Selected-area growth of carbon nanotubes by the combination of focused ion beam and chemical vapor deposition techniques.

In this article, we report a technique for growing carbon nanotubes in a more controllable fashion, which enables us to synthesize nanotubes directly in various forms of designed patterns. This nanofabrication process is based on a combination of focused ion beam (FIB) and chemical vapor deposition (CVD) techniques. In this process, arrays of conductive patterns were first deposited on silicon substrates by directing a gaseous compound (C(9)H(16)Pt) via the capillary needle-sized nozzles within a FIB system. The substrates were then coated with catalyst and further modified by the FIB to localize the position of the catalyst. Finally, the growth of carbon nanotubes on the designed substrates was carried out by CVD of hydrocarbon gases. This fabrication technique has the advantage of positioning carbon nanotubes in selected locations. This may open up opportunities for the direct synthesis of carbon nanotubes onto almost any substrate material, thus allowing fabrication of carbon nanotube-based devices.     

The prediction of sequences

The problem of predicting the short-term future behavior of a sequence, after observing it as long as we please, so as to achieve a specified reliability against all possible sequences is considered. For a particular problem, namely, predicting when in a sequence of 0's and 1's the pair (1, 0) in that order is not coming next, a reliability of 3/4 can be approximated as closely as we please, but not achieved. This article appeared as a Research Memorandum of the Rand Corporation, RM-1570, 12 October 1955.     

Multi-Wavelength Optical Packet Routing Technologies Based on Superstructured Fiber Bragg Gratings

A WDM compatible Edge-to-Edge Self-Routed optical packet switched network that simplifies the optical processing is proposed. The system employs all-optical packet label generation and recognition using coded superstructured Fiber Bragg gratings.     

Zero-divisor graphs, von Neumann regular rings, and Boolean algebras

For a commutative ring R with set of zero-divisors Z(R), the zero-divisor graph of R is Γ(R)=Z(R)−{0}, with distinct vertices x and y adjacent if and only if xy=0. In this paper, we show that Γ(T(R)) and Γ(R) are isomorphic as graphs, where T(R) is the total quotient ring of R, and that Γ(R) is uniquely complemented if and only if either T(R) is von Neumann regular or Γ(R) is a star graph. We also investigate which cardinal numbers can arise as orders of equivalence classes (related to annihilator conditions) in a von Neumann regular ring.     

Total synthesis of the marine cytotoxic caulibugulones A-D

We report the first total synthesis of the cytotoxic marine alkaloids caulibugulone A-D. This synthesis confirmed the assigned structures and provided sufficient material for further biological testing.     

Bismuth compounds in organic synthesis. Bismuth nitrate catalyzed chemoselective synthesis of acylals from aromatic aldehydes

Aromatic aldehydes are smoothly converted into the corresponding acylals in good yields in the presence of 3-10 mol% Bi(NO₃)₃·5H₂O. Ketones are not affected under the reaction conditions. The relatively non-toxic nature of the catalyst, its ease of handling, easy availability and low cost make this procedure especially attractive for large-scale synthesis.     

Structure and catalytic activity of some soluble polyethylene glycol-peptide conjugates

Soluble catalysts for the Juliá-Colonna asymmetric epoxidation reaction have been constructed in three different ways, using NH₂-PEG-OMe as the support system: suitable solvents have been identified and it is shown that the degree of helicity of the conjugates correlates with the extent of conversion and (to a lesser extent) the enantioselectivity of epoxidation.     

Study of ferroelectric switching by domain-wall induced light scattering

Measurements of 90°-scattering of weak laser light are used to investigate pulsed domain switching in ferroelectrics. The studies were performed on strontium-barium niobate (SBN) single crystals. A good agreement of the switching parameters estimated from the optical measurements with those obtained by means of conventional electrical methods proves the validity of the optical method for switching studies. Due to the limited scattering volume in all three spatial dimensions, the method facilitates local probing of the switching within the crystal bulk. In particular, local specialities of the domain density can be detected. Furthermore, the excellent time resolution inherent in optical probing techniques allows for a comprehensive study of the dynamics.     

Vessel Arrival Process and Queueing in Marine Ports Handling Bulk Materials

We study the vessel arrival process in bulk ports handling either cargo containers or minerals. Then we introduce the SHIP/G/1 queue to be able to study the queueing behavior at the port. We present approximations for the asymptotic probabilities of delay and the number of vessels at the port. Numerical examples show the accuracy of the approximations. In appendices, we provide details of the analysis of the number of vessels at the port and the correlation properties of the vessel arrival process.