Theoretical studies of electric quadrupole transition probabilities in Mg II

The relativistic coupled cluster theory is employed to calculate electric quadrupole (E2) transition probabilities among the doublet states of Mg II which are of interest in astrophysical problems. This is the first time a highly correlated fully ab initio method has been used to compute these quantities for this particular ion. The line strengths and transition probabilities of a number of different transitions are reported and compared with those available in the literature.Received: 4 June 2003, Published online: 30 September 2003PACS: 31.10. + z Theory of electronic structure, electronic transitions, and chemical bindingSonjoy Majumder: Present address: Institut für Theoretische Chemie, Technische Universität München, 85747 Garching, Germany.     

Absorption spectrometric study of charge transfer complex formation between 4-acetamidophenol (paracetamol) and a series of quinones including vitamin K3

The formation of charge transfer (CT) complexes of 4-acetamidophenol (commonly called 'paracetamol') and a series of quinones (including Vitamin K3) has been studied spectrophotometrically in ethanol medium. The vertical ionisation potential of paracetamol and the degrees of charge transfer of the complexes in their ground state has been estimated from the trends in the charge transfer bands. The oscillator and transition dipole strengths of the complexes have been determined from the CT absorption spectra at 298 K. The complexes have been found by Job's method of continuous variation to have the uncommon 2:1 (paracetamol:quinone) stoichiometry in each case. The enthalpies and entropies of formation of the complexes have been obtained by determining their formation constants at five different temperatures.     

The mass of 22Mg

Mass measurements with a relative precision of better than 1.5 x 10(-8) were performed on 22Mg and its reaction partners 21Na and 22Na with the ISOLTRAP Penning trap mass spectrometer at CERN, yielding the mass excesses D(22Mg)=-399.92(27) keV, D(21Na)=-2184.71(21) keV, and D(22Na)=-5181.56(16) keV. The importance of these results is twofold. First, a comparative half-life (Ft value) has been obtained for the superallowed beta decay of 22Mg to further test the conserved-vector-current hypothesis. Second, the resonance energy for the 21Na proton capture reaction has been independently determined, allowing direct comparisons of observable gamma radiation in nova explosions with the yield expected from models.     

Dialgebra cohomology as a G-algebra

It is well known that the Hochschild cohomology of an associative algebra admits a G-algebra structure. In this paper we show that the dialgebra cohomology of an associative dialgebra has a similar structure, which is induced from a homotopy G-algebra structure on the dialgebra cochain complex .

     

Highly efficient epoxidation method of olefins with hydrogen peroxide as terminal oxidant, bicarbonate as a co-catalyst and oxodiperoxo molybdenum(VI) complex as catalyst

A combination of the newly synthesized and structurally characterized compound, [MoO(O2)2(saloxH)](saloxH2= salicylaldoxime) as catalyst, H2O2 as terminal oxidant and NaHCO3 as co-catalyst when stirred in CH3CN (10 cm3) at room temperature (rt) shows a very pronounced efficiency epoxidation of olefinic compounds, the method being green and economical.     

Multiphonon vibrations at high angular momentum in 182 Os

Evidence is presented for multiphonon excitations based on a high-spin (25 Planck) intrinsic state in the deformed nucleus 182 Os. Angular momentum generation by this mode competes with collective rotation. The experimental data are compared with tilted-axis cranking calculations, supporting the vibrational interpretation. However, the lower experimental energies provide evidence that more complex interactions of states are playing a role.     

Stereocontrolled total syntheses of (±)-clovan-3-one and (±)-epi-clovan-3-one and a facile total synthesis of (±)-pseudoclovene-A

Stereocontrolled total syntheses of the bridged tricyclic ketones (±)-clovan-3-one (5) and (±)-epi-clovan-3-one (6) and a facile total synthesis of the tricyclic sesquiterpene (±)-pseudoclovene-A (3) have been successfully accomplished involving participation of an aryl intramolecular cyclisation of the bromophenol 11 as a key step.     

Bioinspired synthesis of new silica structures

Silicon and oxygen are the two most abundant elements in the Earth's crust but despite the vast scientific literature on crystalline and amorphous silica, new chemistries, structures and applications continue to be discovered for compounds formed from these elements--thus we present here for the first time the formation of new amorphous silica structures that were uniquely synthesized by a bioinspired synthetic system.     

A unique series of dinuclear transition metal-polyradical complexes with a m-phenylenediamine spacer and their catalytic reactivity

A series of dinuclear transition metal complexes with either six or four iminosemiquinone radicals, in which the metal centres are separated by a distance of approximately 6.8 A, together with their catalytic reactivity is reported.     

On a generalised<Emphasis Type="Italic">ε</Emphasis>-control problem in Banach space

In this paper a linearε-control problem for a general objective function is considered by functional analytic approach. Existence and uniqueness of solutions are shown. The characterization of the solution is given in terms of a hyperplane.