全文获取类型
收费全文 | 96篇 |
免费 | 8篇 |
国内免费 | 1篇 |
专业分类
化学 | 52篇 |
力学 | 2篇 |
数学 | 13篇 |
物理学 | 38篇 |
出版年
2022年 | 6篇 |
2021年 | 3篇 |
2020年 | 2篇 |
2019年 | 5篇 |
2018年 | 6篇 |
2017年 | 3篇 |
2016年 | 2篇 |
2015年 | 2篇 |
2014年 | 9篇 |
2013年 | 2篇 |
2012年 | 8篇 |
2011年 | 2篇 |
2009年 | 1篇 |
2008年 | 4篇 |
2007年 | 3篇 |
2006年 | 1篇 |
2005年 | 3篇 |
2004年 | 3篇 |
2002年 | 4篇 |
2001年 | 4篇 |
2000年 | 4篇 |
1999年 | 4篇 |
1998年 | 2篇 |
1996年 | 4篇 |
1995年 | 4篇 |
1994年 | 2篇 |
1993年 | 5篇 |
1989年 | 1篇 |
1988年 | 2篇 |
1987年 | 1篇 |
1985年 | 1篇 |
1980年 | 1篇 |
1978年 | 1篇 |
排序方式: 共有105条查询结果,搜索用时 0 毫秒
31.
T J Lopez y López-Leitón M E Alvarez Pi?eiro M A Lage Yusty J L Cortizo Davi?a 《Journal of AOAC International》2001,84(6):1799-1801
The levels of 7 PCBs used as markers of dioxin in 62 pork meat samples (head, loin, and dewlap) were determined by supercritical fluid extraction and gas chromatography with electron capture detection. Analytical limits of detection for the individual congeners ranged from 0.048 to 0.2 ng/g dry wt. PCB congeners 153 and 180 were detected in all samples. Among congeners in general, PCB 52, 101, and 153 were the most abundant. There was a linear relationship with a good correlation between PCB 101 and PCB 52. 相似文献
32.
Sérgio M. Soares Sebastião S. Lemos Maria José A. Sales Davi F. Back Ernesto S. Lang 《Polyhedron》2009,28(17):3811-3815
The reaction of cadmium(II) acetate dehydrate with the complexing agents tropolone (tropH), 2-hydroxynaphthoquinone (nqH), 1,2-dihydroxyanthraquinone (alizH2), and 1,8-dihydroxyanthraquinone (chryzH2), afforded the complexes [Cd(trop)2] 1, [Cd2(nq)4(H2O)4]·3H2O 2·3H2O, [Cd(alizH)2(H2O)3] 3, and [Cd(chryzH)2(H2O)2] 4, respectively. The X-ray molecular structure of the dinuclear complex 2·3H2O reveals that each cadmium(II) atom is seven-coordinated. The nature of water molecules (lattice or coordinated) was discerned by thermogravimetric studies. The 113Cd NMR spectra were discussed in light of the chemical exchange. 相似文献
33.
Humberto César Chaves Fernandes Davi Bibiano Brito 《International Journal of Infrared and Millimeter Waves》2007,28(8):651-661
Photonic band gap (PBG) crystals have been used as a perfectly reflecting substrate for many millimeter wave applications.
In this work the fin line directional coupler with substrate PBG was analyzed using the TTL - Transverse Transmission Line
- method. Compared to other full wave methods the TTL is an efficient tool to determine the coupler characteristics, making
possible a significant algebraic simplification of the equations involved in the process. In order to analyze this structure
the effective dielectric constant, the attenuation constant and the coupling were determined. The results obtained for this
application and the conclusions are presented.
This work was partially financed by CNPQ. 相似文献
34.
The recent approach of solving large scale semidefinite programs with a first order method by minimizing an augmented primal-dual function is extended to doubly nonnegative programs. A key point governing the convergence of this approach are regularity properties of the underlying problem. Regularity of the augmented primal-dual function is established under the condition of uniqueness and strict complementarity. The application to the doubly nonnegative cone is motivated by the fact that the cost per iteration does not increase by adding nonnegativity constraints. Numerical experiments indicate that a two phase approach based on the augmented primal-dual function results in a stable method for solving large scale problems. 相似文献
35.
Liniquer Andr Fontana Josili Demetrio Siqueira Joice Ceolin Bernardo Almeida Iglesias Paulo Cesar Piquini Ademir Neves Davi Fernando Back 《应用有机金属化学》2019,33(7)
New mixed‐valence cobalt complexes with ligands derived from pyridoxal were synthesized and characterized, and their application as mimetics of the peroxidase enzyme was investigated. Single‐crystal X‐ray diffraction was used to analyze all complex structures in the solid state and their electrochemical behavior was investigated. A reactivity pattern was observed in the complex synthesis regarding the cobalt compounds from which analogous zwitterionic derivatives were obtained. The importance of these compounds lies in understanding their behavior in an oxidizing environment and evaluating whether they can activate hydrogen peroxide to oxidize phenolic compounds. In nature, enzymes called peroxidases, which efficiently oxidize phenolic compounds, trigger many reactions involving the activation of hydrogen peroxide to oxidize organic substrates. However, these enzymes present several disadvantages, including denaturation and elevated costs. Therefore, these limitations can be overcome by expanding research into the study of synthetic catalysts for the oxidation of phenolic compounds using hydrogen peroxide, which is a highly relevant field of bioinorganic chemistry. 相似文献
36.
The flow behind a vibrating flexible cable at low Reynolds numbers can exhibit complex wake structures such as lace-like patterns,
vortex dislocations and frequency cells. These structures have been observed in experiments and numerical simulations, and
are predicted by a previously developed low-order coupled map lattice (CML). The discrete (in time and space) CML models consist
of a series of diffusively coupled circle map oscillators along the cable span. Motivated by a desire to modify the complex
wake patterns behind flexible vibrating cables we have studied the addition of control terms into the highly efficient CML
models and explored the resulting dynamics. Proportional, adaptive proportional and discontinuous non-linear (DNL) control
methods were used to derive the control laws. The first method employed occasional proportional feedback. The adaptive method
used spatio-temporal feedback control. The DNL method used a discontinuous feedback linearization procedure, and the controller
was designed for the resulting linearized system using eigenvalue assignment. These techniques were applied to a modeled vortex
dislocation structure in the wake of a vibrating cable in uniform freestream flow. Parallel shedding patterns were achieved
for a range of forcing frequency-forcing amplitude combinations studied to validate the control theory. The adaptive proportional
and DNL methods were found to be more effective than the proportional control method due to the incorporation of a spatially
varying feedback gain across the cylinder span. The DNL method was found to be the most efficient controller of the low-order
CML model. The required control level across the cable span was correlated to the 1/1 lock-on behavior of the temporal circle
map. 相似文献
37.
Davi Serradella Vieiraand Lo Degrve 《Journal of Molecular Structure》2002,580(1-3):127-135
A 1.0 M aqueous KCl solution was studied by molecular dynamics simulations at 293 K in order to study the influence of the ionic concentration on the hydration structure of the ions as well as the formation of ion clusters. The hydration structures of the ions are almost independent of the ionic concentration unless in respect to the perturbation that appears due to ionic clustering. Fractions equal to 31.9% of the anions and 37.8% of the cations are associated. Clusters constituted by two, three and four ions were detected. Their mean lifetimes are always affected by thermal effects, reorientational relaxation while the longest lifetimes are a consequence of ionic cloud relaxations. The pairs constituted by two anions or two cations are stabilized by water molecules belonging to the solvation shells of both ions. The neutral K+Cl− pairs are formed under the influence of the electrostatic attraction that, however, is small due to the ionic radii of these ions. Consequently, this kind of pairs contains only 8.8% of the ions while the fraction of ions in the negative and positive pairs are equal to 29.2 and 39.3%, respectively, when the same ion can pertain to more than one pair. 相似文献
38.
39.
Wilami Teixeira da Cruz Davi Monteiro Dantas Roberto Vinhaes Maluf Carlos Alberto Santos Almeida 《Annalen der Physik》2019,531(10)
The Shannon‐like entropic measure of spatially localized functions for a 5D braneworld generated by a double sine‐Gordon (DSG) potential is evaluated. The differential configurational entropy (DCE) has been shown in several recent works to be a configurational informational measure (CIM) that selects critical points and brings out phase transitions in confined energy models with arbitrary parameters. The DSG scenario is selected because it presents an energy‐degenerate spatially localized profile where the solutions to the scalar field demonstrate critical behavior that is only a result of geometrical effects. As is shown, the DCE evaluation provides a method for predicting the existence of a transition between the phases of the domain wall solutions. Moreover, the entropic measure reveals information about the model that is capable of describing the phase sector where resonance modes on the massive spectra of the graviton is obtained. The graviton resonance lifetimes are related to the existence of scales on which 4D gravity is recovered. Thus, the critical points defined by the CIMs with the existence of resonances and their lifetimes are correlated. To extend the research regarding this system, the corrections to Newton's law coming from the graviton modes are calculated. 相似文献
40.
Mateus de Freitas Virgílio Pereira José Manoel Balthazar Davi Antônio dos Santos Angelo Marcelo Tusset Davi Ferreira de Castro Igor Afonso Acampora Prado 《Nonlinear dynamics》2017,87(3):1653-1666
This paper presents a polynomial chaos-based framework for designing optimal linear feedback control laws for nonlinear systems with stochastic parametric uncertainty. The spectral decomposition of the original stochastic dynamical model in an orthogonal polynomial basis, prescribed by the Wiener–Askey scheme, provides a deterministic model from which the optimal linear control law is designed. Optimality of the proposed control law is proved by solving the Hamilton–Jacobi–Bellman equation, and asymptotic stability of the controlled nonlinear systems is guaranteed in the Lyapunov sense. We are especially interested in synchronization of chaotic systems. For this reason, the control strategy is applied in the trajectory tracking of periodic orbits for the Duffing oscillator and the Rössler system with uncertain stochastic parameters and initial conditions. The results are verified with Monte Carlo simulations. 相似文献