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11.
Summary A reversed-phase liquid chromatographic method with sodium dodecylsulphate-n-propanolwater as mobile phase has been used to separate and determine six water-soluble vitamins in twelve minutes. The analytical
characteristics linear range, sensitivity, detection limits, and precision were evaluated. The lowest detection limits were
those of nicotinic acid (not usually present in pharmaceutical products), 0.7 mgL−1, nicotinamide, 1.3 mg L−1, and pyridoxine, 1.4 mg L−1. When the method was applied to the determination of the vitamins in pharmaceutical samples the values found agreed with
those on the labels. 相似文献
12.
Turner DR Henry M Wilkinson C McIntyre GJ Mason SA Goeta AE Steed JW 《Journal of the American Chemical Society》2005,127(31):11063-11074
Four isomorphous complexes of formula [M(L)(4)(H(2)O)(2)]SO(4).2H(2)O (M = Co, 1a; Ni, 1b; Cu, 1c; Zn, 1d) have been isolated and characterized by single-crystal X-ray diffraction and neutron diffraction using the quasi-Laue diffractometer VIVALDI at the Institut Laue-Langevin as well as by thermogravimetric analysis. The structures contain a discrete, strongly hydrogen-bonded water tetramer which causes a significant distortion of the metal coordination sphere in each case. Partial atomic charges and hardness analysis (PACHA) calculations reveal that the shortest hydrogen bonds are not the strongest in this constrained, cyclic solid-state structure and show that the distortion at the metal center is caused by the drive to maintain the integrity of the water tetramer. The system undergoes a disorder-order transition on slow cooling that provides insight into the nature of communication between water squares. 相似文献
13.
Koji Yagi Veronica Garcia Ma. E. Rivas Javier Salas Andres Camargo Takeo Tabata 《Journal of inclusion phenomena and macrocyclic chemistry》1984,2(1-2):179-184
Some crown ethers were found to show significant antifungal activity against some wood-decay fungi, phytopathogenic fungi and eumycetes,Trichophytons for dermatomycosis. Their toxicity was evaluated by the paper disc method as well as by determining the values of ED50, i.e., the concentration which inhibits the mycelium growth by 50%. The fungi examined areTyromyces palustris, Picnoporous coccineus, Coriolous versicolor, Pyricularia filamentosa, Fusarium sp., Trichophyton rubrum, Trichophyton sp., etc. Among the 26 crown ethers tested, 3,5-di-t-butyl-benzo-15-crown-5 showed relatively high activity, the highest ED50 value of which being 8 M or 3 ppm. Other alkylbenzocrown ethers, dicyclohexyl crown ethers and Kryptofix 22DD also showed considerable activity. On the other hand, unsubstituted crown ethers, benzocrown ethers with a polar substituent, Kryptofix 222B and Kryptofix 221 were inactive. 相似文献
14.
15.
Jaime De Andres Antonio Aguilar Jorge Domenech 《Journal of polymer science. Part A, Polymer chemistry》1988,26(5):1323-1334
The kinetics of the reaction between atactic polypropylene (APP) and oxygen in bulk at temperatures ranging from 170 to 210°C and oxygen partial pressures from 160 to 760 torr have been studied by thermal differential analysis. The reaction takes place in two successive steps, both giving hydroperoxide groups as product. Partial reaction orders with respect to APP and oxygen for the first step, which corresponds to the uncatalyzed attack of a C? H tertiary bond to give a hydroperoxide, are one and two, respectively. In the second step, interpreted as another attack on a tertiary C? H by oxygen, catalyzed by a neighboring hydroperoxide group, reaction orders are one and one-half for APP and oxygen, respectively. Activation parameters have been determined and a reaction sequence is proposed. Hydroperoxidated APP subsequently decomposes via a zero-order process giving methylketone groups as its main product. An interpretation of this process is also given. 相似文献
16.
Y. Andres H. J. MacCordick J. -C. Hubert 《Journal of Radioanalytical and Nuclear Chemistry》1992,166(5):431-440
Biosorption of Th4+ and UO
2
2+
ions, both separately and in mixed equimolar ratio, was carried out using nitrate-buffered solutions of the cations at pH 1 in the presence of 5%w/w non-proliferative cell suspensions of Mycobacterium smegmatis. At equilibrium following a 3 h treatment, specific adsorption for 2 mM Th and U was, respectively, 102 and 115 mol g–1 dry biomass for individual solutions and 102 and 42 mol g–1 for the mixed 2/2 mM solution. Desorption studies of the cation-loaded biomass preparations in aqueous media and in soilbacterial suspensions within the pH range <1 to 11 showed that leaching of throium was generally less than 1% at pH 1–11 after 7 d, whereas uranium was leached to the extent of 2% at pH 1 and up to 10% under the same conditions in Th–U mixtures. 相似文献
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19.
Frutos LM Castano O Andres JL Merchan M Acuna AU 《The Journal of chemical physics》2004,120(3):1208-1216
Triplet energy transfer (TET) from aromatic donors to 1,3,5,7-cyclooctatetraene (COT) is an extreme case of "nonvertical" behavior, where the transfer rate for low-energy donors is considerably faster than that predicted for a thermally activated (Arrhenius) process. To explain the anomalous TET of COT and other molecules, a new theoretical model based on transition state theory for nonadiabatic processes is proposed here, which makes use of the adiabatic potential energy surfaces (PES) of reactants and products, as computed from high-level quantum mechanical methods, and a nonadiabatic transfer rate constant. It is shown that the rate of transfer depends on a geometrical distortion parameter gamma=(2g(2)/kappa(1))(1/2) in which g stands for the norm of the energy gradient in the PES of the acceptor triplet state and kappa(1) is a combination of vibrational force constants of the ground-state acceptor in the gradient direction. The application of the model to existing experimental data for the triplet energy transfer reaction to COT from a series of pi,pi(*) triplet donors, provides a detailed interpretation of the parameters that determine the transfer rate constant. In addition, the model shows that the observed decrease of the acceptor electronic excitation energy is due to thermal activation of C=C bond stretchings and C-C bond torsions, which collectively change the ground-state COT bent conformation (D(2d)) toward a planar triplet state (D(8h)). 相似文献
20.