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61.
A facile and one pot electrochemical synthesis of disubstituted hydroquinone generated from the electrochemical oxidation of 4-1-(4-(4-hydroxyphenyl)piperazin-1-yl)ethanone (1) in the presence of 4-hydroxy-6,7-dimethylcoumarin (3) has been reported. The results revealed that p-quinone imine derived from oxidation of (1) participate in Michael addition reactions with 3 and followed by a hydrolysis reaction attain to the highly symmetric and conjugated coumarin derivative. We derived a new product in good yield based on controlled potential electrochemical oxidation at carbon electrode in a divided cell. 相似文献
62.
Gholami Mohammad Reza Akbari Omid Ali Marzban Ali Toghraie Davood Shabani Gholamreza Ahmadi Sheikh Zarringhalam Majid 《Journal of Thermal Analysis and Calorimetry》2018,134(3):1611-1628
Journal of Thermal Analysis and Calorimetry - In this research, the laminar and forced flow and heat transfer of oil/multi-walled carbon nanotubes nanofluid in a microchannel have been numerically... 相似文献
63.
Ahmad R. Massah Davood Azadi Hamid Aliyan Ahmad R. Momeni Hamid Javaherian Naghash Foad Kazemi 《Monatshefte für Chemie / Chemical Monthly》2008,139(3):233-240
Summary. The preparation of N-acylsulfonamides is described using primary amines, arylsulfonyl chlorides and acyl chlorides. Reaction of primary aryl amines
with arylsulfonyl chlorides in the presence of NaHCO3 produced N-arylsulfonamides, which reacted in situ with benzoyl chloride furnishing the corresponding N-benzoyl-N-arylsulfonamides in 72–96% yields. Accordingly, 4-nitrobenzoyl chloride and 3,5-dinitrobenzoyl chloride were used as acylating
agents. All the reactions were carried out under solvent-free conditions at room temperature and the products were isolated
after simple work-up in high yields and purity. 相似文献
64.
Diisopropyltetrahydroquinoxalinedione derivatives are synthesized from the reaction of various catechols with N,N′-diisopropylethylenediamine. Both chemical and electrochemical methods give the same products. While the chemical synthesis is faster, the electrochemical synthesis provides higher yields. 相似文献
65.
Microwave‐assisted aromatization of 1,3,5‐trisubstituted 4,5‐dihydro‐1H‐pyrazoles by in‐situ generation of NO+ and NO2+ respectively from sodium nitrite and sodium nitrate in acetic acid has been carried out efficiently under mild reaction conditions in good to excellent yields. 相似文献
66.
An adsorptive differential pulse stripping method for the simultaneous determination of lead and tin is proposed. The procedure involves an adsorptive accumulation of lead and tin on a hanging mercury drop electrode (HMDE), followed by oxidation of adsorbed lead and tin by voltammetric scan using differential pulse modulation. The optimum experimental conditions are: 0.2 mol L?1 HNO3, accumulation potential of ?900 mV versus Ag/AgCl, accumulation time of 200 s, scan rate of 20 mV s?1 and pulse height of 80 mV. Lead and tin peak currents were observed in the same potential region at about ?400 mV. The simultaneous determination of lead and tin by using voltammetry is a difficult problem in analytical chemistry, due to voltammogram interferences. The resolution of a mixture of lead and tin by the application of orthogonal signal correction‐partial least squares (OSC‐PLS) was performed. The linear dynamic ranges were 0.003‐0.35 and 0.008‐0.50 μg mL?1 and detection limits were land 3 ng mL?1 for lead and tin, respectively. The RMSEP for lead and tin with OSC and without OSC were 2.8737, 6.0557 and 8.0941, 9.5151, respectively. The capability of the method for the analysis of real samples was evaluated by the determination of lead and tin in water samples with satisfactory results. 相似文献
67.
In this work, titanomagnetite nanoparticles (Fe3-xTixO4) have been used as a novel suppport for the synthesis of a magnetic acidic catalyst. These nanoparticles were functionalized with sulfonic acid groups to prepare the Fe3-xTixO4@SO3H nanoparticles. The synthesized acidic nanoparticles have been explored as new and efficient recyclable heterogeneous catalyst for a one-pot, three-component synthesis of tetrahydrobenzo[b]pyrans known as 4H-chromenes and 1,4-dihydropyrano[2,3-c]pyrazoles. The structure of the catalyst was established by infrared, energy dispersive x-ray (EDX), and scanning electron microscopy analyses. The reactions proceed smoothly to furnish the respective products in excellent yields and short reaction times. The facile reaction conditions, easy isolation of the products, versatility, and easy magnetic separation and reusability of the catalyst with no significant loss of activity are the main merits of the present method. 相似文献
68.
Haleh Valian Mohsen A. Jafari Davood Golmohammadi 《Annals of Operations Research》2016,239(2):625-641
A control-theoretic decision making system is proposed for an agent (decision maker) to “optimally” allocate and deploy his/her resources over time among a dynamically changing list of opportunities (e.g., financial assets), in an uncertain market environment. The solution is a sequence of actions with the objective of optimizing total reward function. This control-theoretic approach is unique in a sense that it solves the problem at distinct time epochs over a finite time horizon and strategies are discovered directly. Rather than basing a decision making system on forecasts or training via a reinforcement learning algorithm using current state data, we train our system via a Q-learning algorithm using Geometric Brownian Motion as an asset price function. While the above problem is quite general, we focus solely on the problem of dynamic financial portfolio management with the objective of maximizing the expected utility for a given risk level. The performance functions that we consider for our system are realized mean return, drawdown and standard deviation. We find that our model achieves a better return and drawdown compared to a known market index as a benchmark. 相似文献
69.
Davood Nori-Shargh Seiedeh Negar Mousavi Rose Tale Hooriye Yahyaei 《Structural chemistry》2016,27(6):1753-1768
The correlations between the global hardness (η), hyperconjugative anomeric effect, Pauli exchange-type repulsions, electrostatic model associated with dipole–dipole interaction and structural parameters in 2-fluorotetrahydropyran, -thiopyran, -selenopyran (1–3) and their chloro- (4–6) and bromo-analogs (7–9) were investigated by means of the conventional and range-corrected functionals and natural bond orbital (NBO) interpretation. By deletion of the HC-exo-AE and HC-endo-AE, the equatorial conformations of compounds 1–9 become more stable than their corresponding axial forms, revealing that anomeric relationships in compounds 1–9 have the hyperconjugative anomeric effect origins while the electrostatic model associated with dipole–dipole interaction does not play a determining role on the variations of the anomeric relationships in these compounds. The anomeric relationships in compounds 1–3 have no Pauli exchange-type repulsions origin, but it has a significant impact on the conformational preferences in compounds 4–6 and 7–9. A canonical molecular orbital interpretation was conducted to investigate the correlations between the linear combinations of natural bond orbitals in the HOMOs, LUMOs and the global hardness (η) values. There is a direct relationship between the hyperconjugative anomeric effect, global hardness (η) and zero-point energies in compounds 1–3, 4–6 and 7–9. The harder axial conformations with the greater hyperconjugative anomeric effect and zero-point energy values are more stable than their corresponding equatorial forms. 相似文献
70.
Quantitative structure–property relationships of retention indices of some sulfur organic compounds using random forest technique as a variable selection and modeling method 下载免费PDF全文