可见/近红外光谱分析技术快速鉴别航天育种番茄

提出了利用可见/近红外光谱技术快速无损鉴别航天育种番茄品种的方法,采用偏最小二乘法对光谱特征信息进行提取,与神经网络结合建立番茄品种的鉴别模型.该模型将提取后的主成分作为神经网络的输入,加速了神经网络的训练速度.同时采用小波变换对大量光谱数据进行压缩,并结合神经网络建立番茄品种鉴别模型,该模型将压缩后的数据作为神经网络...     

基于相似度和改进雷达图的概率犹豫模糊多属性决策方法

为了解决属性权重未知的概率犹豫模糊多属性决策问题,构建基于相似度和改进雷达图的多属性决策方法。首先基于概率犹豫模糊元的信息完全度构建概率犹豫模糊集的距离测度和灰色关联系数,然后基于灰色关联理想解法定义了概率犹豫模糊集的相似度,最后根据概率犹豫模糊集的相似度和改进雷达图构建多属性决策模型,并通过案例进行了验证分析。     

Preparation and properties of SnS film grown by two-stage process

SnS films have been prepared by a novel two-stage process. It involved sputtering of Sn film on glass substrate and sulfurization of the thin metallic tin precursor layers in a vacuum furnace. The X-ray diffraction results showed that the SnS layers had orthorhombic structure and (0 4 0) preferential growth is more and more obvious with the increase of sulfurization time. The SnS film obtained by this work shows high optical absorption efficiency, and the film has a direct optical band gap of about 1.3 eV. The films show p-type conductivity and the resistivity of SnS film decreased obviously under illumination.     

Low-temperature liquid phase deposited TiO2 films on stainless steel for photogenerated cathodic protection applications

The low-temperature synthesis of anatase TiO₂ films was an imperative requirement for their application to corrosion prevention of metals. In this paper, a liquid phase deposition (LPD) technique was developed to prepare TiO₂ films on SUS304 stainless steel (304SS) at a relatively low temperature (80 °C). The as-prepared films were characterized using scanning electron microscopy (SEM), X-ray diffraction (XRD), Raman spectroscopy and X-ray photon spectroscopy (XPS). It was observed that a dense and crack-free anatase TiO₂ film with a thickness about 300 nm was obtained. The film contained some fluorine and nitrogen elements, and the amounts of these impurities were greatly decreased upon calcination. Under the white light illumination, the electrode potential of TiO₂ coated 304SS rapidly shifted to a more negative direction. Moreover, the photopotential of TiO₂/304SS electrode showed more negative values with increased film thickness. In conclusion, the photogenerated cathodic protection of 304SS was achieved by the low-temperature LPD-derived TiO₂ film.     

Magnetic moment of phonons in graphene induced by a magnetic field

A magnetic field not only changes the electronic structure in graphene but also affects the phonon excitations via the electron-phonon interaction and even enables the phonons to generate magnetism. In this paper, we evaluate the magnetic moment of phonons in graphene using a generating-functional technique. The calculation results indicate that the phonon magnetic moment exists only in a weak magnetic field. The step-like change of the magnetic moment with the magnetic field reflects a macroscopic quantum effect.     

Effect of surface oxidation on the surface condition and deuterium permeability of a palladium membrane

Oxidation and deoxidation of a Pd membrane was conducted in a quartz tube oven in a temperature range of 23-500 °C. The micromorphology and chemical composition of the Pd membrane surface was characterized using scanning electronic microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Micropores and PdO began to form on the Pd membrane surface after oxidation at 240 °C for 1 h and their quantity increased gradually with increasing temperature. A rough Pd membrane surface was obtained when the temperature rose to 500 °C. The PdO on the Pd membrane surface was completely deoxidized once more using H₂ at room temperature, but the rough surface morphology caused by oxidation remained. The deuterium permeability of the Pd membrane was tested using special equipment in the China National Key Laboratory and the results indicated that the rough Pd membrane surface had higher deuterium permeability than the original membrane. The improved deuterium permeability could be attributed to the higher Pd membrane surface area, which provided deuterium atoms with more adsorption sites and dissociation sites.     

Fermi surface, surface states, and surface reconstruction in Sr2RuO4

The electronic structure of Sr2RuO4 is investigated by high angular resolution ARPES at several incident photon energies. We address the controversial issues of the Fermi surface (FS) topology and the van Hove singularity at the M point, showing that a surface state and the replica of the primary FS due to sqrt[2]xsqrt[2] surface reconstruction are responsible for previous conflicting interpretations. The FS thus determined by ARPES is consistent with the de Haas-van Alphen results, and it provides additional information on the detailed shape of the alpha, beta, and gamma sheets.     

萃取-原子吸收分光光度法测定海水中痕量铜

本文建立了测定海水中痕量铜的新方法,以APDC－MIBK为络合萃取剂,原子吸收分光光度法测定,并研究了最佳测定条件。该法简便、快速,具有良好的精密度和准确度,测定结果令人满意。     

间接原子吸收光谱法测定水样中的痕量硼

本文研究了四氟硼酸根与邻二氮菲银形成的络合物由MIBK萃取后,用火焰原子吸收光谱法间接测定硼,其线性范围为0.002-1μg/mL,检出限为0.41μg/mL,回收率为93%-101%,且K^ 、Na^ 等10个种离子不干扰测定,本方法用于地下水中痕量硼的测定,结果令人满意。