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41.
Ludmila V Roze Anindya Chanda Maris Laivenieks Randolph M Beaudry Katherine A Artymovich Anna V Koptina Deena W Awad Dina Valeeva Arthur D Jones John E Linz 《BMC biochemistry》2010,11(1):33
Background
Filamentous fungi in the genus Aspergillus produce a variety of natural products, including aflatoxin, the most potent naturally occurring carcinogen known. Aflatoxin biosynthesis, one of the most highly characterized secondary metabolic pathways, offers a model system to study secondary metabolism in eukaryotes. To control or customize biosynthesis of natural products we must understand how secondary metabolism integrates into the overall cellular metabolic network. By applying a metabolomics approach we analyzed volatile compounds synthesized by Aspergillus parasiticus in an attempt to define the association of secondary metabolism with other metabolic and cellular processes. 相似文献42.
The field equations for the chiral invariant model of pion dynamics developed by Charap have been revisited. Two new types
of solutions of these equations have been obtained. Each type allows infinite number of solutions. It has also been shown
that the chiral invariant field equations admit invariance for a transformation of the dependent variables. 相似文献
43.
Ruthenium-terpyridine complexes incorporating a 2,2'-dipyridylamine ancillary ligand [Ru(II)(trpy)(L)(X)](ClO(4))(n) [trpy = 2,2':6',2' '-terpyridine; L = 2,2'-dipyridylamine; and X = Cl(-), n = 1 (1); X = H(2)O, n = 2 (2); X = NO(2)(-), n = 1 (3); X = NO(+), n = 3 (4)] were synthesized in a stepwise manner starting from Ru(III)(trpy)(Cl)(3). The single-crystal X-ray structures of all of the four members (1-4) were determined. The Ru(III)/Ru(II) couple of 1 and 3 appeared at 0.64 and 0.88 V versus the saturated calomel electrode in acetonitrile. The aqua complex 2 exhibited a metal-based couple at 0.48 V in water, and the potential increased linearly with the decrease in pH. The electron-proton content of the redox process over the pH range of 6.8-1.0 was calculated to be a 2e(-)/1H(+) process. However, the chemical oxidation of 2 by an aq Ce(IV) solution in 1 N H(2)SO(4) led to the direct formation of corresponding oxo species [Ru(IV)(trpy)(L)(O)](2+) via the concerted 2e(-)/2H(+) oxidation process. The two successive reductions of the coordinated nitrosyl function of 4 appeared at +0.34 and -0.34 V corresponding to Ru(II)-NO(+) --> Ru(II)-NO* and Ru(II)-NO* --> Ru(II)-NO(-), respectively. The one-electron-reduced Ru(II)-NO* species exhibited a free-radical electron paramagnetic resonance signal at g = 1.990 with nitrogen hyperfine structures at 77 K. The NO stretching frequency of 4 (1945 cm(-1)) was shifted to 1830 cm(-1) in the case of [Ru(II)(trpy)(L)(NO*)](2+). In aqueous solution, the nitrosyl complex 4 slowly transformed to the nitro derivative 3 with the pseudo-first-order rate constant of k(298)/s(-1) = 1.7 x 10(-4). The chloro complex 1 exhibited a dual luminescence at 650 and 715 nm with excited-state lifetimes of 6 and 1 micros, respectively. 相似文献
44.
Rahul Bhattacharya Sumana Chanda Andrea Cantoni Gabriele Bocelli Ashutosh Ghosh 《Journal of chemical crystallography》2004,34(5):325-331
The crystal structures of benzimidazolium tetrahalocobaltates (HBz)2[CoX4] (X = Cl and Br) have been determined. The chloride salt is triclinic, P-1, with a = 7.670(3) Å, b = 8.307(3) Å, c = 15.730(2) Å, and = 87.37(3)°, = 84.99(3)°, = 67.72(2)°. The bromide salt is monoclinic, C2/c, with a = 15.568(2) Å, b = 8.063(3) Å, c = 5.762(2) Å and = 91.36(3)°. The structures of the two salts are closely related. Both the compounds contain isolated tetrahedral CoX4
2– anions and benzimidazolium cations. In the chloride salt, three chloride ions are involved in strong hydrogen bonding while only two bromide ions participate in the bromide salt. The greater deviation from the ideal tetrahedral geometry in CoBr4
2– can be related to the less extensive hydrogen-bonding network compared to the chloro complex. 相似文献
45.
The inhomogeneous vertical turbulent convection in the planetary boundary layer has been analysed. The governing equation is the three dimensional advection equation. With the help of a model of the temperature-velocity correlation the advection equation is transformed into a solvable equation. Numerical solution has been obtained for some particular conditions. 相似文献
46.
Painlevé test for integrability for the combined equations generated from Yang’s self-dual equations for SU (2) gauge fields and Charap’s equations for chiral invariant model of pion dynamics faces some peculiar situations that allow
none of the stages (leading order analysis, resonance calculation and checking of the existence of the requisite number of
arbitrary functions) to be conclusive. It is also revealed from a comparative study with the previous results that the existence
of abnormal behaviour at any of the stated stages may have a correlation with the existence of chaotic property or some other
properties that do not correspond to solitonic behaviour.
相似文献
47.
Madhukar N.?JachakEmail author Chanda D.?Tantak Raghunath B.?Toche Naresh S.?Badgujar 《Monatshefte für Chemie / Chemical Monthly》2004,135(12):1529-1538
Summary. A series of ureidopropenenitriles were synthesised by Knoevenagel condensation of ArCOCH2CN and HC(OEt)3 in presence of ureas in a one pot reaction. These ureidopropenenitriles were cyclised to 4-aryl-5-cyano-3-substituted pyrimidines (in acid) or to 4-amino-5-benzoylpyrimidines (in base) in 60–70% yields. The amine pyrimidine derivatives were further converted to substituted uracils by hydrolysis with isopentyl nitrite in DMF. Alkylation of uracils furnished 1,3-dimethyluracil derivatives with DMS in alkali. All new compounds were characterised by spectral and analytical methods. 相似文献
48.
A theoretical framework has been proposed to study patternsof innovation diffusion in a heterogeneous population, withapplicability to a number of problem areas including marketing.The heterogeneity in the population is captured through randomlyvarying parameters, which have been modelled in terms of two-pointdistributions. The effect of heterogeneity leads to the generationof bi-modal life cycle patterns besides the conventional uni-modalpattern resulting from S-shaped curve. The stochastic evolutionof the mean and variance of the number of adopters is foundto depict a high level of relative fluctuation around the pointof inflexion. As a result of randomness in parameters, the resultingdifferential equation for the evolution of the mean of the adoptionprocess is characterized by a non-autonomous system having parameterswhich are no longer constant but become time dependent. Fordemonstrating the effectiveness of the proposed framework, areal data set which depicts a bi-modal life cycle curve is investigated.The fit is found to be extremely good while capturing appropriateproduct life cycle curve. 相似文献
49.
Sushobhan Chowdhury Tanmoy Chanda Suvajit Koley B. Janaki Ramulu Keshav Raghuvanshi Maya Shankar Singh 《Tetrahedron》2014
β-Allyl-β-hydroxy dithioesters have been employed in the synthesis of hitherto unreported and synthetically demanding 2H-thiopyrans via regioselective intramolecular annulation strategy. Lewis acid BF3·Et2O efficiently mediates the regioselective dehydration followed by intramolecular thioannulation at room temperature. The attractive features of this protocol include mild conditions, high atom-economy and excellent yields with the elimination of water as the only by-product. 相似文献
50.
Madhukar N. Jachak Chanda D. Tantak Raghunath B. Toche Naresh S. Badgujar 《Monatshefte für Chemie / Chemical Monthly》2004,30(5):1529-1538
A series of ureidopropenenitriles were synthesised by Knoevenagel condensation of ArCOCH2CN and HC(OEt)3 in presence of ureas in a one pot reaction. These ureidopropenenitriles were cyclised to 4-aryl-5-cyano-3-substituted pyrimidines (in acid) or to 4-amino-5-benzoylpyrimidines (in base) in 60–70% yields. The amine pyrimidine derivatives were further converted to substituted uracils by hydrolysis with isopentyl nitrite in DMF. Alkylation of uracils furnished 1,3-dimethyluracil derivatives with DMS in alkali. All new compounds were characterised by spectral and analytical methods. 相似文献