Negative molecular ions of azafullerenes and their hydrogenated derivatives

The formation and decay of negative molecular ions of azafullerenes and their hydrogenated derivatives are investigated by mass spectrometry. The mechanisms of resonant electron capture and the lifetimes of negative molecular ions with respect to the electron autodetachment in azafullerene molecules are discussed. A comparative analysis of the data obtained for azafullerenes and hydrogenated fullerene derivatives is carried out.     

A simplified method of computing the process of opening of a parachute

We propose a simplified method of determining the integral characteristics of the opening of a parachute which makes it possible to compute the maximal stress on a parachute and the trajectory parameters of the motion of the load in the region of the opening of the parachute, and to determine the size of the portion of the canopy at the time of maximal stress.Translated fromDinamicheskie Sistemy, No. 6, 1987, pp. 38–41.     

An expedient route to diaza-spirocycles utilizing a sequential multicomponent α-aminoallylation/ring-closing metathesis strategy

A general method for the preparation of diaza-spirocycles is reported. This method used an olefin metathesis in order to construct the desired spirocyclic framework. Beginning with commercially available protected amino ketones, this strategy ultimately produced pharmacologically relevant diaza-scaffolds in an efficient and high-yielding process.     

A Class of C ·0-Contractions: Hyperinvariant Subspaces and Intertwining Operators

We consider a class of C_·0-contractions that is a generalization of the class of C_·0-contractions with finite defect indices. Some results of Uchigama and Wu for C_·0-contractions with finite defect indices are generalized: the lattices of hyperinvariant subspaces of such a contraction T is isomorphic to that of its Jordan model and is generated by subspaces of the form Ker ϕ(T) and Ran ϕ(T), where ϕ ∈ H^∞. The form of the inverse to an isomorphism of the invariant subspace lattices given by an intertwining quasiaffinity is also studied. Next, for C_·0-contractions in question, the characteristic disc related to the lattice of invariant subspaces is computed. Bibliography: 13 titles. __________ Translated from Zapiski Nauchnykh Seminarov POMI, Vol. 315, 2004, pp. 48–62.     

Effect of Alkali Metal Cation on Copolymerization of Acrylamide with Salts of 2-Acrylamido-2-methylpropanesulfonic Acid in Aqueous Solutions

The kinetics of radical copolymerization of acrylamide with lithium, sodium, and potassium 2-acrylamido-2-methylpropanesulfonates in concentrated aqueous solutions in the presence of potassium persulfate as initiating agent at pH 9 and 50°C was studied by dilatometry.     

Contact Interaction of Two Elastic Wedges

We consider the problem of contact of two elastic wedges and assume that only the vertices of the wedges touch before loading. After loading, the edges of both wedges come in contact near their common vertex. We reduce the constructed system of dual integral equations to a Fredholm integral equation of the second kind with difference kernel given on the semiaxis. We analytically solve the Fredholm equation by reducing it to the boundary-value Riemann problem for analytic functions. We obtain an analytic expression for contact stresses.     

A NOTE ON FINITE DIFFERENCE ESTIMATION OF ACOUSTIC PARTICLE VELOCITY

The influence of instrumentation amplitude and phase mismatch on finite difference measurement of mean square particle velocity is examined. It is shown theoretically and demonstrated experimentally that the resulting error depends on two properties of the sound field, the ratio of the active intensity to the mean square particle velocity and the ratio of the reactive intensity to the mean square particle velocity. Very large errors can occur near particle velocity nodes in interference fields even with well-matched state-of-the-art sound intensity measurement systems. However, outside of such regions, moderate phase mismatch has very little influence on the performance of the measurement system. Amplitude mismatch is somewhat more problematic.     

Dynamical Characteristics of Traveling Wave Packets of Total Electron Content Disturbances

Using the COPHASE method and the GPS interferometry method for travelling ionospheric disturbances, we analyze in detail the spatio-temporal properties of travelling wave packets (TWP) of total electron content (TEC) disturbances. The analysis is performed on the example of a clearest TWP manifestation observed in California, USA, in October 18, 2001, using the GLOBDET technique, developed at the Institute of Solar-Terrestrial Physics of the Siberian Branch of RAS for global detection and monitoring of natural and technogenic ionospheric disturbances on the basis of TEC variations retrieved from the global network of GPS receivers. In the time domain, TWPs are quasi-periodic TEC oscillations of duration about 1 h, period of 10–20 min, and amplitude exceeding that of the background TEC fluctuations by at least one order of magnitude. The velocity and direction of TWP motion are similar to those of mid-latitude mesoscale travelling ionospheric disturbances, as obtained earlier from the analysis of phase parameters of HF radio signals and the signals of geostationary satellites and discrete space radio sources.     

On the critical exponents of random k‐SAT

There has been much recent interest in the satisfiability of random Boolean formulas. A random k‐SAT formula is the conjunction of m random clauses, each of which is the disjunction of k literals (a variable or its negation). It is known that when the number of variables n is large, there is a sharp transition from satisfiability to unsatisfiability; in the case of 2‐SAT this happens when m/n → 1, for 3‐SAT the critical ratio is thought to be m/n ≈ 4.2. The sharpness of this transition is characterized by a critical exponent, sometimes called ν = ν_k (the smaller the value of ν the sharper the transition). Experiments have suggested that ν₃ = 1.5 ± 0.1. ν₄ = 1.25 ± 0.05, ν₅ = 1.1 ± 0.05, ν₆ = 1.05 ± 0.05, and heuristics have suggested that ν_k → 1 as k → ∞. We give here a simple proof that each of these exponents is at least 2 (provided the exponent is well defined). This result holds for each of the three standard ensembles of random k‐SAT formulas: m clauses selected uniformly at random without replacement, m clauses selected uniformly at random with replacement, and each clause selected with probability p independent of the other clauses. We also obtain similar results for q‐colorability and the appearance of a q‐core in a random graph. © 2002 Wiley Periodicals, Inc. Random Struct. Alg., 21: 182–195, 2002