排序方式: 共有18条查询结果,搜索用时 31 毫秒
11.
B. B. Tumataeva B. K. Kasenov S. Zh. Davrenbekov E. S. Mustafin Zh. I. Sagintaeva Sh. B. Kasenova S. T. Edil’baeva 《Russian Journal of Inorganic Chemistry》2009,54(1):27-29
Ytterbium alkali-metal chromites YbMCr2O5 (M = Li, Na, K, Cs) were synthesized by a ceramic procedure from the corresponding oxides and carbonates. Their crystal systems and unit cell parameters were determined by the homology method: for YbLiCr2O5, a = 10.34 Å, b = 10.62 Å, c = 15.05 Å, Z = 16, V o = 1653.74 Å3, ρX-ray = 5.85 g/cm3, ρpycn = 5.81 ± 0.03 g/cm3; for YbNaCr2O5, a = 10.30 Å, b = 10.56 Å, c = 16.46 Å, Z = 16, V o = 1790.32 Å3, ρX-ray = 5.64 g/cm3, ρpycn = 5.59 ± 0.07 g/cm3; for YbKCr2O5, a = 10.33 Å, b = 10.63 Å, c = 19.93 Å, Z = 16, V o = 2188.47 Å3, ρX-ray = 5.95 g/cm3, ρpycn = 5.91 ± 0.03 g/cm3; and for YbCsCr2O5, a = 10.34 Å, b = 10.63 Å, c = 18.43 Å, Z = 16, V o = 2025.72 Å3, ρX-ray = 5.19 g/cm3, ρpycn = 5.16 ± 0.05 g/cm3. 相似文献
12.
B. K. Kasenov S. Zh. Davrenbekov E. S. Mustafin Sh. B. Kasenova Zh. I. Sagintaeva A. Zh. Abil’daeva B. T. Ermagambet Zh. S. Bekturganov 《Russian Journal of Inorganic Chemistry》2013,58(5):570-573
Manganite ferrites NdM 1.5 II MnFeO6 (MII = Mg, Ca, Sr, Ba) were synthesized from neodymium(III), manganese(III), and iron(III) oxides and alkaline-earth metal carbonates by a ceramic technology. By grinding the obtained compounds in a ball mill, their nanostructured particles were produced, the sizes of which were determined with an electron microscope. X-ray diffraction study established that the nanostructured compounds crystallize in the cubic and tetragonal systems with the following lattice parameters: NdMg1.5MnFeO6 (tetragonal): a = 10.955 Å, c = 17.848 Å, V 0 = 2141.975 Å3, Z = 16, V e1.cel1 0 = 133.873 Å3, ρX-ray = 4.80 g/cm3, and ρpycn = 4.76 ± 0.05 g/cm3; NdCa1.5MnFeO6 (cubic): a= 10.809 Å, V 0 = 1262.864 Å3, Z = 8, V e1.cel1 0 = 157.858 Å3, ρX-ray = 4.32 g/cm3, and ρpycn = 4.27 ± 0.03 g/cm3; NdSr1.5MnFeO6 (cubic): a = 10.911 Å, V 0 = 1298.953 Å3, Z = 8, V e1.cel1 0 = 162.369 Å3, ρX-ray = 4.93 g/cm3, and ρpycn= 4.88 ± 0.05 g/cm3; and NdBa1.5MnFeO6 (tetragonal): a = 11.011 Å, c = 18.001 Å, V 0 = 2182.479 Å3, Z = 16, V e1.cel1 0 = 136.405 Å3, ρX-ray = 6.78 g/cm3, and ρpycn= 6.75 ± 0.07 g/cm3. 相似文献
13.
B. K. Kasenov Zh. I. Sagintaeva Sh. B. Kasenova A. Zh. Abil’daeva S. Zh. Davrenbekov Zh. S. Bekturganov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2013,87(6):1057-1059
The standard enthalpies of formation of LnMIIMnFeO5.5 manganitoferrites (Ln is a rare-earth element, and MII is an alkali-earth metal) were estimated by the developed method of calculation. Their standard entropies were calculated by the method of ionic increments, and their standard Gibbs energies of formation were determined by the Gibbs-Helmholtz equation. 相似文献
14.
B. K. Kasenov S. T. Edil’baeva E. S. Mustafin S. M. Sergazina Sh. B. Kasenova S. Zh. Davrenbekov 《Russian Journal of Inorganic Chemistry》2007,52(8):1180-1183
New ferrites ErMFe2O5 (M = Li, Na, K) were synthesized from erbium and iron(III) oxides and lithium, sodium, and potassium carbonates by solid-state annealing. According to X-ray powder diffraction, these compounds crystallize in the orthorhombic system with the following unit cell parameters: ErLiFe2O5, a = 10.510 Å, b = 10.776 Å, c = 14.270 Å, V 0 = 1616.16 Å3; Z = 16, V subcell 0 = 101.01 Å3, ρX = 6.01 g/cm3, ρpycn = 5.97 ± 0.05 g/cm3; ErNaFe2O5, a = 10.519 Å, b = 10.785 Å, c = 15.510 Å, V 0 = 1759.56 Å3, Z = 16, V subcell 0 = 109.90 Å3, ρX = 5.77 g/cm3, ρpycn = 5.72 ± 0.08 g/cm3; ErKFe2O5, a = 10.050 Å, b = 11.320 Å, c = 15.480 Å, V 0 = 1937.33 Å3, Z = 16, V subcell 0 = 121.08 Å3, ρX = 5.46 g/cm3, ρpycn = 5.41 ± 0.04 g/cm3. 相似文献
15.
B. K. Kasenov E. S. Mustafin M. A. Akubaeva Zh. I. Sagintaeva S. T. Edil’baeva Sh. B. Kasenova S. Zh. Davrenbekov 《Russian Journal of Inorganic Chemistry》2008,53(11):1691-1693
Ternary chromites of the composition LaMIMg(CrO3)2 (MI = Li, Na, K) were synthesized for the first time by ceramic technology from stoichiometric amounts of high purity grade La2O3; pure for analysis grade Li2CO3, Na2CO3, K2CO3, and MgCO3; and chemically pure grade Cr2O3. Using X-ray diffractometry, it has been established that compounds are crystallized in cubic and tetragonal crystal systems, and parameters of their crystal lattices have been determined. 相似文献
16.
Burkeev M. Zh. Khamitova T. O. Havliček D. Sarsenbekova A. Zh. Davrenbekov S. Zh. Tazhbaev E. M. Kozhabekova G. E. Imanbekova Zh. K. Bolatbai A. N. 《Russian Journal of Applied Chemistry》2019,92(1):1-8
Russian Journal of Applied Chemistry - New mono- and bimetallic polymer nanocomposites based on polyethylene(propylene) glycol maleates with acrylic acid and silver and nickel metals were prepared... 相似文献
17.
B. K. Kasenov E. S. Mustafin M. A. Akubaeva S. T. Edil’baeva Sh. B. Kasenova Zh. I. Sagintaeva S. Zh. Davrenbekov 《Russian Journal of Inorganic Chemistry》2010,55(9):1454-1457
Manganites DyM3IMg3Mn4O12 and DyM3IBa3Mn4O12 (MI = Li, Na, K) were synthesized by the solid-state reaction of dysprosium and manganese(III) oxides and magnesium and corresponding alkali metal carbonates. The X-ray powder diffraction studies showed that the crystals
are orthozhombic with the following unit cell parameters and densities: DyLi3Mg3Mn4O12—a = 10.88 ?, b = 10.73 ?, c = 19.63 ?, V
0 = 1656.2 ?3, Z = 8, ρcalc = 5.36 g/cm3, ρpycn = 5.11 ± 0.05 g/cm3; DyNaMg3Mn4O12—a = 10.55 ?, b = 10.72 ?, c = 18.28 ?, V
0 = 2067.4 ?3, Z = 8, ρcalc = 4.60 g/cm3, ρpycn = 4.88 ± 0.09 g/cm3; DyK3Mg3Mn4O12—a = 10.56 ?, b = 10.72 ?, c = 20.89 ?, V
0 = 2206.0 ?3, Z = 8, ρcalc = 4.60 g/cm3, ρpycn = 4.92 ± 0.06 g/cm3; DyLi3Ba3Mn4O12—a = 10.53 ?, b = 10.69 ?, c = 21.28 ?, V
0 = 2395.4 ?3, Z = 8, ρcalc = 5.58 g/cm3, ρpycn = 5.98 ± 0.12 g/cm3; DyNa3Ba3Mn4O12—a = 10.53 ?, b = 10.74 ?, c = 23.00 ?, V
0 = 2602.3 ?3, Z = 8, ρcalc = 5.39 g/cm3, ρpycn = 5.30 ± 0.07 g/cm3; DyK3Ba3Mn4O12—a = 10.52 ?, b = 10.75 ?, c = 25.69 ?, V
0 = 2905.2 ?3, Z = 8, ρcalc = 5.04 g/cm3, ρpycn = 5.00 ± 0.18 g/cm3. 相似文献
18.
Sh. B. Kasenova A. Zh. Abil’daeva Zh. I. Sagintaeva S. Zh. Davrenbekov B. K. Kasenov 《Russian Journal of Physical Chemistry A, Focus on Chemistry》2013,87(5):719-723
The heat capacities of the new manganite ferrites NdMIMnFeO5 (MI = Li, Na) are investigated in the range of 298.15–673 K by dynamic calorimetry. It is found that in the investigated temperature range, C p ○ ~ f(T) curves exhibit λ-shaped effects at 348 and 473 K for NdLiMnFeO5, and at 423 K for NdNaMnFeO5, corresponding probably to phase transitions of the second kind. Equations describing the experimentally obtained C p ○ ~ f(T) curves are derived, and the temperature dependences of the investigated compounds’ thermodynamic functions, S○(T), H○(T) ? H○(298.15), and Φ xx (T), are calculated. 相似文献