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311.
Dr. Davood Zare Prof. Dr. Claude Piguet Dr. Alessandro Prescimone Prof. Dr. Catherine E. Housecroft Prof. Dr. Edwin C. Constable 《Chemistry (Weinheim an der Bergstrasse, Germany)》2022,28(42):e202200912
The allosteric positive cooperativity accompanying the formation of compact [CuI(α,α′-diimine)2]+ building blocks contributed to the historically efficient synthesis of metal-containing catenates and knotted assemblies. However, its limited magnitude can easily be overcome by the negative chelate cooperativity that controls the overall formation of related polymetallic multistranded helicates and grids. Despite the more abundant use of analogous dioxygen-resistant [AgI(α,α′-diimine)2]+ units in modern entangled metallo-supramolecular assemblies, a related thermodynamic justification was absent. Solid-state structural characterizations show the successive formation of [AgI(α,α′-diimine)(CH3CN)][X] and [AgI(α,α′-diimine)2][X] upon the stepwise reactions of α,α′-diimine=2,2′-bipyridine (bpy) or 1,10-phenanthroline (phen) derivatives with AgX (X=BF4−, ClO4−, PF6−). In room-temperature, 5–10 mM acetonitrile solutions, these cationic complexes exist as mixtures in fast exchange on the NMR timescale. Spectrophotometric titrations using the unsubstituted bpy and phen ligands point to the statistical (=non-cooperative) binding of two successive bidentate ligands around AgI, a mechanism probably driven by the formation of hydrophobic belts, that overcomes the unfavorable decrease in the positive charge borne by the metallic cation. Surprisingly, the addition of methyl groups adjacent to the nitrogen donors (6,6′ positions in dmbpy; 2,9 positions in dmphen) induces positive cooperativity for the formation of [Ag(dmbpy)2]+ and [Ag(dmphen)2]+, a trend assigned to additional stabilizing interligand interactions. Adding rigid and polarizable phenyl side arms in [Ag(Brdmbpy)2]+ further reinforces the positively cooperative process, while limiting the overall decrease in metal–ligand affinity. 相似文献
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Abstract
Stereoselective reaction of various substituted phenols with alkyl propiolates in the presence of a catalytic amount of sodium azide in tert-butyl alcohol at reflux temperature leads to alkyl (Z)-3-phenoxy-2-propenoates in good yields. 相似文献315.
Behrooz Maleki Davood Azarifar Seyede Fateme Hojati Hojat Veisi Mostafa Gholizadeh Hafezeh Salehabadi Mona Khodaverdian Moghadam 《Journal of heterocyclic chemistry》2011,48(2):449-453
2,4,6‐Trichloro‐1,3,5‐triazine efficiently catalyzed the condensation reactions between 2‐aminothiophenol and aromatic aldehydes to afford 2‐arylbenzothiazolles in good‐to‐excellent yields. Simple and mild reaction conditions, the use of a cheap catalyst and easy work up, and isolation are notable features of this method. J. Heterocyclic Chem., (2011). 相似文献
316.
Lida Fotouhi Esmail Tammari Samaneh Asadi Majid M. Heravi Davood Nematollahi 《国际化学动力学杂志》2009,41(6):426-431
The reaction of o‐benzoquinone derived by the oxidation of catechols ( 1a–c ) with some nucleophiles containing thiol group ( 2a–f ) has been studied in various conditions, such as pH, nucleophile concentration, and scan rate, using cyclic voltammetry. In various conditions, based on an EC electrochemical mechanism (“E” represents an electron transfer at the electrode surface and “C” represents a homogeneous chemical reaction), the observed homogeneous rate constants (kobs) were estimated by comparison of the experimental cyclic voltammetric responses with the digital simulated results for each of the nucleophile. The results show that the magnitude of kobs is dependent on the nature of the substituted group on the catechol ring and nucleophilicity of nucleophile. © 2009 Wiley Periodicals, Inc. Int J Chem Kinet 41: 426–431, 2009 相似文献
317.
Mohammad Ali Zolfigol Iraj Mohammadpoor-Baltork Davood Habibi BiBi Fatemeh Mirjalili Abdolhamid Bamoniri 《Phosphorus, sulfur, and silicon and the related elements》2013,188(11):2189-2193
Trimethylsilyl ethers were converted to their corresponding alcohols in the presence Nafion-H® and wet SiO 2 with good-to-excellent yields under mild and heterogeneous conditions. 相似文献
318.
Mohammad Hossein Davood Abadi Farahani Dangchen Ma Pegah Nazemizadeh Ardakani 《Separation & Purification Reviews》2020,49(3):177-206
Organic solvent nanofiltration (OSN) is a molecular separation method which offers a sustainable and reliable solution compared to the conventional energy-intensive separation processes. OSN can be successfully applied to several applications, such as food, pharmaceutical, petrochemical and fine-chemical industries. Current research on OSN membranes mainly focuses on polymeric materials due to the ease of processing, controlled formation of pores, lower fabrication costs and higher flexibility as compared with inorganic materials. However, there are some limitations for the polymeric membranes which can be partially surmounted by adding nanoscale fillers into the polymeric matrix to make nanocomposite membranes. This review aims to comprehensively evaluate and report the advances in nanocomposite membranes prepared by using either different nanoscale fillers or various fabrication methods for OSN applications. Nanoparticles that will be discussed include metal-organic framework, graphene oxide, carbon nanotubes, silica, titanium, gold, zeolite and other fillers. The incorporation of these nanoscale fillers into the polymeric membranes can positively influence the mechanical strength, chemical and thermal stability, hydrophilicity, solute selectivity and solvent permeance. This study may provide helpful insights to develop next-generation of OSN membranes for years to come. 相似文献
319.
1,2-Di(p-tolylimino)ethane (Ⅰ) and 1,2-Di(2,4-dimethylphenylimino)ethane (Ⅱ) were synthesized and their electrochemical behavior investigated in dimethylformamide using classical voltammetry, differential pulse voltammetry, cyclic voltammetry, chronoamperometry, controlled potential electrolysis and coulometry. Both bis-Schiff base ligands examined show a cathodic irreversible peak which corresponds to one-electron reduction of the substrate to form anion radical. According to the fact obtained from cyclic voltammetry, that the current function (ip/v^1/2) is a decreasing function of the scan rate, it can be concluded that there is a following coupling chemical reaction (EC mechanism). Thus, the most probable mechanism of electroreduction of both ligands is the coupling of two radicals to form a dimer. 相似文献
320.
An efficient and user‐friendly procedure has been developed for the chemoselective protection of aldehyde carbonyl groups such as bis(2‐hydroxyethyl)dithioacetals with 2‐mercaptoethanol catalyzed by silica‐supported sodium bisulphate under solvent‐free conditions. It has been shown that a variety of aldehydes can expeditiously undergo this reaction to produce their corresponding dithioacetals with impressive yields at room temperature. 相似文献