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51.
[reaction: see text] A new poly(ethylene glycol)-supported porphyrin has been prepared and its ability as a promoter in photooxidation reactions has been studied. The PEG-supported catalyst exhibits high activity, comparable to that of a nonanchored sensitizer, and it is easily removable by filtration from the reaction mixture. The polymer-bound porphyrin has been recycled up to six times with no loss of chemical and stereochemical efficiency. 相似文献
52.
Davide Franco 《Annali di Matematica Pura ed Applicata》1996,170(1):133-145
Sunto
Si analizzano delle condizioni per l'annullamento della coomologia di fibrati stabili di rango 2su
P
3.Dopo i primi risultati di annullamento dovuti principalmente ad Hartshorne, Chang congetturò che alcune disuguaglianze sulle, classi di Chern fossero sufficienti per l'annullamento del primo gruppo di coomologia. La congettura finora è provata solo in alcuni casi particolari. Nel lavoro si dimostra la congettura in molti altri casi. In particolare si completano alcuni risultati recenti dovuti ad Ellia affrontando il caso in cui la prima classe di Chern è dispari. 相似文献
53.
In this paper we study the nature of the singularity of the Kontsevichs solution of the WDVV equations of associativity. We prove that it corresponds to a singularity in the change of two coordinates systems of the Frobenius manifold given by the quantum cohomology of CP2.
Mathematics Subject Classifications (2000) 53C99, 32D99, 14N35, 88A99. 相似文献
54.
We use classical molecular dynamics combined with the recently developed metadynamics method [Laio, A.; Parrinello, M. Proc. Natl. Acad. Sci. U.S.A. 2002, 99, 20] to study the process of bulk melting in hexagonal ice. Our simulations show that bulk melting is mediated by the formation of topological defects which preserve the coordination of the tetrahedral network. Such defects cluster to form a defective region involving about 50 molecules with a surprisingly long lifetime. The subsequent formation of coordination defects triggers the transition to the liquid state. 相似文献
55.
Working in the Wannier representation, we derive an expression for the orbital magnetization of a periodic insulator. The magnetization is shown to be comprised of two contributions, an obvious one associated with the internal circulation of bulklike Wannier functions in the interior, and an unexpected one arising from net currents carried by Wannier functions near the surface. Each contribution can be expressed as a bulk property in terms of Bloch functions in a gauge-invariant way. Our expression is verified by comparing numerical tight-binding calculations for finite and periodic samples. 相似文献
56.
Dionigi C Nozar P Di Domenico D Calestani G 《Journal of colloid and interface science》2004,275(2):445-449
In this paper we propose a simple model for the formation of monodisperse polymer colloids, which provides a convenient set of synthetic parameters for given bead diameters. We provide experimental data in support of this model. 相似文献
57.
[reaction: see text] The ring-closing olefin metathesis (RCM) of 2,2'-divinylbiphenyls, using a second-generation RCM ruthenium-based catalyst, leads to differently substituted phenanthrenes in quantitative yield under very mild reaction conditions, independent of both nature and position of the groups present on the biphenyl moiety. 相似文献
58.
We consider an elliptic operator of second order with Dirichlet boundary
conditions in a cylindrical domain. We show that a suitable interpretation of this
operator in a certain space of continuous functions vanishing on the boundary is
the infinitesimal generator of an analytic semigroup in the space of continuous
functions. We prove several inclusions of the domain of the infinitesimal generator
and of the real interpolation spaces between this domain and the basic space of
continuous functions. 相似文献
59.
We show that, in low-dimensional photonic bandgaps, wave diffraction resulting from localization in the translational-invariant directions is strongly influenced by the photonic band structure of the periodic crystal, leading to new kinds of wave localization. In particular, for a periodic layered structure we show that, close to a bandgap edge, diffraction is enhanced, with a transition from a parabolic diffraction curve-typical of isotropic media and supporting Gaussian beams-to hyperbolic or elliptic diffraction curves. In the last two cases localization in the form of stationary X-shaped or sinc-shaped waves is possible. 相似文献
60.
Bianco A Pantarotto D Hoebeke J Briand JP Prato M 《Organic & biomolecular chemistry》2003,1(23):4141-4143
A peptide analogue from a histone H3 protein containing the L-fulleropyrrolidino-glutamic acid has been prepared by a solid-phase approach and has been fully characterized. By molecular modelling it was verified that this peptide derivative is able to retain a binding capacity to the MHC (major histocompatibility complex) molecule similar to that of the cognate epitope. 相似文献