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61.
62.
Alexander N Shivanyuk Dmitry M Rudkevich David N Reinhoudt 《Tetrahedron letters》1996,37(52):9341-9344
An assembly of cation receptor 1 and anion receptor 2 via the hydrogen bonding melamine-barbiturate structural motif complexes sodium thiocyanate, sodium iodide, and sodium azide in apolar solvents. 相似文献
63.
Carl W. David 《Journal of computational chemistry》1993,14(6):715-717
A scheme for sprouting peptide side chains using X-PLOR is introduced using an example from the collagen system to show how reasonable starting structures for minimization studies may be created. © 1993 John Wiley & Sons, Inc. 相似文献
64.
65.
F. Rubio F. García H. D. Burrows A. A. C. C. Pais A. J. M. Valente M. J. Tapia J. M. García 《Journal of polymer science. Part A, Polymer chemistry》2007,45(9):1788-1799
The interaction between trivalent lanthanide ions and poly(1,4,7,10,13‐pentaoxacyclopentadecan‐2‐yl‐methyl methacrylate), PCR5, in aqueous solution and in the solid state have been studied. In aqueous solution, evidence of a weak interaction between the lanthanides and PCR5 comes from the small red shift of the Ce(III) emission spectra and the slight broadening of the Gd(III) EPR spectra. From the Tb(III) lifetimes in the presence of H2O and D2O the loss of one or two water coordinated molecules is confirmed when Tb(III) is bound to PCR5. An association constant of the order of 200 M?1 was obtained for a 1:1 (lanthanide:15‐crown‐5) complex from the shift of the polymer NMR signals induced by Tb(III). A similar association constant is obtained from the differences of the molar conductivity of Ce(III) solution at various concentrations in presence and absence of PCR5. When Tb(III) is adsorbed on PCR5 membranes, lifetime experiments in H2O and D2O confirm the loss of 5 or 6 water coordinated molecules indicating that in solid state the lanthanide(III)‐PCR5 interaction is stronger than in solution. The adsorption of Ce(III) in PCR5 membranes shows a Langmuir type isotherm, from which an equilibrium constant of 39 M?1 has been calculated. SEM shows that the membrane morphology is not much affected by lanthanide adsorption. Support for lanthanide ion–crown interactions comes from ab initio calculations on 15‐crown‐5/La(III) complex. © 2007 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 45: 1788–1799, 2007 相似文献
66.
David Stanovský 《Czechoslovak Mathematical Journal》2007,57(1):191-200
We investigate the variety of residuated lattices with a commutative and idempotent monoid reduct. 相似文献
67.
In this paper, we apply a three-stage-DEA model to the Spanish Professional Football League, which means separating the teams’
economic behaviour into three components: operating efficiency—of the offence and defence—athletic or operating effectiveness,
and social effectiveness. The results showed that the technical inefficiency of the defence is greater than that of the offence,
both being caused by aspects linked to the poor management of players’ abilities and by the football team’s size. Teams showed
a favourable evolution of their offensive and defensive efficiency during the 2004/2005 season and to a lesser extent in the
season before. The point system assigned by the professional football league regulations evaluates the teams’ athletic effectiveness,
but we detected that the teams with the most experience perform athletically in a more effective manner. Their social effectiveness
is strongly related to the level of play in itself and to factors linked to their PFL ranking: participation in international
competitions for important football teams; or the struggle of minor football teams to stay in the first division. 相似文献
68.
Neutral Community Theory: How Stochasticity and Dispersal-Limitation Can Explain Species Coexistence
Neutral community theory explains biodiversity, i.e. the coexistence of several species, as the result of a stochastic balance
between immigration and extinction on a local level, and between speciation and extinction on a regional level. The most popular
model, presented by Hubbell in 2001, has seen many analytical developments in recent years, which can be used in model analysis,
model testing and model comparison. We review these developments here, and present alternative derivations and shine previously
unnoticed lights on them. 相似文献
69.
Let P(G,λ) be the chromatic polynomial of a graph G with n vertices, independence number α and clique number ω. We show that for every λ≥n, ()α≤≤ ()
n
−ω. We characterize the graphs that yield the lower bound or the upper bound.?These results give new bounds on the mean colour
number μ(G) of G: n− (n−ω)()
n
−ω≤μ(G)≤n−α() α.
Received: December 12, 2000 / Accepted: October 18, 2001?Published online February 14, 2002 相似文献
70.
Jose Manuel Corcuera Joao Guerra David Nualart Wim Schoutens 《Applied Mathematics and Optimization》2006,53(3):279-309
In this paper we consider the optimal investment problem in a market where the stock price process is modeled by a geometric
Levy process (taking into account jumps).
Except for the geometric Brownian model and the geometric Poissonian model, the
resulting models are incomplete and there are many equivalent martingale measures.
However, the model can be completed by the so-called power-jump assets. By doing this we allow investment in these new assets
and we can try to maximize the expected utility of these portfolios. As particular cases we obtain the optimal portfolios
based in stocks
and bonds, showing that the new assets are superfluous for certain martingale measures
that depend on the utility function we use. 相似文献