? yrast non-collective oblate configuration. This assignment is supported by Total Routhian Surface (TRS) calculations which also suggest a similar oblate assignment to the states at J^π = 21/2^? and 23/2^?. A higher 47/2^? state is also found and is suggested to be the fully aligned [πg_7/2 ²]₆+ ? [vh _11/2 ⁵]_35/2? configuration.     

Shape changes at high spin in 78Kr

High-spin states in ⁷⁸Kr have been studied via the ⁶³Cu (¹⁹F, 2p2n)⁷⁸Kr reaction at a beam energy of 60 MeV using the Indian National Gamma Array (INGA). In this nucleus, lifetimes have been measured upto the I^π=22⁺ level in the yrast positive-parity band and upto the I^π=15^- level in the negative-parity band using the Doppler Shift Attenuation Method (DSAM). The deduced transition quadrupole moments Q_t's are found to decrease with rotational frequency for both the bands.     

High spin states in102Ag

High spin states are populated in¹⁰²Ag using the reaction¹⁶O+⁸⁹Y with projectile energies in the energy range 60–80 MeV. Gamma multipolarities are inferred from DCO ratios and coincidence relationships are established among the gamma rays assigned to¹⁰²Ag. A comprehensive level scheme is constructed with four band systems, two of positive parity and the other two of negative parity. The present study extended spins upto 19^– in the main negative parity band. A new band is populated in the present work and is similar to the one observed in¹⁰⁶Ag.The authors wish to thank and record their appreciation to Dr. S.K. Parthasaradhi, VECC, Calcutta for preparing the target used in this experiment. The authors gratefully acknowledge useful discussions with Dr. Rakhesh Popli. The authors record their grateful thanks to Prof. A.P. Patro and Prof. G.K. Mehta, former and present directors of the Nuclear Science Centre, for their interest in this work, helpful discussions and providing excellent facilities. The authors also thank Dr. S.K. Datta of the Nuclear Science Centre for his continued interest and helpful discussions and accelerator staff of N.S.C. for their efficient services in delivering the beam. Grateful thanks are also due to the University Grants Commission for providing financial support.     

Spectroscopy and lifetime measurement of high spin states in 73Se

The nucleus ⁷³ Se was studied by the reaction ⁵¹ V(²⁸ Si,αpn)⁷³ Se. The level scheme extended upto $\frac{{41}} {2}\bar h $ in both +ve and ?ve parity bands with 10 new transitions placed in the level scheme. Lifetimes of 17 high spin states measured by DSAM. The transitional quadrupole moment is found to drop down after the band crossing suggesting a less deformed configuration. At the band crossing region, Q _t increases suddenly in both +ve and ?ve parity bands. It is argued that the +ve parity band is a decoupled band.     

On some results of A. E. Livingston and coefficient problems for concave univalent functions

We consider functions that map the open unit disc conformally onto the complement of a bounded convex set. We call these functions concave univalent functions. In 1994, Livingston presented a characterization for these functions. In this paper, we observe that there is a minor flaw with this characterization. We obtain certain sharp estimates and the exact set of variability involving Laurent and Taylor coefficients for concave functions. We also present the exact set of variability of the linear combination of certain successive Taylor coefficients of concave functions.     

A self-assembled, luminescent europium cholate hydrogel: a novel approach towards lanthanide sensitization

We propose a new self-assembly based strategy for the design of novel lanthanide based luminescent materials. In this approach a europium hydrogel is prepared and sensitization is achieved by doping the gel with pyrene in a non-coordinated fashion.     

Solution,thermal and optical properties of novel poly(pyridinium salt)s derived from conjugated pyridine diamines

Several novel poly(pyridinium salt)s with heterocyclic pyridine moieties in their backbones with tosylate and triflimide counterions were prepared by either ring‐transmutation polymerization reaction of phenylated‐bis(pyrylium tosylate) with isomeric pyridine diamines of 4‐phenyl‐2,6‐bis(4‐aminophenyl)pyridine in dimethyl sulfoxide (DMSO) for 48 h at 130–140 °C or by metathesis reaction of the respective tosylate polymers with lithium triflimide in DMSO at about 60 °C. Their chemical structures were characterized by FTIR, ¹H, ¹³C NMR spectroscopy, and elemental analysis. Their number‐average molecular weights (M_n) were in the range of 8,000–51,000 and their polydispersities in the range of 1.18–2.13 as determined by gel permeation chromatography. They had excellent thermal stabilities of 340–458 °C and high glass transition temperatures >200 °C. As they showed good solubilities in common organic solvents, their solution properties were also characterized for their lyotropic liquid‐crystalline properties with polarizing optical microscopy (POM) studies. Their photoluminescent properties were examined by using a spectrofluorometer in both solution and solid states. Their quantum yields were rather low, which were in the range of 1.3–2.0%. Additionally, hand‐drawn fibers from the melts were examined to determine their morphologies with a number of microscopic techniques including POM, scanning electron microscopy, and transmission electron microscopy. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2010     

Level structure of 99Rh at high spins

High spins states in ⁹⁹Rh were populated via the ⁶⁶Zn(³⁷Cl, 2p2n)⁹⁹Rh reaction at an incident beam energy of 130 MeV. Seventeen new transitions have been observed in the present study and the level scheme has now been extended up to a spin of J∼ 25ħ and an excitation energy of about E _x∼ 10 MeV. The observation of a positive parity E2 cascade based on the 9/2⁺ isomeric level is suggestive of collective behaviour in this nucleus up to high spins. Spherical shell model (within restricted model space) and Cranked shell model calculations were performed to obtain an insight into the observed level structure. The new collective band observed up to a spin of J∼ 25ħ is suggested to be based on (πg _9/2 ³) ⊗ (νg _7/2 ²) quasi-particle excitations. Received: 12 July 1999 / Revised version: 14 September 1999