A general synthetic method for the formation of arylaminotetrazoles using natural natrolite zeolite as a new and reusable heterogeneous catalyst

An efficient method for preparation of arylaminotetrazoles is reported using natrolite zeolite as a natural catalyst. Generally, isomer of 5-arylamino-1H-tetrazole can be obtained from arylcyanamides carrying electron-withdrawing substituent on aryl ring and as the electropositivity of substituent is increased, the product is shifted toward the isomer of 1-aryl-5-amino-1H-tetrazole. This method has the advantages of high yields, simple methodology, short reaction times and easy work-up. The catalyst can be recovered by simple filtration and reused in good yields.     

Late-time acceleration and phantom divide line crossing with?non-minimal coupling and Lorentz-invariance violation

We consider two alternative dark-energy models: a Lorentz-invariance preserving model with a non-minimally coupled scalar field and a Lorentz-invariance violating model with a minimally coupled scalar field. We study accelerated expansion and the dynamics of the equation of state parameter in these scenarios. While a minimally coupled scalar field does not have the capability to be a successful dark-energy candidate with line crossing of the cosmological constant, a non-minimally coupled scalar field in the presence of Lorentz invariance or a minimally coupled scalar field with Lorentz-invariance violation have this capability. In the latter case, accelerated expansion and phantom divide line crossing are the results of the interactive nature of this Lorentz-violating scenario.     

Local solution of the stress and strain fields in the necking section of cylindrical bars under uniaxial tension

The problem of finding the stress and strain fields over the minimum cross section of necked cylindrical bars under uniaxial tensile load has been solved locally using a new fast numerical method. The scheme delivers both the accuracy of the finite element analysis and the applicability of simple closed-form analytical solutions. The required inputs are the distributions of curvature radii for both isostatic and material lines. It is numerically observed that the mathematical formulas available in the literature fail to adequately predict these distributions. Introducing the stress normalized strain-hardening rate as the most decisive parameter affecting the curvature radii, a database and interpolation technique have been developed in order to estimate the necessary information based on the results of the previously FE analyzed samples. Finally, a practical case has been solved and compared with the FE results.     

Nonlinear dynamics of an inclined beam subjected to a moving load

In this paper, the nonlinear dynamic response of an inclined pinned-pinned beam with a constant cross section, finite length subjected to a concentrated vertical force traveling with a constant velocity is investigated. The study is focused on the mode summation method and also on frequency analysis of the governing PDEs equations of motion. Furthermore, the steady-state response is studied by applying the multiple scales method. The nonlinear response of the beam is obtained by solving two coupled nonlinear PDEs governing equations of planar motion for both longitudinal and transverse oscillations of the beam. The dynamic magnification factor and normalized time histories of mid-pint of the beam are obtained for various load velocity ratios and the outcome results have been illustrated and compared to the results with those obtained from traditional linear solution. The appropriate parametric study considering the effects of the linear viscous damping, the velocity of the traveling load, beam inclination angle under zero or nonzero axial load are carried out to capture the influence of the effect of large deflections caused by stretching effects due to the beam’s immovable ends. It was seen that quadratic nonlinearity renders the softening effect on the dynamic response of the beam under the act of traveling load. Also in the case where the object leaves the inclined beam, its planar motion path is derived and the targeting accuracy is investigated and compared with those from the rigid solution assumption. Moreover, the stability analysis of steady-state response for the modes equations having quadratic nonlinearity was carried out and it was observed from the frequency response curves that for the considered parameters in the case of internal-external primary resonance, both saturation phenomenon and jump phenomenon can be predicted for the longitudinal excitation.     

Hypercomplex mathematics and HPM for the time-delayed Burgers equation with convergence analysis

We investigate the analytical and numerical solutions of the time-delayed Burgers equation, by applying the idea of commutative hypercomplex mathematics and the homotopy perturbation method. Moreover, we discuss at great length the convergence conditions of the homotopy perturbation Method (HPM) by using the Banach fixed point theory , which could provide a good iteration algorithm. Finally, we also give some numerical illustrations to the obtained results.     

Analytical approach to heat and mass transfer in MHD free convection from amoving permeable vertical surface

An analytical study is performed on heat and mass transfer in MHD‐free convection from a moving permeable vertical surface and the results are compared with previous works on this phenomenon to test the validity. The coupled equations of boundary layer are transformed from their non‐linear form to ordinary form using similarity transformation and then are solved by a newly developed method, homotopy analysis method. Having different base functions, homotopy analysis method provides us with great freedom in choosing the solution of a nonlinear problem. Solving the boundry layer equations, the effects of different parameters such as magnetic field strength parameter (M), Prandtl number (Pr), Schmidt number (Sc), buoyancy ratio and suction/blowing parameter (f_w) on velocity, temperature, and concentration profiles are taken into consideration. Obtained results show that increment of magnetic field strength parameter (M) leads to decrease in velocity profile. Copyright © 2011 John Wiley & Sons, Ltd.     

Correction to: On the optimization of a vertical twisted tape arrangement in a channel subjected to MWCNT–water nanofluid by coupling numerical simulation and genetic algorithm

Journal of Thermal Analysis and Calorimetry - Lignin-based polycaprolactone (PCL) graft copolymers with various graft ratios were prepared by ring-opening reaction in order to design new lignin...     

Application of rotating circular obstacles in improving ferrofluid heat transfer in an enclosure saturated with porous medium subjected to a magnetic field

Journal of Thermal Analysis and Calorimetry - In this paper, the evaluation of the heat transfer rate and fluid flow in an enclosure with rotating circular obstacles has been studied. The enclosure...     

An environmentally friendly electrochemical method for synthesis of benzofuranoquinone derivatives

Electrochemical oxidation of catechols (1a-c) has been studied in the presence of 2-hydroxy-1,4-naphtoquinone (3b) in aqueous solutions, using cyclic voltammetry and controlled-potential coulometry. The results indicated that the electrochemically generated o-benzoquinones (2a-c) participate in Michael addition reaction with 3b to the corresponding benzofuranoquinones (8a-c, 10a-c). The electrochemical synthesis of these compounds has been successfully preformed at a carbon rod electrode with good yields using an environmentally friendly method.     

Voltammetry of Electroinactive Species Using Quinone/Hydroquinone Redox: A Known Redox System Viewed in a New Perspective

Electrochemical behavior of p‐benzoquinone (Q), hydroquinone (H₂Q) and quinhydrone complex (QH) have been investigated in aqueous unbuffered solutions. The results revealed that in unbuffered solution the half wave potential of hydroquinone has a significant difference with quinone's half wave potential. It shown that, added acid in an unbuffered solution of Q, give rise to a new reduction peak at a more positive potential than original reduction peak of Q. The half‐peak potential of this new peak is dependent on acidity of added acid (pK_a) and its height is proportional to the acid concentration. Also, added base in an unbuffered solution of H₂Q, give rise to a new oxidation peak at a more negative potential than original oxidation peak of H₂Q. The half‐peak potential of this new peak is dependent on basicity of added base (pK_b) and its height is proportional to the base concentration. This paper shows new perspectives for a known system in aqueous unbuffered solutions, by means of voltammetric responses that can be exploited for the electrochemical investigation of non electroactive species such as HPO , HCO or CH₃COOH.