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41.
The oxidative coupling reaction between hydroquinone or catechols and various sodium benzenesulfinates was investigated using the laccase from Trametes versicolor, in the presence of O2 in a phosphate buffer solution at room temperature to afford sulfonyl benzenediols in 75–95% yield. 相似文献
42.
A new method for modeling and analysis of deformed carbon nanotubes (CNTs) using Green’s function, is presented in this paper,
for the first time. Using the proposed method, a new circuit model is obtained for the deformation region of a deformed single-walled
CNT (SWCNT), which the values of its elements depend on the type of deformation and also the deformation parameters such as
the coupling matrices and the energy variations of deformation region. The comparison between the obtained results from the
analysis of proposed model and the literature gives a good match which approves the accuracy and correctness of the proposed
model. 相似文献
43.
44.
Abstract
Arylaminotetrazoles were efficiently synthesized from secondary arylcyanamides by application of ZnCl2/AlCl3/silica as a reusable heterogeneous Lewis acid catalyst. 5-Arylamino-1H-tetrazoles can be obtained from arylcyanamides carrying electron-withdrawing substituents on the aryl ring, while with electron-releasing groups 1-aryl-5-amino-1H-tetrazoles will be produced. The former isomer is also produced within longer reaction times (~20 h) even with electron-releasing groups. 相似文献45.
Electrochemical oxidation of catechol and its derivatives ( 1a–d ) has been studied in the presence of 4‐amino‐3‐thio‐1,2,4‐triazole ( 3 ) at various pHs. Some electrochemical techniques such as cyclic voltammetry using the diagnostic criteria derived by Nicholson and Shain for various electrode mechanisms and controlled‐potential coulometry were used. Results indicate the participation of catechols ( 1a–d ) with 3 in an intramolecular cyclization reaction to form the corresponding 1,2,4‐triazino[5,4‐b]‐1,3,4‐thiadiazine derivatives. In various scan rates, based on an electron transfer–chemical reaction–electron transfer–chemical reaction mechanism, the observed homogeneous rate constants (kobs) for Michael addition reaction were estimated by comparing the experimental cyclic voltammetric responses with the digital simulated results. The oxidation reaction mechanism of catechols ( 1a–d ) in the presence of 4‐amino‐3‐thio‐1,2,4‐triazole ( 3 ) was also studied. © 2007 Wiley Periodicals, Inc. Int J Chem Kinet 39: 340–345, 2007 相似文献
46.
Electrochemical oxidation of some catecholamines such as dopamine ( 1 ), L ‐dopa ( 2 ), and methyldopa ( 3 ) has been studied in various pH values, using cyclic voltammetry. The results indicate participation of catecholamines ( 1–3 ) in intramolecular cyclization reaction to form the corresponding o‐quinone derivatives ( 1d–3d ). In various pHs, based on ECE mechanism, the observed homogeneous rate constants (kobs) of cyclization reaction were estimated by comparing the experimental cyclic voltammetric responses with the digital‐simulated results. Also, the cyclization rate constants (kcyc) were calculated using microscopic acidic dissociation constant of ammonium groups. The significant differences in electrochemical behavior, kobs and kcyc, of L ‐dopa ( 2 ) and methyldopa ( 3 ) with dopamine ( 1 ) are due to the effects of the side chain carboxyl group. © 2004 Wiley Periodicals, Inc. Int J Chem Kinet 37: 17–24, 2005 相似文献
47.
We show that for an inverse semigroup S with the set idempotents E acting on S trivially from left and by multiplication from right, any bounded module derivation from \(\ell ^1(S)\) to \(({\ell ^1(S)}/{J})^*=J^{\perp }\) is inner, where J is the closed ideal generated by elements of the form \(\delta _{set}-\delta _{st}\) with \(s,t\in S\) and \(e\in E\). 相似文献
48.
Lesarri A Vega-Toribio A Suenram RD Brugh DJ Nori-Shargh D Boggs JE Grabow JU 《Physical chemistry chemical physics : PCCP》2011,13(14):6610-6618
The conformational and structural properties of the inhalational anesthetic isoflurane (1-chloro-2,2,2-trifluoroethyl difluoromethyl ether) have been probed in a supersonic jet expansion using Fourier-transform microwave (FT-MW) spectroscopy. Two conformers of the isolated molecule were identified from the rotational spectrum of the parent and several (37)Cl and (13)C isotopologues detected in natural abundance. The two most stable structures of isoflurane are characterized by an anti carbon skeleton (τ(C(1)-C(2)-O-C(3)) = 137.8(11)° or 167.4(19)°), differing in the trans (AT) or gauche (AG) orientation of the difluoromethyl group. The conformational abundances in the jet were estimated from relative intensity measurements as (AT)/(AG) ≈ 3:1. The structural preferences of the molecule have been rationalized with supporting ab initio calculations and natural-bond-orbital (NBO) analysis, which suggest that the molecule is stabilized by hyperconjugative effects. The NBO analysis of donor-acceptor (LP → σ*) interactions showed that these stereoelectronic effects decrease from the AT to AG conformations, so the conformational preferences can be accounted for in terms of the generalized anomeric effect. 相似文献
49.
Karimi Kerdabadi Javad Haghanimanesh Maedeh Karimipour Arash Toghraie Davood Tlili Iskander 《Journal of Thermal Analysis and Calorimetry》2021,143(1):293-308
Journal of Thermal Analysis and Calorimetry - Hot-rolled strips are cooled on the run-out table to achieve the customer-required mechanical properties. Cooling reduces the oxidation, which can... 相似文献
50.
Rostami Sara Toghraie Davood Esfahani Masihollah Ahmadi Hekmatifar Maboud Sina Nima 《Journal of Thermal Analysis and Calorimetry》2021,143(2):1119-1128
Journal of Thermal Analysis and Calorimetry - In the current work, after generating experimental data points for different volume fraction of nanoparticles ( $$\phi$$ ) and different temperatures,... 相似文献