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51.
Sarma DD Ray S Tanaka K Kobayashi M Fujimori A Sanyal P Krishnamurthy HR Dasgupta C 《Physical review letters》2007,98(15):157205
We present magnetization (M) and magnetoresistance (MR) data for a series of Sr2FeMoO6 samples with independent control on antisite defect and grain-boundary densities, which reveal several unexpected features, including a novel switching-like behavior of MR with M. These, in conjunction with model calculations, establish that the MR in Sr2FeMoO6 is dominantly controlled by a new mechanism, derived from the magnetic polarization of grain-boundary regions acting like spin valves, leading to behavior qualitatively different from that usually encountered in tunneling MR. We show that a simple and useful experimental signature for the presence of this spin-valve-type MR (SVMR) is a wider hysteresis in MR compared to that in M. 相似文献
52.
Tamoghna Bhattacharyya Arumoy Chatterjee Budhaditya Chatterjee Sufi O. Raja Anjan Kr. Dasgupta 《Electrophoresis》2015,36(24):3009-3013
We report both the experimental and theoretical insights of differential electro‐diffusion behavior of carbon nanomaterials (e.g. single wall, multiwall carbon nanotubes, and graphene). We thus discriminate one from the other in a soft gel system. The differential mobility of such material depends on their intrinsic properties, both extend and rate of migration bearing the discriminatory signature. The mobility analysis is made by a real time monitoring of the respective bands. 相似文献
53.
54.
Kumar H Mukherjee B Lin ST Dasgupta C Sood AK Maiti PK 《The Journal of chemical physics》2011,134(12):124105
Experiments and computer simulations demonstrate that water spontaneously fills the hydrophobic cavity of a carbon nanotube. To gain a quantitative thermodynamic understanding of this phenomenon, we use the recently developed two phase thermodynamics method to compute translational and rotational entropies of confined water molecules inside single-walled carbon nanotubes and show that the increase in energy of a water molecule inside the nanotube is compensated by the gain in its rotational entropy. The confined water is in equilibrium with the bulk water and the Helmholtz free energy per water molecule of confined water is the same as that in the bulk within the accuracy of the simulation results. A comparison of translational and rotational spectra of water molecules confined in carbon nanotubes with that of bulk water shows significant shifts in the positions of the spectral peaks that are directly related to the tube radius. 相似文献
55.
A two-dimensional (2-D) “heart-cutting” HPLC system was used to fractionate oligostyrenes into the respective diastereoisomers. For samples of known composition, the response of an ultraviolet (UV) absorbance detector followed the anticipated pattern. The response of an evaporative light-scattering (ELSD) detector on the other hand indicated quite different concentrations for the two diastereoisomers, relative to what was anticipated and what was indicated by the UV detector. Whereas approximately the same concentration was indicated by UV, ELSD in some cases indicated no detection of the later eluting isomer. The magnitude of the errors depended on both the molecular weight and the tacticity of the diastereomers. These anomalies appear to be an artifact of power transform functions imbedded within the firmware processor of the ELSD, invisible to the user. 相似文献
56.
Dasgupta S Banerjee K Utture S Kusari P Wagh S Dhumal K Kolekar S Adsule PG 《Journal of chromatography. A》2011,1218(38):6780-6791
57.
Dong SS Nielsen RJ Palmer JH Gray HB Gross Z Dasgupta S Goddard WA 《Inorganic chemistry》2011,50(3):764-770
The electronic structures of metallocorroles (tpfc)M(NH(3))(2) and (tfc)M(NH(3))(2) (tpfc is the trianion of 5,10,15-(tris)pentafluorophenylcorrole, tfc is the trianion of 5,10,15-trifluorocorrole, and M = Co, Rh, Ir) have been computed using first principles quantum mechanics [B3LYP flavor of Density Functional Theory (DFT) with Poisson-Boltzmann continuum solvation]. The geometry was optimized for both the neutral systems (formal M(III) oxidation state) and the one-electron oxidized systems (formally M(IV)). As expected, the M(III) systems have a closed shell d(6) configuration; for all three metals, the one-electron oxidation was calculated to occur from a ligand-based orbital (highest occupied molecular orbital (HOMO) of B(1) symmetry). The ground state of the formal M(IV) system has M(III)-Cπ character, indicating that the metal remains d(6), with the hole in the corrole π system. As a result the calculated M(IV/III) reduction potentials are quite similar (0.64, 0.67, and 0.56 V vs SCE for M = Ir, Rh and Co, respectively), whereas the differences would have been large for purely metal-based oxidations. Vertically excited states with substantial metal character are well separated from the ground state in one-electron-oxidized cobalt (0.27 eV) and rhodium (0.24 eV) corroles, but become closer in energy in the iridium (0.15 eV) analogues. The exact splittings depend on the chosen functional and basis set combination and vary by ~0.1 eV. 相似文献
58.
Hrishikesh E. Patel T. Sundararajan T. Pradeep A. Dasgupta N. Dasgupta Sarit K. Das 《Pramana》2005,65(5):863-869
Increase in the specific surface area as well as Brownian motion are supposed to be the most significant reasons for the anomalous
enhancement in thermal conductivity of nanofluids. This work presents a semi-empirical approach for the same by emphasizing
the above two effects through micro-convection. A new way of modeling thermal conductivity of nanofluids has been explored
which is found to agree excellently with a wide range of experimental data obtained by the present authors as well as the
data published in literature 相似文献
59.
D.J. Hinde A.C. Berriman R.D. Butt M. Dasgupta C.R. Morton A. Mukherjee J.O. Newton 《The European Physical Journal A - Hadrons and Nuclei》2002,13(1-2):149-154
In the fusion of heavy nuclei, there is a distribution of fusion barrier energies resulting from coupling between intrinsic
motion and internal degrees of freedom. Precise experimental measurements of excitation functions have allowed the extraction
of the distributions by taking the second derivative using a point-difference method. In the case of statically deformed nuclei,
experimental data shows that the different fusion barrier energies correspond to different physical configurations of the
colliding nuclei, the latter affecting the subsequent dynamical trajectories over the potential energy surface, influencing
the ultimate reaction products, as for example in quasi-fission. The fusion barrier distribution is also valuable in understanding
the fusion of weakly bound nuclei, enabling a reliable prediction of the expected fusion cross-sections, and thus the determination
of fusion suppression factors at above-barrier energies.
Received: 1 May 2001 / Accepted: 4 December 2001 相似文献
60.
Eikonalization of dual pole amplitudes, such as the Veneziano amplitude, is shown to lead to singularities in the impact parameter
plane, which, in the eikonal approximation, may be interpreted as branch points in the direct channel angular momentum plane.
This result is discussed in the light of dual absorption models. 相似文献